海泡石功能化绿色建材研究进展与应用现状
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摘要
绿色建材是具有消磁、消声、调温、调湿、隔热、防火、抗静电等性能的新型功能化建筑材料,其注重人体健康与环保,是未来新型建材的重要发展方向。我国天然海泡石资源丰富,因其具有比表面积大、吸放湿性好、吸附性强、阻燃隔热、耐高温、抗盐以及流变性能好等优点,海泡石尤其适用于调湿材料、防火材料、空气净化材料、节能保温材料及水泥基材料。本文根据国内外海泡石建材的研究及应用现状,综述了海泡石的组成、产量、特性及其用于几种绿色建筑材料中的可行性和作用机理。同时,也提出了目前尚存在的问题,对海泡石在功能化绿色建材领域的合理应用具有较好的理论指导意义。
Green building materials are new functional building materials with degaussing, noise elimination,attemperation,humidity-controlling,heat insulation,fire resistance and antistatic property,they focus on human health and environmental protection and are important development direction of new materials in the future. Our country is rich in natural sepiolite resources, because it has many advantages,such as its large surface area,good moisture absorption and desorption,strong adsorption,flame retardant and heat insulation,high temperature resistance,salt tolerance and good rheological properties, sepiolite especially suitable for humidity-controlling material, fireproof material, air purification material,energy-saving insulation material and cement-based material and so on. According to the current research and application of sepiolite building materials at home and abroad,this paper summarizes the composition,yield,properties of sepiolite and feasibility and action mechanism of its application in several green building materials. At the same time,it also puts forward the existing problems,and has better theoretical guiding significance on reasonable application of sepiolite in functional green building materials.
Green building materials are new functional building materials with degaussing, noise elimination,attemperation,humidity-controlling,heat insulation,fire resistance and antistatic property,they focus on human health and environmental protection and are important development direction of new materials in the future. Our country is rich in natural sepiolite resources, because it has many advantages,such as its large surface area,good moisture absorption and desorption,strong adsorption,flame retardant and heat insulation,high temperature resistance,salt tolerance and good rheological properties, sepiolite especially suitable for humidity-controlling material, fireproof material, air purification material,energy-saving insulation material and cement-based material and so on. According to the current research and application of sepiolite building materials at home and abroad,this paper summarizes the composition,yield,properties of sepiolite and feasibility and action mechanism of its application in several green building materials. At the same time,it also puts forward the existing problems,and has better theoretical guiding significance on reasonable application of sepiolite in functional green building materials.
引文
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[4]冯秀娟,王海宁,普红平.改性海泡石在环境污染治理中的应用[J].环境污染治理技术与设备,2004,5(4):80-83.
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[6]韩炜,陈敬中,刘霞,等.纳米粘土矿物海泡石[J].矿产保护与利用,2003(6):19-25.
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[9]王汉青,易辉,李端茹,等.海泡石调湿涂料配制及调湿性能试验研究[J].建筑科学,2014,30(12):60-64.
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[20]Fouad L,Olivier P,Leila B,et al.Flame retardant polypropylene through the joint action of sepiolite and polyamide 6[J].Polymer Degradation and Stability,2013,98(10):1972-1980.
[21]吴娜,丁超,杨荣杰,等.海泡石对膨胀阻燃聚丙烯燃烧和热分解的影响[J].物理化学学报,2010,26(9):2429-2436.
[22]段晓东.建筑物用防火涂料的研究现状及进展[J].硅酸盐通报,2012,31(5):1190-1193.
[23]王国建,高堂铃,刘琳,等.海泡石对水性钢结构防火涂料性能的影响[J].建筑材料学报,2007,10(4):459-462.
[24]Bodzay B,Bocz K,Barkai Z,et al.Influence of Theological additives on char formation and fire resistance of intumescent coatings[J].Polymer Degradation and Stability,2011,96(3):355-362.
[25]杨守生.海泡石阻燃纸的研制[J].中国造纸学报,2005,20(1):153-155.
[26]Aldobenedetto Z,Anna B,Alfonso M,et al.Effect of sepiolite filler on mechanical behaviour of a bisphenol A-based epoxy system[J].Composites:Part B,2014,67:400-409.
[27]鲁旖,仇丹,章凯丽.海泡石吸附剂的应用研究进展[J].宁波工程学院学报,2016,28(1):17-21.
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[30]易文静,高小红.改性海泡石除甲醛净化剂的研制[J].科技创业月刊,2014,2:187-189.
[31]张韬,贺洋.海泡石环境吸附材料制备研究[J].非金属矿,2016,39(4):46-47.
[32]Erhong D,Jing H,Yu S,et al.Adsorption of styrene on the hydrothermal-modified sepiolite[J].Materials Letters,2013,111:150-153.
[33]Tuler F E,Portela R,Avila P,et al.Development of sepiolite/Si C porous catalytic filters for diesel soot abatement[J].Microporous and Mesoporous Materials,2016,230:11-19.
[34]屈小梭,宋贝,郑水林,等.海泡石的选矿提纯与精矿物化特性研究[J].非金属矿,2013,36(4):35-36.
