风化壳中主要铁氧化物矿物的研究进展
|
摘要
铁氧化物是成土作用的最终产物,是古气候环境演化的良好信息载体,它们的成分结构、组合特征、相态转化和赋存形式等在一定程度上记录了形成时的沉积环境状况。本文在基于国内外有关铁氧化物研究的基础上,结合前人已取得的相关研究成果,综述了风化壳中铁氧化物矿物的主要类型、成因、常用定量分析方法、气候演变信息以及当前研究存在的不足之处。
Iron oxide is a good information carrier for the final product of soil formation and the evolution of paleoclimate environment. Their constituent structures, combined features, phase transformation and occurrence form are recorded to a certain extent. Basing on the study of iron oxide literature at home and abroad, this paper summarizes the main types,genesis, commonly used quantitative analysis methods, climate evolution information of iron oxide minerals in weathering crust and deficiency existing in the current study.
Iron oxide is a good information carrier for the final product of soil formation and the evolution of paleoclimate environment. Their constituent structures, combined features, phase transformation and occurrence form are recorded to a certain extent. Basing on the study of iron oxide literature at home and abroad, this paper summarizes the main types,genesis, commonly used quantitative analysis methods, climate evolution information of iron oxide minerals in weathering crust and deficiency existing in the current study.
引文
[1]黄崇玲.不同铁氧化物对土壤镉有效性及水稻累积镉的影响[D].南宁:广西大学,2013.
[2]龙晓泳.热带亚热带表生铁氧化物的气候响应研究[D].南京:南京大学,2011.
[3]吴思源,练有为,郑红,等.制备条件对合成针铁矿的影响[J].环境化学,2012,31(10):1625-1629.
[4]李响,蔡元峰.沉积物中铁氧化物的定量方法及其在白垩纪大洋红层中的应用[J].高校地质学报,2014,20(3):433-444.
[5]韩巍,梁成华,杜立宇,等.不同p H值条件下人工合成铁氧化物对磷的吸附特性[J].浙江农业学报,2010,22(1):77-80.
[6]季峻峰,陈骏,刘连文,等.黄土剖面中赤铁矿和针铁矿的定量分析与气候干湿变化研究[J].第四纪研究,2007,27(2):221-229.
[7]李丰义.黄土剖面中铁氧化物的特征及其成土环境的指示[D].武汉:华中农业大学,2011.
[8]李荣彪.长江中下游网纹红土中氧化铁矿物相及其气候环境意义[D].武汉:中国地质大学,2014.
[9]胡雪峰.黄土-古土壤序列中氧化铁和有机质对磁化率的影响[J].土壤学报,2004,41(1):7-12.
[10]李梦婕.腐殖酸、铁氧化物及其共存时对土壤汞赋存状态及生物活性的影响[D].重庆:西南大学,2012.
[11]CORNELL R M,SCHWERTMANN U.The iron oxides:structure,properties,reactions,occurrences and uses[M].Wiley-VCH,Weinheim:Germany,2003:345-363.
[12]邹雪华,陈天虎,张萍,等.天然针铁矿热处理产物的结构特征[J].硅酸盐学报,2013,41(10):1442-1446.
[13]CORNELL R M,SCHWERTMANN U.The iron oxides:structure,properties,reactions,occurrence and uses[M].Weinheim:VCⅡVerlagsgesellschaft,1996:573-579.
[14]K?MPF N,SCHWERTMANN U.Goethite and hematite in a climosequence in southern Brazil and their application in classification of kaolinitic soils[J].Geoderma,1983,29(1):27-39.
[15]TROLARD F,TARDY Y.The stabilities of gibbsite,boehmite,aluminous goethites and aluminous hematites in bauxites,ferricretes and laterites as a function of water activity,temperature and particle size[J].Geochimica et Cosmochimica Acta,1987,51(4):945-957.
[16]SCHWERTMANN U.Occurrence and formation of iron oxides in various pedoenvironments[M]//Iron in soils and clay minerals.Netherlands:Springer,1988:267-308.
[17]FISCHER W R,SCHWERTMANN U.The formation of hematite from amorphous iron(III)hydroxide[J].Clays and Clay Minerals,1975,23(1):33-37.
[18]SCHWERTMANN U.The effect of pedogenic environments on iron oxide minerals[M]//Advances in soil science.New York:Springer,1958:171-200.
[19]TORRENT J,SCHWERTMANN U,Schulze D G.Iron oxide mineralogy of some soils of two river terrace sequences in Spain[J].Geoderma,1980,23(3):191-208.
