无机水合盐三水乙酸钠作相变储热材料的研究进展
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摘要
三水乙酸钠是一种研究较为广泛的无机水合盐类潜热储热材料,但其在储能工程应用中存在过冷、相分层及低导热率等问题。本文综述了解决这3类问题的国内外最新研究进展,目前主要采用试验法寻找成核剂和增稠剂来解决相分层和过冷问题,还没有找到理论依据来确定添加剂配方和用量。采用添加高导热率的物质来改善其导热效率,但三水乙酸钠的稳定性较差,应用于相变储热装置必须进行复合化、定型化、纳微化等处理。最后总结指出,三水乙酸钠储热材料的研究应该结合相变储热装置和系统进行,研制高充放热功率的储热换热器是关键,且应重点强化材料侧的传热效率。
Sodium acetate trihydrate has been widely studied as an inorganic hydration salt based latent heat storage material. The key challenges in the use of such a material include super cooling, phase separation, and low thermal conductivity. This article reviews the progress to address the challenges. Current methods of resolving the phase separation and supercooling challenges are mainly empirical, involving the search for nucleating agents and thickeners, for which little has been found on the development of theoretical approaches to determine the formulation and dosage. The low thermal conductivity has been addressed through the addition of highly thermally conductive. It is concluded that considerations are needed from both the device and system level for an effective use of sodium acetate trihydrate for thermal energy storage.
Sodium acetate trihydrate has been widely studied as an inorganic hydration salt based latent heat storage material. The key challenges in the use of such a material include super cooling, phase separation, and low thermal conductivity. This article reviews the progress to address the challenges. Current methods of resolving the phase separation and supercooling challenges are mainly empirical, involving the search for nucleating agents and thickeners, for which little has been found on the development of theoretical approaches to determine the formulation and dosage. The low thermal conductivity has been addressed through the addition of highly thermally conductive. It is concluded that considerations are needed from both the device and system level for an effective use of sodium acetate trihydrate for thermal energy storage.
引文
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[2]张寅平,胡汉平,孔祥冬.相变储能—理论和应用[M].合肥:中国科学技术大学出版社,1996.ZHANG Yinping,HU Hanping,KONG Xiangdong.Phase transition energy storage—Theory and applications[M].Heifei:China Science and Technology University Press,1996.
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[4]李金田,茅靳丰,李伟华,等.三水乙酸钠的过冷机理与实验研究[J].制冷学报,2009,30(5):32-35.LI Jintian,MAO Jinfeng,LI Weihua,et al.Supercooling mechanism and experimental study of sodium acetate trihydrate[J].Journal of Refrigeration,2009,30(5):32-35.
[5]阮德水,张太平,张道圣,等.水合盐相变热长期贮存的研究[J].太阳能学报,1993,14(1):16-22.RUAN Deshui,ZHANG Taiping,ZHANG Daosheng,et al.Study on long-term heat storage using molten salt hydrates[J].Acta Energiae Solaris Sinica,1993,14(1):16-22.
[6]阮德水,黎原斌,贺洛夫.无机晶体结构及其模型的教学[J].湖南城市学院学报,1989(6):82-88.RUAN Deshui,NI Yuanbin,HE Luofu.On the teaching of inorganic crystal structure and its models[J].Journal of Hunan City College,1989(6):82-88.
[7]丁益民,阎立诚,薛俊慧.水合盐储热材料的成核作用[J].化学物理学报,1996,9(1):83-86.DING Yimin,YAN Licheng,XUE Junhui.Nucleation of salt-hydrates as the thermal energy storage material[J].Chinese Journal of Chemical Physics,1996,9(1):83-86.
[8]WEI L,OHSASA K.Supercooling and solidification behavior of phase change material[J].ISIJ International,2010,50(9):1265-1269.
[9]王智平,郭长华,王克振,等.相变材料三水乙酸钠储热性能实验研究[J].化学工程,2011,39(5):27-30.WANG Zhiping,GUO Changhua,WANG Kezhen,et al.Experimental study on heat storage performance of sodium acetate trihydrate as phase change material[J].Chemical Engineering(China),2011,39(5):27-30.
[10]JIN X,MARIO A.Phase-change characteristic analysis of partially melted sodium acetate trihydrate using DSC[J].International Journal of Thermophysics,2014,35(1):45-52.
[11]JIN Xing,ZHANG Shuanglong,MARIO A.Experimental study of the cooling process of partially-melted sodium acetate trihydrate[J].Energy and Buildings,2014,76(7):654-660.
[12]YUUSUKE Y,KURAOKA M,SENGOKU K.Induction time and three-electrode current vs.voltage characteristics for electrical nucleation of concentrated solutions of sodium acetate trihydrate[J].Journal of Crystal Growth,2002,237(1):414-418.
[13]张雪梅,蔡路茵,苏忠杰.超声波对三水乙酸钠相分离及结晶的影响[J].化工学报,2010,61(1):104-108.ZHANG Xuemei,CAI Luyin,SU Zhongjie.Effects of ultrasound on phase separation and crystallization of sodium acetate trihydrate[J].Journal of the Chemical Industry and Engineering Society of China,2010,61(1):104-108.
[14]SEO K,SUZUKI S,KINOSHITA T,et al.Effect of ultrasonic irradiation on the crystallization of sodium acetate trihydrate[J].Chemical Engineering&Technology,2012,35(6):1013-1016.
