基于卟啉及其衍生物气体传感器的研究进展
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摘要
卟啉及其金属配合物具有较大的摩尔消光系数、较高的磷光密度以及较好的耐光性,是检测挥发性有机气体的潜在的气敏材料。将卟啉及其金属配合物敏感材料应用于环境中的VOCs的检测已有了深入并活跃的研究。该文将基于不同制造技术的卟啉传感器的分类及其工作原理进行了简要介绍,并在VOCs的检测领域及研究方向做了展望。
Porphyrins and metalloporphyrin complexes have a larger molar extinction coeffcient, higher phosphorescence density and better light fastness, is a potential gas-sensing material for the detection of volatile organic gases. The use of porphyrins and metalloporphyrin complexes for the detection of volatile organic compounds(VOCs) in the field of environment has been studied intensively. The classification and working principle of porphyrin sensors based on different manufacturing technologies are briefly introduced in this paper,and the field of detection and research status of VOCs are prospected.
Porphyrins and metalloporphyrin complexes have a larger molar extinction coeffcient, higher phosphorescence density and better light fastness, is a potential gas-sensing material for the detection of volatile organic gases. The use of porphyrins and metalloporphyrin complexes for the detection of volatile organic compounds(VOCs) in the field of environment has been studied intensively. The classification and working principle of porphyrin sensors based on different manufacturing technologies are briefly introduced in this paper,and the field of detection and research status of VOCs are prospected.
引文
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[2]Cai H,Gu Y,Sun Q.Effect Of Hematoporphyrin Monomethyl Ether-Mediated Photodynamic Therapy On Hypertrophic Scar Fibroblasts[J].Photodermatology Photoimmunology and Photomedicine,2011,27(2):90-96.
[3]Evyapan M,Dunbar A D F.Improving the Selectivity of a Free Base Tetraphenylporphyrin Based gas Sensor for NO2and Carboxylic Acid Vapors[J].Sens.Actuators,2015,74-83.
[4]Evyapan M,Dunbar A D F.Controlling surface adsorption to enhance the selectivity of porphyrin based gas sensors[J].Appl.Surf.Sci.,2016,191:362.
[5]Wang B,Zuo X,Wu Y Q,et al.Preparation,Characterization and Gas Sensing Properties of Lead Tetra-(tertbutyl)-5,10,15,20-tetraazaporphyrin Spin-coating Films[J].Sens.Actuator B,2007,1(25):268-273.
[6]Zuo X,Wang B,Wu Y Q.Effects of sensing temperature on the NO2-sensing properties of octa-iso-pentyloxymetallonaphthalocyanine spin-coated films[J].Sens.Actuator B.,2007,123(1):94-100.
[7]Xingfa M,Jingzhi S,Mang W,et al.Effects of Fluorination in the Ring of Zinc Tetraphenyl Porphyrin on Its Gas Response to Volatiles at Room Temperature[J].Sens.Actuator B,2006,114:1035-1042.
[8]Huixiang T,Mi Y,Xingfa M,et al.Gas sensing behavior of polyvinylpyrrolidone-modified Zn O nanoparticles for trimethylamine[J].Sen.Actuators B,2006,113(1):324-328.
[9]Bin W,Xia Z,Yiqun W,et al.Comparative gas sensing in copper porphyrin and copper phthalocyanine spin-coating films[J].Sens.Actuators B,2011,152:191-195.
[10]Marcus A,Martin H,Ingemar L,et al.Development of a Chem FET Sensor with Molecular Films of Porphyrins as Sensitive Layer[J].Sens.Actuator B,2001,77:567-571.
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[13]Daniel P,Marcello M,Valentina L,et al.Selection of peptide ligands for piezoelectric peptide based gas sensors arrays using a virtual screening approach[J].Biosens.Bioelectron.,2014,52(15):247-254.
