摘要
以特殊钢尾渣粉制备了特殊钢尾渣泡沫混凝土,并利用傅里叶变换红外光谱仪(FTIR)分析了养护过程各阶段的产物,测试了所制备混凝土的28d相关性能.结果表明:在养护过程前期(0~7d),特殊钢尾渣泡沫混凝土中的3CaO·SiO_2参与了水化反应;在养护过程后期(14~28d),特殊钢尾渣泡沫混凝土中的2CaO·SiO_2与吸附水作用,生成了C-S-H凝胶与Ca(OH)_2;养护龄期为28d的特殊钢尾渣泡沫混凝土具有较好的轻质性能和良好的力学性能,其干密度为627.69g/cm~3,抗压强度为2.671MPa,内照射指数I_(Ra)和外照射指数I_γ均为0.1,说明特殊钢尾渣粉应用的安全性得到了大幅提高.
Special steel tailing foam concrete was prepared from special steel tailing powder. Special steel tailing powder and products in different curing stages of special steel tailing foam concrete were measured by Fourier transform infrared spectroscopy(FTIR). Related performances of special steel tailing foam concrete(curing age is 28 d) were tested. The results show that the 3 CaO·SiO_2 reacts with special steel tailing foam concrete at the early stage of the curing process(0-7 d); 2 CaO·SiO_2 reacts with water absorbted in special steel tailing foam concrete, generating C-S-H gel and Ca(OH)_2 at the late stage of the curing process(14-28 d). Special steel tailing foam concrete(curing age is 28 d) has good light weight performance and good mechanical performance, at the same time, the safety of special steel tailings powder application is greatly improved. Its dry density is 627.69 g/cm~3, compressive strength is 2.671 MPa, internal exposure index I_(Ra) and external exposure index I_γ are 0.1.
引文
[1] HUNAITI Y M.Strength of composite sections with foamed and lightweight aggregate concrete[J].Journal of Materials in Civil Engineering,1997(5):60-62.
[2] CARLONE P,PALAZZO G S.A multi-scale non-deterministic approach to composite curing process simulation[J].Advanced Materials Research,2013,750-752:11-15.
[3] 张作顺,连芳,廖洪强,等.利用铁尾矿高温改性钢渣的性能[J].北京科技大学学报,2012,34(12):1379-1384.ZHANG Zuoshun,LIAN Fang,LIAO Hongqiang,et al.Modifying the properties of steel slag by iron tailings at high temperature[J].Journal of University of Science and Technology Beijing,2012,34(12):1379-1384.(in Chinese)
[4] AYDIN S,BARADAN B.Mechanical and microstructural properties of heat cured alkali-activated slag mortars[J].Materials and Design,2012,35:374-383.
[5] TSAKIRIDIS P E,PAPADIMITRIOU G D.Utilization of steel slag for Portland cement clinker production[J].Journal of Hazardous Materials,2008,152:805-811.
[6] 单俊鸿,邢振影,王军,等.脱硫渣用于加气混凝土生产的试验研究[J].河北工程大学学报(自然科学版),2010,27(1):29-32.SHAN Junhong,XING Zhenying,WANG Jun,et al.Experimental study of the desulfuration residue in aerated concrete[J].Journal of Heibei University of Engineering(Natural Science),2010,27(1):29-32.(in Chinese)
[7] JONES M R,MCARTHY A.Utilising unprocessed low-lime coal fly ash in foamed concrete[J].Science Direct,2005,84:1398-1409.
[8] LI G Q,MUTHYALA V D.A cement based syntactic foam[J].Materials Science Engineering A,2008,478:77-86.