[15]GOGATE U N.Ultrasound assisted cooling crystallization of sodium acetate[J].Industrial&Engineering Chemistry Research,2012,39:12901-12909.
[16]KENJI S,MASAYA I,HIROSHI H.A crystallographic study on the deactivation temperature of crystal nucleating agents for supercooled sodium acetate trihydrate[J].J.Chem.Eng.Jpn.,2007,40(1):36-43.
[17]阮德水,龙凌,张太平.三水合乙酸钠相变贮热的研究[J].华中师范大学学报(自然科学版),1987(3):393-396.RUAN Deshui,LONG Ling,ZHANG Taiping.Study on phase change heat storage of sodium acetate trihydrate[J].Journal of Central China Normal University,1987(3):393-396.
[18]徐建霞,柯秀芳.三水合乙酸钠相变储能性能研究[J].材料导报,2007(3):319-321.XU Jinxia,KE Xiufang.Study of phase change property of sodium acetate trihy drate as energy storage material[J].Materials Review,2007(3):319-321.
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[20]李晶,刘中良,马重芳.改善三水乙酸钠固液相变性能的实验研究[J].工程热物理学报,2006,26(5):817-819.LI Jin,LIU Zhongliang,MA Chongfang.Expermental study on improving solid-liquid phase change performance of acetate hydroxide trihydrate[J].Journal of Engineering Thermpohysics,2006,26(5):817-819.
[21]卢大杰,胡芃,赵斌斌,等.三水合乙酸钠纳米成核剂的性能研究[J].工程热物理学报,2012,33(8):19-25.LU Dajie,HU Peng,ZHAO Binbin,et al.Study on the performance of nanoparticles as nucleating agents for sodium acetate trihydrate[J].Journal of Engineering Thermpohysics,2012,33(8):19-25.
[22]GARAY Ramirez,CHRIST Glorieux,SAN Martinez.Tuning of thermal properties of sodium acetate trihydrate by blending with polymer and silver nanoparticles[J].Applied Thermal Engineer,2014,62(2):838-844.
[23]WADA T,YAMAMOTO R,MATSUO Y.Heat storage capacity of sodium acetate trihydrate during thermal cycling[J].Solar Energy,1984,33:373-375.
[24]CABEZA LF,SVENSSON G,HIEBLER S.Thermal performance of sodium acetate trihydrate thickened with different materials as phase change energy storage material[J].Applied Thermal Engineering,2003,23(13):1697-1704.
[25]EL-BASSUONI A A,TAYEB A M.Modification of urea-sodium acetate trihydrate mixture for solar energy storage[J].Renewable Energy,2003,28(10):1629-1643.
[26]杨果.CMC接枝AA改性三水乙酸钠相变材料的研究[D].广州:华南理工大学,2013.YANG Guo.Investigation of sodium acetate trihydrate phase change material modified by CMC-g-AA[D].Guangzhou:South China Univeristy of Technology,2013.
[27]KEINANEN M.Latent heat recovery from supercooled sodium acetate trihydrate using a brush heat exchanger[D].Helsinki:Helsinki University of Technology,2007.
[28]BONY J,CITHERLET S.Comparison between a new trnsys model and experimental data of phase change materials in a solar combisystem[J].Proceedings:Building Simulation,2007.
[29]茅靳丰,刁孝发,李金田,等.三水乙酸钠固液相变性能优化实验研究[J].制冷空调与电力机械,2009,30(5):1-4.MAO Jinfeng,DIAO Xiaofa,LI Jintian,et al.Optimizing experimental study on phase transition property of sodium acetate trihydrate[J].Refrigeration Air Conditioning&Electric Power Machinery,2009,30(5):1-4.
[30]李伟华,茅靳丰,李金田,等.三水乙酸钠基复合相变材料导热能力强化研究[J].建筑材料学报,2013(3):517-520.LI Weihua,MAO Jinfeng,LI Jintian,et al.Study of enhancing heat conductivity of composite phase change material based on sodium acetate trihydrate[J].Journal of Building Materials,2013(3):517-520.
[31]刘亚平,王家俊,周后恩.石墨填充复合相变储热材料导热性能和稳定性能研究[J].浙江理工大学学报,2011,28(4):586-590.LIU Yaping,WANG Jiajun,ZHOU Hou’en.Study on thermal conductivity and stability of expanded graphite filled phase change materials[J].Journal of Zhejiang Sci-Tech University,2011,28(4):586-590.
[32]王崇云,王维,冯利利,等.正二十烷与膨胀石墨共改性三水合乙酸钠相变材料储热性能[J].复合材料学报,2014(3):824-829.WANG Congyun,WANG Wei,FENG Lili,et al.Phase change property of sodium acetate trihydrate modified with n-eicosane and expanded graphite[J].Acta Materiae Compositae Sinica,2014(3):824-829.
[33]CHEN L.Phase change performance of sodium acetate trihydrate with Al N nanoparticles and CMC[J].Solar Energy Materials and Solar Cells,2011(9):2645-2649.
[34]杜晓冬,章学来,丁锦宏.纳米成核剂对三水乙酸钠蓄热性能的影响[J].建筑节能,2017,45(9):25-28.DU Xiaodong,ZHANG Xuelai,DING Jinhong.Effects of nanoparticles nucleating agents on the performance of sodium acetate trihydrate[J].Building Energy Efficiency,2017,45(9):25-28.
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