[20]WALKER T R.Formation of red beds in modern and ancient deserts[J].Geological Society of America Bulletin,1967,78(3):353-368.
[21]王小明.几种亚稳态铁氧化物的结构形成转化及其表面物理化学特性[D].武汉:华中农业大学,2015.
[22]BECHINE K,?UBRT J,HANSLIK T,et al.Transformation of syntheticγ-Fe OOH(lepidocrocite)in aqueous solutions of ferrous sulphate[J].Zeitschrift für anorganische und allgemeine Chemie,1982,489(1):186-196.
[23]OHTA S,EFFENDI S,TANAKA N,et al.Ultisols of lowland dipterocarp forest in East Kalimantan,Indonesia:III.clay minerals,free oxides,and exchangeable cations[J].Soil Science and Plant Nutrition,1993,39(1):1-12.
[24]范德江,陈彬,王亮,等.长江口外悬浮颗粒物中自生纤铁矿和胶黄铁矿[J].地球科学:中国地质大学学报,2014,39(10):1464-1469.
[25]SCHWERTMANN U,FITZPATRICK R W.Occurrence of lepidocrocite and its association with goethite in Natal soils[J].Soil Science Society of America Journal,1977,41(5):1013-1018.
[26]王小明,杨凯光,孙世发,等.水铁矿的结构、组成及环境地球化学行为[J].地学前缘,2011,18(2):339-347.
[27]SCHWERTMANN U,FISCHER W R.Natural“amorphous”ferric hydroxide[J].Geoderma,1973,10(3):237-247.
[28]CORNELL R M,SCHWERTMANN U.Influence of organic anions on the crystallization of ferrihydrite[J].Clays Clay Miner,1979,27(6):402-410.
[29]CHILDS C W.Ferrihydrite:A review of structure,properties and occurrence in relation to soils[J].Journal of Plant Nutrition and Soil Science,1992,155(5):441-448.
[30]CHUKHROV F V,ZVYAGIN B B,GORSHKOV A I,et al.Ferrihydrite[J].International Geology Review,1973,16:1131-1143.
[31]李学垣.土壤化学[M].北京:高等教育出版社,2001:1-402.
[32]BLAKEMORE R P.Magnetotactic bacteria[J].Science,1975,190(4212):377-379.
[33]Maher B A,Taylor R M.Formation of ultrafine-grained magnetite in soils[J].Nature,1988,336(6197):368-370.
[34]尧德中,俞劲炎,刘榜华.表土磁性增强现象的穆斯堡尔谱研究[J].土壤通报,1990,23(3):135-136.
[35]TAYLOR R M,SCHWERTMANN U.Maghemite in soils and Its origin I.properties and observations on soil maghemites[J].Clay Minerals,1974,10(4):289-298.
[36]FASSBINDER J W E,STANJEKT H,VALI H.Occurrence of magnetic bacteria in soil[J].Nature,1990,343(6254):161-163.
[37]刘秀铭,JOHN S,蒋建中,等.磁赤铁矿的几种类型与特点分析[J].中国科学:地球科学,2010,40(5):592-602.
[38]BARRN V,TORRENT J.Evidence for a simple pathway to maghemite in Earth and Mars soils[J].Geochimica et Cosmochimica Acta,2002,66(15):2801-2806.
[39]SCHWERTMANN U,FECHTER H.The influence of aluminum on iron oxides:XI.aluminum-substituted maghemite in soils and its formation[J].Soil Science Society of America Journal,1984,48(6):1462-1463.
[40]闫晓丽,杨一博,方小敏,等.临夏盆地晚中新世沉积物中赤铁矿和针铁矿的含量特征及其意义[J].兰州大学学报(自然科学版),2012,48(1):56-61.
[41]ZHANG Y G,JI J F,WILLIAM BALSAM,et al.High resolution hematite and goethite records from ODP 1143,South China Sea co-evolution of monsoonal precipitation and El Ni?o over the past 600,000years[J].Earth and Planetary Science Letters,2007,264(1-2):136-150.
[42]林伟伟,宋桂友.沉积物中X射线衍射物相定量分析中的两种方法对比研究[J].地球环境学报,2017,8(1):78-87.
[43]沈春玉,储刚.X射线衍射定量相分析新方法[J].分析测试学报,2003,22(6):80-82.
[44]BROWN G,WOOD I G.Estimation of iron oxides in soil clays by profile refinement combined with differential X-ray diffraction[J].Clay Minerals,1985,20(1):15-27.
[45]迟广成,肖刚,汪寅夫,等.铁矿石矿物组分的X射线粉晶衍射半定量分析[J].冶金分析,2015,35(1):38-44.
