摘要
单分子磁体在量子计算、高密度存储材料以及分子自旋电子学等领域具有广阔的应用前景。3d过渡金属单离子磁体具有结构简单、易于研究磁构关系以及可控配体场获得高能垒等特点,因而成为近年来单分子磁体领域的研究热点。本文结合现有研究成果,从配位构型出发,旨在对近年来基于3d过渡金属离子的单离子磁体进行综述,重点阐述配体场、磁各向异性和单离子磁体性质三者之间的关系,为设计合成单分子磁体提供新的思路。
Single molecule magnets are potentially useful in quantum computing,high density data storage and molecular spintronics. 3 d transition-metal-based single-ion magnets have attracted intensive interest because their structures are simple,and it is easy to explore the magneto-structural relationship,and achieve the higher barriers by tunable ligand field. Unifying the domestic and foreign research situation,the paper will showan overall perspective of the present single-ion magnets( SIMs) based on the 3 d transition metal with the coordinated geometry,and highlight the relationship among the ligand field,the magnetic anisotropy and the behavior of single molecule magnet,which will provide a newroute for the syntheses of single molecule magnets.
引文
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