[35]胡军.一种新型硅酸盐保温隔热涂料的研究[D].兰州:西北大学,2008.
[36]Alexandre B,Philippe D,Sheelagh L,et al.Preparation and properties of thermal insulation latex paint for exterior wall based on defibred sepiolite and hollow glass microspheres[J].Biofouling,2008,24(3-4):291-302.
[37]李文超,余剑英.海泡石纤维对玻化微珠保温材料性能的影响[J].新型建筑材料,2009(1):66-69.
[38]郑成,陈岚生,李璧宜,等.海泡石隔热保温涂料用于蚕茧烘炉的试验及效益分析(初报)[R].1992.
[39]彭吕元,唐先澧.海泡石保温隔热防水堵漏膏及用途:CN93115584.3[P].1995-03-31.
[40]强晓震.一种隔音加气混凝土砌块:中国,CN103467009A[P].2013-12-25.
[41]顾春林,孙宝珑.一种保温效果好的海泡石纤维混凝土加气砖:CN103936350A[P].2014-07-23.
[42]晋元龙,陈德全.一种海泡石粉混凝土加气砖及其制作方法:CN103833277A[P].2014-06-04.
[43]王立国,张树鹏,李东旭,等.纳米材料改性水泥基材料的研究应用进展[J].硅酸盐通报,2016,35(7):2128-2134.
[44]王镇龙,景镇子,单成冲,等.水热固化海泡石基黏土的研究[J].非金属矿,2011,34(1):6-10.
[45]Kavas T,Sabah E,Celik M S.Structural properties of sepiolite reinforced cement composite[J].Cement and Concrete Research,2004,34(11):2135-2139.
[46]Elena F,RocíO J,Ana M,et al.Effect of sepiolite on retention and drainage of suspensions of fibre-reinforced cement[J].Construction and Building Materials,2010,24(11):2117-2123.
[47]Hakime A,Ali R G,Amir T A.The compatibility of bentonite/sepiolite plastic concrete cut-off wall material[J].Construction and Building Materials,2016,124:1165-1173.
[48]Slavka A,Ana L,Fernando R,et al.Air lime-metakaolin-sepiolite mortars for earth based walls[J].Construction and Building Materials,2013,44(3):133-141.
[49]胡亚敏,刘德春,李秀云.海泡石纤维增强干混修补砂浆的研究[J].建材发展导向,2007(4):31-33.
[50]方明珠.一种抗裂混凝土及制备方法:CN104016621A[P].2014-09-03.
[2]陆现彩,尹琳,赵连泽,等.常见层状硅酸盐矿物的表面特征[J].硅酸盐学报,2003,31(1):60-65.
[3]李虹.海泡石资源的开发及利用[J].国外建材科技,1996,17(2):3-8.
[4]冯秀娟,王海宁,普红平.改性海泡石在环境污染治理中的应用[J].环境污染治理技术与设备,2004,5(4):80-83.
[5]张江凤,段星.海泡石的性能及其应用[J].中国非金属矿工业导刊,2009(4):19-22.
[6]韩炜,陈敬中,刘霞,等.纳米粘土矿物海泡石[J].矿产保护与利用,2003(6):19-25.
[7]Kok M V.Thermal characterization of sepiolite samples[J].Energy sources,Part A.Recovery,Utilization,and Environmental Effects,2013,35(1/4):173-183.
[8]Ahmed S,Afify M,Hassan M,et al.Elaboration and characterization of modified sepiolites and their humidity sensing features for environmental monitoring[J].Applied Clay Science,2015,115:165-173.
[9]王汉青,易辉,李端茹,等.海泡石调湿涂料配制及调湿性能试验研究[J].建筑科学,2014,30(12):60-64.
[10]洪苑秀,周斌强,郭立,等.海泡石水热合成C-S-H增强调湿建筑材料[J].新型建筑材料,2015,42(10):17-21.
[11]李国胜,梁金生,丁燕,等.海泡石矿物材料的纤维结构对其吸湿性能的影响[J].硅酸盐学报,2005,33(5):604-608.
[12]姜洪义,王一萍,万维新.沸石、硅藻土孔结构及调湿性能的研究[J].硅酸盐通报,2006,25(6):30-33.
[13]SuáR M,García-Rivas J,García-Romero E,et al.Mineralogical characterisation and surface properties of sepiolite from Polatli(Turkey)[J].Applied Clay Science,2016,131:124-130.
[14]蒋正武,曾志勇.酸化条件对海泡石调湿性能的影响[J].同济大学学报(自然科学版),2008,36(12):1674-1678.
[15]姜洪义,栾聪梅.改性海泡石粉体的孔结构与调湿性能[J].武汉理工大学学报,2010,32(5):9-11.
[16]邓妮.多孔矿物基复合调湿材料的制备与性能[D].杭州:浙江大学,2014.
[17]陈旬,袁利萍,胡云楚,等.聚磷酸铵和改性海泡石处理木材的阻燃抑烟作用[J].中南林业科技大学学报,2013,33(10):147-152.