[46]郑国栋.基于穆斯堡尔谱技术的铁化学种及其在相关表生地球科学研究中的应用[J].矿物岩石地球化学通报,2008,27(2):161-167.
[47]卓文钦,吴新,赵长遂.基于穆斯堡尔谱的燃煤飞灰磁特性研究[J].中国电机工程学报,2010,30(20):65-70.
[48]张汉辉,韩勇,邢光熹.应用穆斯堡尔谱M?ssbauer_谱学方法研究燥红土中的氧化铁[J].土壤学报,1989,26(4):316-323.
[49]朱立军,李哲.碳酸盐岩红土中氧化铁矿物的穆斯堡尔谱学研究[J].贵州工学院学报,1996,25(5):34-38.
[50]商广凤.大气气溶胶中铁的溶解机制研究[D].上海:复旦大学,2013.
[51]JI J,BALSAM W,CHEN J.Mineralogic and climatic interpretationsoftheLuochuanloesssection(China)based on diffuse reflectance spectrophotometry[J].Quaternary Research,2001,56(1):23-30.
[52]李超,杨守业.长江沉积物中赤铁矿和针铁矿的漫反射光谱分析[J].地球科学:中国地质大学学报,2012(S1):11-19.
[53]周玮,季峻峰,陈骏.利用漫反射光谱鉴定红粘土中针铁矿和赤铁矿[J].高校地质学报,2007,13(4):730-736.
[54]盛阳.格尔木地区沙尘气溶胶理化特征及其来源分析[D].南京:南京师范大学,2015.
[55]王晶,陈震,陈国能.华南沿海末次冰期类黄土沉积的漫反射光谱与激光粒度研究[J].光谱学与光谱分析,2014,34(11):2901-2907.
[56]赵其国,杨浩.中国南方红土与第四纪环境变迁的初步研究[J].第四纪研究,1995,2:107-116.
[57]袁国栋,龚子同.第四纪红土的土壤发生及其古地理意义[J].土壤学报,1990,27(1):54-62.
[58]李小平,夏应菲,杨浩.安徽宣城第四纪红土剖面的全氧化铁含量及其古环境意义[J].江苏地质,1998,22(3):182-185.
[59]杨石岭,丁仲礼.7.0Ma以来中国北方风尘沉积的游离铁/全铁值变化及其古季风指示意义[J].科学通报,2000,45(2):2453-2456.
[60]郝振青,郭正堂.1.2Ma以来黄土-古土壤序列风化成壤强度的定量化研究与东亚夏季风演化[J].中国科学(D辑),2001,31(6):520-528.
[61]谢巧勤,陈天虎,孙玉兵,等.洛川黄土-古土壤序列铁氧化物组成及其古气候意义[J].矿物学报,2008,28(4):389-396.
[62]袁双.网纹红土铁形态特征与网纹红土形成环境[D].金华:浙江师范大学,2010.
[63]王思源.中国南方红土磁学特征、起源及其与成土过程关系研究[D].杭州:浙江大学,2014.
[2]龙晓泳.热带亚热带表生铁氧化物的气候响应研究[D].南京:南京大学,2011.
[3]吴思源,练有为,郑红,等.制备条件对合成针铁矿的影响[J].环境化学,2012,31(10):1625-1629.
[4]李响,蔡元峰.沉积物中铁氧化物的定量方法及其在白垩纪大洋红层中的应用[J].高校地质学报,2014,20(3):433-444.
[5]韩巍,梁成华,杜立宇,等.不同p H值条件下人工合成铁氧化物对磷的吸附特性[J].浙江农业学报,2010,22(1):77-80.
[6]季峻峰,陈骏,刘连文,等.黄土剖面中赤铁矿和针铁矿的定量分析与气候干湿变化研究[J].第四纪研究,2007,27(2):221-229.
[7]李丰义.黄土剖面中铁氧化物的特征及其成土环境的指示[D].武汉:华中农业大学,2011.
[8]李荣彪.长江中下游网纹红土中氧化铁矿物相及其气候环境意义[D].武汉:中国地质大学,2014.
[9]胡雪峰.黄土-古土壤序列中氧化铁和有机质对磁化率的影响[J].土壤学报,2004,41(1):7-12.
[10]李梦婕.腐殖酸、铁氧化物及其共存时对土壤汞赋存状态及生物活性的影响[D].重庆:西南大学,2012.
[11]CORNELL R M,SCHWERTMANN U.The iron oxides:structure,properties,reactions,occurrences and uses[M].Wiley-VCH,Weinheim:Germany,2003:345-363.