[14]Zhong Q Z,Jun W Z,Qiao F H,et al.Enhanced Photoelectrochemical Performances of Graphene-basedcomposite Functionalized by Zn2+Tetraphenylporphyrin[J].Appl.Surf.Sci.,2014,321:404-411.
[15]Ding H,Victor E,Manoi K R,et al.A Physicalinsight into the Gas-sensing Properties of Copper(11)tetra-tertbutyl-5,10,15,20-tetraazaporphyrin Langnuir-Blodgett Films[J].Thin Solid Films,2000,379:279-286.
[16]Natale C D,Paolesse R,D’Amico A.Metalloporphyrinsbased artificial olfactory receptors[J].Sens.Actuators B,2007,121:238-246.
[17]Antonella M,Emanuela S,Roberto P,et al.Sorption and Condensation Phenomena of Volatile Compounds on Solid-state Metalloporphyrin Films[J].Sens.Actuator B,2007,124:260-268.
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[19]Corrado D N,Danio S,Roberto P,et al.Porphyrins Based Opto-electronic Nose for Volatile Compounds Detection[J].Sens.Actuator,2000,65:220-226.
[20]Tonezzer M,Maggioni G,Quaranta A,et al.Optical Sensing Properties of Co TPP Thin Films Deposited by Glow-discharge-induced Sublimation[J].Sens.Actuators B,2007,122:613-619.
[21]Bemini R,Tonezzer M,Mottola F,et al.Volatile Organic Compounds Detection Using Porphyrin Based Metalcladding Leaky Waveguides[J].Sens.Actuator B,2007,127:231-236.
[22]Palanisamy M,Abraham J.Optochemical Ammonia Gas Sensing Properties of Meso-substituted Porphyrin Derivatives Immobilized Nafion Film on Glass Slide[J].Sens.Actuators B,2012,174(43):74-80.
[23]姑力米然·吐尔地,艾尔肯·吐尔逊,阿曼古丽·图尔贡,等.四苯基卟啉锌薄膜/K+-交换玻璃光波导传感器检测挥发性有机化合物气体[J].应用化学,2015,32(2):232-238.
[24]姑力米热·吐尔地,帕提曼·尼扎木丁,燕音,等.四苯基卟啉薄膜/K+-交换玻璃光波导传感器的研制及其气敏性研究[J].传感技术学报,2016,29(7):966-970.
[25]Itoh K,Fujishima A.Highly sensitive flash photolysis with opticalwaveguides:photodepo-sition of silver onto particulate Ti O2from solution[J].J.Am.Chem.Soc.,1988,110(18):6267-6269.
[26]Sen A,Suslick K S.Shape-Selective Discrimination of Small Organic Molecules[J].Am.Chem.Soci.,2000,122:11565-11566.
[27]Suslick K S,Rakow N A,Sen A.Colorimetric Sensor Arrays for Molecular Recognition[J].Tetrahedron,2004,60:11133-l1138.
[28]Zhang C,Suslick K S.A Colorimetric Sensor Array for Organicsin Water[J].Am.Chem.Soci.,2005,127:11548-11549.
[29]Michael C Jn,Jennifer B P,Daniel P B,et al.Colorimetric Sensor Arrays for Volatile Organic Compounds[J].Anal.Chem.,2006,78:3591-3600.
[30]Sara N,Donato M,Coo'ado D,et al.Preparation and Characterization of Cobalt Porphyrin Modifiedtin Dioxide Films for Sensor Applications[J].Sens.Actuators B,2004,103:339-343.
[31]Elena G E,Rimma T K,Tat'yana A S,et al.Photophysics and Oxygen Sensing Properties of Tetraphenylporphyrin Lanthanide Complexes[J].Dye.Pigm.,2013,97?(1):209-214.
[32]Javier R,JoséM P,et al.Optical Detection of Amine Vapors Using Zntriad Porphyrin Thin Films[J].Sens.Actuator,2015,210:28-35.
[33]Yael Z,Yu C,Sameer R S.Dissolved Ammonia Sensing in Complex Mixtures Using Metalloporphyrin-based Optoelectronic Sensor and Spectroscopic Detection[J].Sens.Actuators B,2014,202(10):976-983.
