固体电解质在锂空气电池中的应用
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摘要
锂空气电池的理论比能量高达3 505 Wh/kg,是新一代高比能电池的研发热点,有望应用于清洁能源、电动汽车及其他储能系统上。当前普遍研究的以有机电解液为基础的非水系锂空气电池存在着电解液挥发、分解以及锂负极粉化腐蚀等问题,这些问题极大地限制了锂空气电池的发展。固体电解质有高电位下稳定、不挥发、致密坚固的特点,使用固体电解质有望从根本上解决上述问题,推动锂空气电池的发展。从固体电解质的选择,固体电解质复合空气正极,电池性能等方面对近年国内外的研究进行总结,并对未来的研究方向进行展望。
The theoretical specific energy of Li-air battery is 3 505 Wh/kg, which is much higher than traditional Li-ion batteries. So, it has attracted a great interest for a new generation batteries which is essential for clean energy storage, electric vehicles, and other high-energy storage applications. However, there are significant technical challenges which restrict the development of practical lithium-air batteries: the instability of electrolytes and the corrosion of the lithium. The solid-state electrolytes with the advantages of stability, nonvolatility and sturdiness are promising to solve these problems completely, which is a great development of lithium-air batteries. The application of the solid-state electrolytes including the materials and the cathode was reviewed, and development forecast for the soild-state electrolytes was suggested.
The theoretical specific energy of Li-air battery is 3 505 Wh/kg, which is much higher than traditional Li-ion batteries. So, it has attracted a great interest for a new generation batteries which is essential for clean energy storage, electric vehicles, and other high-energy storage applications. However, there are significant technical challenges which restrict the development of practical lithium-air batteries: the instability of electrolytes and the corrosion of the lithium. The solid-state electrolytes with the advantages of stability, nonvolatility and sturdiness are promising to solve these problems completely, which is a great development of lithium-air batteries. The application of the solid-state electrolytes including the materials and the cathode was reviewed, and development forecast for the soild-state electrolytes was suggested.
引文
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[3]HUANG J,FAGHRI A.Analysis of electrolyte level change in a lithium air battery[J].Journal of Power Sources,2016,307:45-55.
[4]MIZUNO F,NAKANISHI S,KOTANI Y,et al.Rechargeable Li-air batteries with carbonate-cased liquid electrolytes[J].Electrochemistry,2010,78(5):403-405.
[5]JUNG H G,HASSOUN J,PARK J B,et al.An improved high-performance lithium-air battery[J].Nature Chemistry,2012,4(7):579-585.
[6]LIU T,LESKES M,YU W,et al.Cycling Li-O2 batteries via LiOHformation and decomposition[J].Science,2015,350(6260):530-533.
[7]PENG Z Q,FREUNBERGER S A,CHEN Y H,et al.A reversible and higher-rate Li-O2 battery[J].Science,2012,337:563-566.
[8]AKHTAR N,AKHTAR W.Prospects,challenges,and latest developments in lithium-air batteries[J].International Journal of Energy Research,2014,39(3):303-316.
[9]CHOI N S,LEE Y M,CHO K Y,et al.Protective layer with oligo(ethylene glycol)borate anion receptor for lithium metal electrode stabilization[J].Electrochemistry Communications,2004,6(12):1238-1242.
[10]KITAURA H,ZHOU H.Electrochemical performance and reaction mechanism of all-solid-state lithium-air batteries composed of lithium,Li1+xAlyGe2-y(PO4)3 soild electrolyte and carbon nanotube air electrode[J].Energy Environ Sci,2012,5:9077-9084.
[11]YI J,ZHOU H.A unique hybrid quasi-solid-state electrolyte for Li-O2 batteries with improved cycle life and safety[J].Chemsuschem,2016,9(17):2391-2396.
[12]LIN D,LIU Y,CUI Y.Reviving the lithium metal anode for highenergy batteries[J].Nature Nanotechnology,2017,13(2):194-206.
[13]KUMAR B,KUMAR J,LEESE R,et al.A solid-state,rechargeable,long cycle life lithium-air Battery[J].J.Electrochem Soc,2010,157:A50-A54.
[14]LIU Y,LI B,KITAURA H,et al.Fabrication and performance of all-solid-state Li-air battery with SWCNTs/LAGP cathode[J].Acs Applied Materials&Interfaces,2015,7(31):17307.
[15]WANG X,ZHU D,SONG M,et al.A Li-O2/air battery using an inorganic solid-state air cathode[J].ACS Applied Materials&Interfaces,2014,14(6):11204-11210.
[16]ZHU X B,ZHAO T S,WEI Z H,et al.A high-rate and long cycle life solid-state lithium-air battery[J].Energy&Environmental Science,2015,8(12):3745-3754.
[17]ZHU X,ZHAO T S,WEI Z,et al.A novel solid-state Li-O2 battery with an integrated electrolyte and cathode structure[J].Energy&Environmental Science,2015,8(9):2782-2790.
[18]ZHU X,ZHAO T,TAN P,et al.A high-performance solid-state lithium-oxygen battery with a ceramic-carbon nanostructured electrode[J].Nano Energy,2016,26:565-576.
[19]ZHANG T,IMANISHI N,HASEGAWA S,et al.Li/polymer electrolyte/water stable lithium-conducting glass ceramics composite for lithium-air secondary batteries with an aqueous electrolyte[J].Journal of the Electrochemical Society,2008,155(12):A965-A969.
[20]HARTMANN P,LEICHTWEISS T,BUSCHE M R,et al.Degradation of NASICON-type materials in contact with lithium metal:formation of mixed conducting interphases(MCI)on solid electrolytes(527)[J].The Journal of Physical Chemistry C,2013,41(117):21064-21074.
[21]MURUGAN R,THANGADURAI V,WEPPNER W.Fast lithium ion conduction in garnet-type Li7La3Zr2O12[J].Angewandte Chemie International Edition,2007,41(46):7778-7781.
[22]SUN J,ZHAO N,LI Y,et al.A rechargeable Li-air fuel cell battery based on garnet solid electrolytes[J].Scientific Reports,2017,7(1):41217.
[23]ZHAO Y,DING Y,LI Y,et al.A chemistry and material perspective on lithium redox flow batteries towards high-density electrical energy storage[J].Chemical Society Reviews,2015,44(22):7968-7996.
[24]BALAISH M,PELED E,GOLODNITSKY D,et al.Liquid-free lithium-oxygen batteries[J].Angewandte Chemie,2015,127(2):446-450.
[25]BONNETMERCIER N,WONG R A,THOMAS M L,et al.A structured three-dimensional polymer electrolyte with enlarged active reaction zone for Li-O2 batteries[J].Scientific Reports,2014,4(4):7127.
[26]NOOR I S,MAJID S R,AROF A K.Poly(vinyl alcohol)-LiBOBcomplexes for lithium-air cells[J].Electrochimica Acta,2013,102(21):149-160.
[27]JUNG K N,LEE J I,JUNG J H,et al.A quasi-solid-state rechargeable lithium-oxygen battery based on a gel polymer electrolyte with an ionic liquid[J].Chemical Communications,2014,50:5458-5461.
[28]HARDING J R,AMANCHUKU C V,HAMMOND P T,et al.Instability of poly(ethylene oxide)upon oxidation in lithium-air batteries[J].The Journal of Physical Chemistry C,2015,13(119):6947-6955.
[29]NASYBULIN E,XU W,ENGELHARD M H,et al.Stability of polymer binders in Li-O2 batteries[J].Journal of Power Sources,2013,243:899-907.