[12]邹雪华,陈天虎,张萍,等.天然针铁矿热处理产物的结构特征[J].硅酸盐学报,2013,41(10):1442-1446.
[13]CORNELL R M,SCHWERTMANN U.The iron oxides:structure,properties,reactions,occurrence and uses[M].Weinheim:VCⅡVerlagsgesellschaft,1996:573-579.
[14]K?MPF N,SCHWERTMANN U.Goethite and hematite in a climosequence in southern Brazil and their application in classification of kaolinitic soils[J].Geoderma,1983,29(1):27-39.
[15]TROLARD F,TARDY Y.The stabilities of gibbsite,boehmite,aluminous goethites and aluminous hematites in bauxites,ferricretes and laterites as a function of water activity,temperature and particle size[J].Geochimica et Cosmochimica Acta,1987,51(4):945-957.
[16]SCHWERTMANN U.Occurrence and formation of iron oxides in various pedoenvironments[M]//Iron in soils and clay minerals.Netherlands:Springer,1988:267-308.
[17]FISCHER W R,SCHWERTMANN U.The formation of hematite from amorphous iron(III)hydroxide[J].Clays and Clay Minerals,1975,23(1):33-37.
[18]SCHWERTMANN U.The effect of pedogenic environments on iron oxide minerals[M]//Advances in soil science.New York:Springer,1958:171-200.
[19]TORRENT J,SCHWERTMANN U,Schulze D G.Iron oxide mineralogy of some soils of two river terrace sequences in Spain[J].Geoderma,1980,23(3):191-208.
[20]WALKER T R.Formation of red beds in modern and ancient deserts[J].Geological Society of America Bulletin,1967,78(3):353-368.
[21]王小明.几种亚稳态铁氧化物的结构形成转化及其表面物理化学特性[D].武汉:华中农业大学,2015.
[22]BECHINE K,?UBRT J,HANSLIK T,et al.Transformation of syntheticγ-Fe OOH(lepidocrocite)in aqueous solutions of ferrous sulphate[J].Zeitschrift für anorganische und allgemeine Chemie,1982,489(1):186-196.
[23]OHTA S,EFFENDI S,TANAKA N,et al.Ultisols of lowland dipterocarp forest in East Kalimantan,Indonesia:III.clay minerals,free oxides,and exchangeable cations[J].Soil Science and Plant Nutrition,1993,39(1):1-12.
[24]范德江,陈彬,王亮,等.长江口外悬浮颗粒物中自生纤铁矿和胶黄铁矿[J].地球科学:中国地质大学学报,2014,39(10):1464-1469.
[25]SCHWERTMANN U,FITZPATRICK R W.Occurrence of lepidocrocite and its association with goethite in Natal soils[J].Soil Science Society of America Journal,1977,41(5):1013-1018.
[26]王小明,杨凯光,孙世发,等.水铁矿的结构、组成及环境地球化学行为[J].地学前缘,2011,18(2):339-347.
[27]SCHWERTMANN U,FISCHER W R.Natural“amorphous”ferric hydroxide[J].Geoderma,1973,10(3):237-247.
[28]CORNELL R M,SCHWERTMANN U.Influence of organic anions on the crystallization of ferrihydrite[J].Clays Clay Miner,1979,27(6):402-410.
[29]CHILDS C W.Ferrihydrite:A review of structure,properties and occurrence in relation to soils[J].Journal of Plant Nutrition and Soil Science,1992,155(5):441-448.
[30]CHUKHROV F V,ZVYAGIN B B,GORSHKOV A I,et al.Ferrihydrite[J].International Geology Review,1973,16:1131-1143.
[31]李学垣.土壤化学[M].北京:高等教育出版社,2001:1-402.
[32]BLAKEMORE R P.Magnetotactic bacteria[J].Science,1975,190(4212):377-379.
[33]Maher B A,Taylor R M.Formation of ultrafine-grained magnetite in soils[J].Nature,1988,336(6197):368-370.
[34]尧德中,俞劲炎,刘榜华.表土磁性增强现象的穆斯堡尔谱研究[J].土壤通报,1990,23(3):135-136.
[35]TAYLOR R M,SCHWERTMANN U.Maghemite in soils and Its origin I.properties and observations on soil maghemites[J].Clay Minerals,1974,10(4):289-298.
[36]FASSBINDER J W E,STANJEKT H,VALI H.Occurrence of magnetic bacteria in soil[J].Nature,1990,343(6254):161-163.
[37]刘秀铭,JOHN S,蒋建中,等.磁赤铁矿的几种类型与特点分析[J].中国科学:地球科学,2010,40(5):592-602.
