Ni-W-Cr-P多元合金膜制备与表征综合型实验设计
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摘要
设计了一个用化学镀工艺在钛合金表面制备Ni-W-Cr-P四元合金镀层的综合型实验。通过多元合金膜材料组分的设计、制备,让学生学习固相反应方法、X射线衍射分析、扫描电子显微镜分析、电化学性能分析等内容,系统地拓展了学生对当今材料科学的前沿认知。该实验条件简单,结果可靠,涉及材料科学、晶体学、电化学等知识。教学实践表明该综合型实验取得了良好的效果。
A comprehensive experiment on the preparation of the Ni-W-Cr-P four-element alloy coating on the titanium alloy surface by the electroless plating process is designed.Through the design and preparation of the components of the multiple alloy film material,this comprehensive experiment enables the students to learn the content including the solid-state reaction method,X-ray diffraction analysis,scanning electron microscope analysis,electrochemical performance analysis,etc.It focuses on the design and preparation of the content in the multiple alloy film,involving the solid-phase reaction method,X-ray diffraction analysis,scanning electron microscopy and electrochemical property analysis,which has systematically expanded students' frontiers in today's materials science.The experimental conditions are simple,and the results are reliable,involving materials science,crystallography,electrochemistry,etc.The teaching practice shows that this comprehensive experiment has achieved good results.
A comprehensive experiment on the preparation of the Ni-W-Cr-P four-element alloy coating on the titanium alloy surface by the electroless plating process is designed.Through the design and preparation of the components of the multiple alloy film material,this comprehensive experiment enables the students to learn the content including the solid-state reaction method,X-ray diffraction analysis,scanning electron microscope analysis,electrochemical performance analysis,etc.It focuses on the design and preparation of the content in the multiple alloy film,involving the solid-phase reaction method,X-ray diffraction analysis,scanning electron microscopy and electrochemical property analysis,which has systematically expanded students' frontiers in today's materials science.The experimental conditions are simple,and the results are reliable,involving materials science,crystallography,electrochemistry,etc.The teaching practice shows that this comprehensive experiment has achieved good results.
引文
[1]张冠军,来维亚,尹成先,等.金属表面Ni-P化学镀层研究现状[J].表面技术,2016,45(2):8-16.
[2]姜晓霞,沈伟.化学镀理及实践[M].北京:国防工业出版社,2000:26-38.
[3]晋勇,焦志峰.化学镀多元合金膜制备技术在实验教学中的应用[J].实验技术与管理,2015,32(10):32-34.
[4]王朋,刘宏,吕媛媛.化学沉积Ni-Mo-P和Ni-P镀层退火晶化组织及耐蚀性[J].表面技术,2015,44(10):7-15.
[5]马修泉,孙方红,齐志佳,等.热处理对化学镀镀层性能影响的研究进展[J].金属热处理,2015,40(7):160-163.
[6]晋勇,孙平,刘巧玲,等.热处理对不锈钢表面化学镀Ni-Cr-P合金镀层结构及性能的影响[J].材料热处理学报,2012,33(3):146-150.
[7]Ranganatha S,Venkatesha T V,Vathsala K.Electroless Ni-W-P Coating and Its Nano-WS2Composite:Preparation and Properties[J].Ind Eng Chem Res,2012,51(23):7932-7940.
[8]Liu H,GuoR X,Liu Y,et al.The effect of processing gas on corrosion performance of electroless Ni-W-P coatings treated by laser[J].Surface&Coatings Technology,2012(15):3350-3359.
[9]张慧娟,李琛,茹秀玲,等.温度对化学镀Co-W-P合金镀层性能的影响[J].电镀与环保,2017,37(3):30-32.
[10]奚小波,缪宏,金亦富,等.化学镀Ni-P电镀Ni-Co-Mn复合层力学及耐热腐蚀性能[J].稀有金属材料与工程,2017,46(3):790-795.
[11]Gostin P F,Gebert A,Schult L.An ultrathin polymer coating of carboxylate self-assembled monolayer adsorbed on passivated iron to prevent iron corrosion in 0.1M Na2SO4[J].Corrosion Science,2010,52(1):273-276.
[12]孙延安,李春福,张家林.Ni-Fe-P化学镀层抗CO2腐蚀性机理研究[J].表面技术,2014,43(6):1-5.