[34]Rimeika R,Ricardas R,Vilius P,et al.Surface Acoustic Wave Interaction with Humidity-Sensitive TPPS4NanoStrip Stricture[J].Ultragnrsas Nr.,2006,58(1):13-15.
[2]Cai H,Gu Y,Sun Q.Effect Of Hematoporphyrin Monomethyl Ether-Mediated Photodynamic Therapy On Hypertrophic Scar Fibroblasts[J].Photodermatology Photoimmunology and Photomedicine,2011,27(2):90-96.
[3]Evyapan M,Dunbar A D F.Improving the Selectivity of a Free Base Tetraphenylporphyrin Based gas Sensor for NO2and Carboxylic Acid Vapors[J].Sens.Actuators,2015,74-83.
[4]Evyapan M,Dunbar A D F.Controlling surface adsorption to enhance the selectivity of porphyrin based gas sensors[J].Appl.Surf.Sci.,2016,191:362.
[5]Wang B,Zuo X,Wu Y Q,et al.Preparation,Characterization and Gas Sensing Properties of Lead Tetra-(tertbutyl)-5,10,15,20-tetraazaporphyrin Spin-coating Films[J].Sens.Actuator B,2007,1(25):268-273.
[6]Zuo X,Wang B,Wu Y Q.Effects of sensing temperature on the NO2-sensing properties of octa-iso-pentyloxymetallonaphthalocyanine spin-coated films[J].Sens.Actuator B.,2007,123(1):94-100.
[7]Xingfa M,Jingzhi S,Mang W,et al.Effects of Fluorination in the Ring of Zinc Tetraphenyl Porphyrin on Its Gas Response to Volatiles at Room Temperature[J].Sens.Actuator B,2006,114:1035-1042.
[8]Huixiang T,Mi Y,Xingfa M,et al.Gas sensing behavior of polyvinylpyrrolidone-modified Zn O nanoparticles for trimethylamine[J].Sen.Actuators B,2006,113(1):324-328.
[9]Bin W,Xia Z,Yiqun W,et al.Comparative gas sensing in copper porphyrin and copper phthalocyanine spin-coating films[J].Sens.Actuators B,2011,152:191-195.
[10]Marcus A,Martin H,Ingemar L,et al.Development of a Chem FET Sensor with Molecular Films of Porphyrins as Sensitive Layer[J].Sens.Actuator B,2001,77:567-571.
[11]Corrado D N,Roberto P,Alessandro M,et al.Kelvin Prove Investigation of Self-assembled-monolayers of Thiolderivatized Porphyrins Interacting with Volatile Compounds[J].Sens.Actuator,1998,48:368-372.
[12]Gabriele M,Yuvaraj S,Eugenio M,et al.The influence of film morphology and illumination conditions on the sensitivity of porphyrins-coated Zn O nanorods[J].Anal.Chim.Acta,2014,810(31):86-93.
[13]Daniel P,Marcello M,Valentina L,et al.Selection of peptide ligands for piezoelectric peptide based gas sensors arrays using a virtual screening approach[J].Biosens.Bioelectron.,2014,52(15):247-254.
[14]Zhong Q Z,Jun W Z,Qiao F H,et al.Enhanced Photoelectrochemical Performances of Graphene-basedcomposite Functionalized by Zn2+Tetraphenylporphyrin[J].Appl.Surf.Sci.,2014,321:404-411.
[15]Ding H,Victor E,Manoi K R,et al.A Physicalinsight into the Gas-sensing Properties of Copper(11)tetra-tertbutyl-5,10,15,20-tetraazaporphyrin Langnuir-Blodgett Films[J].Thin Solid Films,2000,379:279-286.
[16]Natale C D,Paolesse R,D’Amico A.Metalloporphyrinsbased artificial olfactory receptors[J].Sens.Actuators B,2007,121:238-246.
