摘要
利用水热技术合成了一种keggin型杂多酸盐,对化合物C60H48N12Ni2GeMo12.Sb2O40进行X-射线单晶衍射、元素分析、红外光谱分析确定了该化合物的结构并对其进行表征.该化合物属于单斜晶系,P21/n空间群.化合物的晶胞参数:a=10. 707 (10) nm,b=16. 250(4) nm,c=16. 346 (17) nm,α=62. 85°,β=72. 38 (10)°,γ=74. 71°,V=2385. 4(13)3,Z=1,R=0. 1018,wR2=0. 3361.
A keggin-type heteropoly acid salt was synthesized by hydrothermal technique,The structure of C60 H48 N12 Ni2 GeMo12 Sb2 O40 was determined and characterized by X-ray single crystal diffraction,elemental analysis and infrared spectrum analysis. Compound crystallized in the Monoclinic orthogonal crystal system,space groupP21/n. Crystal cell parameters of compounds: a = 10. 707( 10) nm,b = 16. 250( 4) nm,c = 16. 346( 17) nm,α = 62. 85°,β = 72. 38( 10) °,γ = 74. 71°,V = 2385. 4( 13)3,Z = 1,R = 0. 1018,wR2=0. 3361.
引文
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