[13]Sinem Eraslan,Mustafargen.Oxidation behavior of electroless Ni-P,Ni-B and Ni-W-B coatings deposited on steel substrates Research article[J].Surface and Coatings Technology,2015,215:46-52.
[14]Chou Yuhsien,Bai Chingyuan,Ger Ming Der,et al.Studies on NiMo-P Coatings by Electroless Deposition[J].Key Engineering Materials,2008,86(364):333-339.
[15]张含卓,李晶,欧雪梅,等.化学镀Ni-Co-Cu-P非晶镀层及其耐蚀性能[J].稀有金属材料与工程,2016,45(11):2965-2969.
[16]方信贤,白允强,王章忠.J4不锈钢及Ni-P和Ni-Cu-P镀层在液-固两相流中的冲刷腐蚀行为[J].金属学报,2010,46(2):239-244.
[17]Cheng Yanhai,Cao Shuai,Hou Qingqiang,et al.Effect of Tungsten Addition on the Anti-fouling Property of the Electroless NiW-P Deposits[J].Rare Metal Materials and Engineering,2016,45(8):1931-1937.
[2]姜晓霞,沈伟.化学镀理及实践[M].北京:国防工业出版社,2000:26-38.
[3]晋勇,焦志峰.化学镀多元合金膜制备技术在实验教学中的应用[J].实验技术与管理,2015,32(10):32-34.
[4]王朋,刘宏,吕媛媛.化学沉积Ni-Mo-P和Ni-P镀层退火晶化组织及耐蚀性[J].表面技术,2015,44(10):7-15.
[5]马修泉,孙方红,齐志佳,等.热处理对化学镀镀层性能影响的研究进展[J].金属热处理,2015,40(7):160-163.
[6]晋勇,孙平,刘巧玲,等.热处理对不锈钢表面化学镀Ni-Cr-P合金镀层结构及性能的影响[J].材料热处理学报,2012,33(3):146-150.
[7]Ranganatha S,Venkatesha T V,Vathsala K.Electroless Ni-W-P Coating and Its Nano-WS2Composite:Preparation and Properties[J].Ind Eng Chem Res,2012,51(23):7932-7940.
[8]Liu H,GuoR X,Liu Y,et al.The effect of processing gas on corrosion performance of electroless Ni-W-P coatings treated by laser[J].Surface&Coatings Technology,2012(15):3350-3359.
[9]张慧娟,李琛,茹秀玲,等.温度对化学镀Co-W-P合金镀层性能的影响[J].电镀与环保,2017,37(3):30-32.
[10]奚小波,缪宏,金亦富,等.化学镀Ni-P电镀Ni-Co-Mn复合层力学及耐热腐蚀性能[J].稀有金属材料与工程,2017,46(3):790-795.
[11]Gostin P F,Gebert A,Schult L.An ultrathin polymer coating of carboxylate self-assembled monolayer adsorbed on passivated iron to prevent iron corrosion in 0.1M Na2SO4[J].Corrosion Science,2010,52(1):273-276.
[12]孙延安,李春福,张家林.Ni-Fe-P化学镀层抗CO2腐蚀性机理研究[J].表面技术,2014,43(6):1-5.
[13]Sinem Eraslan,Mustafargen.Oxidation behavior of electroless Ni-P,Ni-B and Ni-W-B coatings deposited on steel substrates Research article[J].Surface and Coatings Technology,2015,215:46-52.
[14]Chou Yuhsien,Bai Chingyuan,Ger Ming Der,et al.Studies on NiMo-P Coatings by Electroless Deposition[J].Key Engineering Materials,2008,86(364):333-339.
[15]张含卓,李晶,欧雪梅,等.化学镀Ni-Co-Cu-P非晶镀层及其耐蚀性能[J].稀有金属材料与工程,2016,45(11):2965-2969.
[16]方信贤,白允强,王章忠.J4不锈钢及Ni-P和Ni-Cu-P镀层在液-固两相流中的冲刷腐蚀行为[J].金属学报,2010,46(2):239-244.
[17]Cheng Yanhai,Cao Shuai,Hou Qingqiang,et al.Effect of Tungsten Addition on the Anti-fouling Property of the Electroless NiW-P Deposits[J].Rare Metal Materials and Engineering,2016,45(8):1931-1937.