[38]BARRN V,TORRENT J.Evidence for a simple pathway to maghemite in Earth and Mars soils[J].Geochimica et Cosmochimica Acta,2002,66(15):2801-2806.
[39]SCHWERTMANN U,FECHTER H.The influence of aluminum on iron oxides:XI.aluminum-substituted maghemite in soils and its formation[J].Soil Science Society of America Journal,1984,48(6):1462-1463.
[40]闫晓丽,杨一博,方小敏,等.临夏盆地晚中新世沉积物中赤铁矿和针铁矿的含量特征及其意义[J].兰州大学学报(自然科学版),2012,48(1):56-61.
[41]ZHANG Y G,JI J F,WILLIAM BALSAM,et al.High resolution hematite and goethite records from ODP 1143,South China Sea co-evolution of monsoonal precipitation and El Ni?o over the past 600,000years[J].Earth and Planetary Science Letters,2007,264(1-2):136-150.
[42]林伟伟,宋桂友.沉积物中X射线衍射物相定量分析中的两种方法对比研究[J].地球环境学报,2017,8(1):78-87.
[43]沈春玉,储刚.X射线衍射定量相分析新方法[J].分析测试学报,2003,22(6):80-82.
[44]BROWN G,WOOD I G.Estimation of iron oxides in soil clays by profile refinement combined with differential X-ray diffraction[J].Clay Minerals,1985,20(1):15-27.
[45]迟广成,肖刚,汪寅夫,等.铁矿石矿物组分的X射线粉晶衍射半定量分析[J].冶金分析,2015,35(1):38-44.
[46]郑国栋.基于穆斯堡尔谱技术的铁化学种及其在相关表生地球科学研究中的应用[J].矿物岩石地球化学通报,2008,27(2):161-167.
[47]卓文钦,吴新,赵长遂.基于穆斯堡尔谱的燃煤飞灰磁特性研究[J].中国电机工程学报,2010,30(20):65-70.
[48]张汉辉,韩勇,邢光熹.应用穆斯堡尔谱M?ssbauer_谱学方法研究燥红土中的氧化铁[J].土壤学报,1989,26(4):316-323.
[49]朱立军,李哲.碳酸盐岩红土中氧化铁矿物的穆斯堡尔谱学研究[J].贵州工学院学报,1996,25(5):34-38.
[50]商广凤.大气气溶胶中铁的溶解机制研究[D].上海:复旦大学,2013.
[51]JI J,BALSAM W,CHEN J.Mineralogic and climatic interpretationsoftheLuochuanloesssection(China)based on diffuse reflectance spectrophotometry[J].Quaternary Research,2001,56(1):23-30.
[52]李超,杨守业.长江沉积物中赤铁矿和针铁矿的漫反射光谱分析[J].地球科学:中国地质大学学报,2012(S1):11-19.
[53]周玮,季峻峰,陈骏.利用漫反射光谱鉴定红粘土中针铁矿和赤铁矿[J].高校地质学报,2007,13(4):730-736.
[54]盛阳.格尔木地区沙尘气溶胶理化特征及其来源分析[D].南京:南京师范大学,2015.
[55]王晶,陈震,陈国能.华南沿海末次冰期类黄土沉积的漫反射光谱与激光粒度研究[J].光谱学与光谱分析,2014,34(11):2901-2907.
[56]赵其国,杨浩.中国南方红土与第四纪环境变迁的初步研究[J].第四纪研究,1995,2:107-116.
[57]袁国栋,龚子同.第四纪红土的土壤发生及其古地理意义[J].土壤学报,1990,27(1):54-62.
[58]李小平,夏应菲,杨浩.安徽宣城第四纪红土剖面的全氧化铁含量及其古环境意义[J].江苏地质,1998,22(3):182-185.
[59]杨石岭,丁仲礼.7.0Ma以来中国北方风尘沉积的游离铁/全铁值变化及其古季风指示意义[J].科学通报,2000,45(2):2453-2456.
[60]郝振青,郭正堂.1.2Ma以来黄土-古土壤序列风化成壤强度的定量化研究与东亚夏季风演化[J].中国科学(D辑),2001,31(6):520-528.
[61]谢巧勤,陈天虎,孙玉兵,等.洛川黄土-古土壤序列铁氧化物组成及其古气候意义[J].矿物学报,2008,28(4):389-396.
[62]袁双.网纹红土铁形态特征与网纹红土形成环境[D].金华:浙江师范大学,2010.
[63]王思源.中国南方红土磁学特征、起源及其与成土过程关系研究[D].杭州:浙江大学,2014.