[17]Antonella M,Emanuela S,Roberto P,et al.Sorption and Condensation Phenomena of Volatile Compounds on Solid-state Metalloporphyrin Films[J].Sens.Actuator B,2007,124:260-268.
[18]Corrado D N,Roberto P,Antonella M,et al.Qualitative Structure-Sensitivity Relationship in Porphyrins Based QMB Chemical Sensors[J].Sens.Actuator B,2000,68:319-323.
[19]Corrado D N,Danio S,Roberto P,et al.Porphyrins Based Opto-electronic Nose for Volatile Compounds Detection[J].Sens.Actuator,2000,65:220-226.
[20]Tonezzer M,Maggioni G,Quaranta A,et al.Optical Sensing Properties of Co TPP Thin Films Deposited by Glow-discharge-induced Sublimation[J].Sens.Actuators B,2007,122:613-619.
[21]Bemini R,Tonezzer M,Mottola F,et al.Volatile Organic Compounds Detection Using Porphyrin Based Metalcladding Leaky Waveguides[J].Sens.Actuator B,2007,127:231-236.
[22]Palanisamy M,Abraham J.Optochemical Ammonia Gas Sensing Properties of Meso-substituted Porphyrin Derivatives Immobilized Nafion Film on Glass Slide[J].Sens.Actuators B,2012,174(43):74-80.
[23]姑力米然·吐尔地,艾尔肯·吐尔逊,阿曼古丽·图尔贡,等.四苯基卟啉锌薄膜/K+-交换玻璃光波导传感器检测挥发性有机化合物气体[J].应用化学,2015,32(2):232-238.
[24]姑力米热·吐尔地,帕提曼·尼扎木丁,燕音,等.四苯基卟啉薄膜/K+-交换玻璃光波导传感器的研制及其气敏性研究[J].传感技术学报,2016,29(7):966-970.
[25]Itoh K,Fujishima A.Highly sensitive flash photolysis with opticalwaveguides:photodepo-sition of silver onto particulate Ti O2from solution[J].J.Am.Chem.Soc.,1988,110(18):6267-6269.
[26]Sen A,Suslick K S.Shape-Selective Discrimination of Small Organic Molecules[J].Am.Chem.Soci.,2000,122:11565-11566.
[27]Suslick K S,Rakow N A,Sen A.Colorimetric Sensor Arrays for Molecular Recognition[J].Tetrahedron,2004,60:11133-l1138.
[28]Zhang C,Suslick K S.A Colorimetric Sensor Array for Organicsin Water[J].Am.Chem.Soci.,2005,127:11548-11549.
[29]Michael C Jn,Jennifer B P,Daniel P B,et al.Colorimetric Sensor Arrays for Volatile Organic Compounds[J].Anal.Chem.,2006,78:3591-3600.
[30]Sara N,Donato M,Coo'ado D,et al.Preparation and Characterization of Cobalt Porphyrin Modifiedtin Dioxide Films for Sensor Applications[J].Sens.Actuators B,2004,103:339-343.
[31]Elena G E,Rimma T K,Tat'yana A S,et al.Photophysics and Oxygen Sensing Properties of Tetraphenylporphyrin Lanthanide Complexes[J].Dye.Pigm.,2013,97?(1):209-214.
[32]Javier R,JoséM P,et al.Optical Detection of Amine Vapors Using Zntriad Porphyrin Thin Films[J].Sens.Actuator,2015,210:28-35.
[33]Yael Z,Yu C,Sameer R S.Dissolved Ammonia Sensing in Complex Mixtures Using Metalloporphyrin-based Optoelectronic Sensor and Spectroscopic Detection[J].Sens.Actuators B,2014,202(10):976-983.
[34]Rimeika R,Ricardas R,Vilius P,et al.Surface Acoustic Wave Interaction with Humidity-Sensitive TPPS4NanoStrip Stricture[J].Ultragnrsas Nr.,2006,58(1):13-15.