[18]李少先,胡小平,王玉忠,等.阻燃化改性海泡石纤维的制备及其结构与性能[J].复合材料学报,2012,29(1):73-78.
[19]Aldobenedetto Z,Anna B,Mariarosaria R,et al.Effects of sepiolite clay on degradation and fire behavior of a bisphenol a-based epoxy[J].Composites:Part B,2015,73:139-148.
[20]Fouad L,Olivier P,Leila B,et al.Flame retardant polypropylene through the joint action of sepiolite and polyamide 6[J].Polymer Degradation and Stability,2013,98(10):1972-1980.
[21]吴娜,丁超,杨荣杰,等.海泡石对膨胀阻燃聚丙烯燃烧和热分解的影响[J].物理化学学报,2010,26(9):2429-2436.
[22]段晓东.建筑物用防火涂料的研究现状及进展[J].硅酸盐通报,2012,31(5):1190-1193.
[23]王国建,高堂铃,刘琳,等.海泡石对水性钢结构防火涂料性能的影响[J].建筑材料学报,2007,10(4):459-462.
[24]Bodzay B,Bocz K,Barkai Z,et al.Influence of Theological additives on char formation and fire resistance of intumescent coatings[J].Polymer Degradation and Stability,2011,96(3):355-362.
[25]杨守生.海泡石阻燃纸的研制[J].中国造纸学报,2005,20(1):153-155.
[26]Aldobenedetto Z,Anna B,Alfonso M,et al.Effect of sepiolite filler on mechanical behaviour of a bisphenol A-based epoxy system[J].Composites:Part B,2014,67:400-409.
[27]鲁旖,仇丹,章凯丽.海泡石吸附剂的应用研究进展[J].宁波工程学院学报,2016,28(1):17-21.
[28]崔国治,张高科.海泡石除臭剂研制[J].非金属矿,1990(3):24-25.
[29]丛丽娜,孟令国,刘明星,等.海泡石矿物的应用研究进展[J].中国资源综合利用,2008,26(6):9-11.
[30]易文静,高小红.改性海泡石除甲醛净化剂的研制[J].科技创业月刊,2014,2:187-189.
[31]张韬,贺洋.海泡石环境吸附材料制备研究[J].非金属矿,2016,39(4):46-47.
[32]Erhong D,Jing H,Yu S,et al.Adsorption of styrene on the hydrothermal-modified sepiolite[J].Materials Letters,2013,111:150-153.
[33]Tuler F E,Portela R,Avila P,et al.Development of sepiolite/Si C porous catalytic filters for diesel soot abatement[J].Microporous and Mesoporous Materials,2016,230:11-19.
[34]屈小梭,宋贝,郑水林,等.海泡石的选矿提纯与精矿物化特性研究[J].非金属矿,2013,36(4):35-36.
[35]胡军.一种新型硅酸盐保温隔热涂料的研究[D].兰州:西北大学,2008.
[36]Alexandre B,Philippe D,Sheelagh L,et al.Preparation and properties of thermal insulation latex paint for exterior wall based on defibred sepiolite and hollow glass microspheres[J].Biofouling,2008,24(3-4):291-302.
[37]李文超,余剑英.海泡石纤维对玻化微珠保温材料性能的影响[J].新型建筑材料,2009(1):66-69.
[38]郑成,陈岚生,李璧宜,等.海泡石隔热保温涂料用于蚕茧烘炉的试验及效益分析(初报)[R].1992.
[39]彭吕元,唐先澧.海泡石保温隔热防水堵漏膏及用途:CN93115584.3[P].1995-03-31.
[40]强晓震.一种隔音加气混凝土砌块:中国,CN103467009A[P].2013-12-25.
[41]顾春林,孙宝珑.一种保温效果好的海泡石纤维混凝土加气砖:CN103936350A[P].2014-07-23.
[42]晋元龙,陈德全.一种海泡石粉混凝土加气砖及其制作方法:CN103833277A[P].2014-06-04.
[43]王立国,张树鹏,李东旭,等.纳米材料改性水泥基材料的研究应用进展[J].硅酸盐通报,2016,35(7):2128-2134.
[44]王镇龙,景镇子,单成冲,等.水热固化海泡石基黏土的研究[J].非金属矿,2011,34(1):6-10.
[45]Kavas T,Sabah E,Celik M S.Structural properties of sepiolite reinforced cement composite[J].Cement and Concrete Research,2004,34(11):2135-2139.
[46]Elena F,RocíO J,Ana M,et al.Effect of sepiolite on retention and drainage of suspensions of fibre-reinforced cement[J].Construction and Building Materials,2010,24(11):2117-2123.
[47]Hakime A,Ali R G,Amir T A.The compatibility of bentonite/sepiolite plastic concrete cut-off wall material[J].Construction and Building Materials,2016,124:1165-1173.
[48]Slavka A,Ana L,Fernando R,et al.Air lime-metakaolin-sepiolite mortars for earth based walls[J].Construction and Building Materials,2013,44(3):133-141.
[49]胡亚敏,刘德春,李秀云.海泡石纤维增强干混修补砂浆的研究[J].建材发展导向,2007(4):31-33.
[50]方明珠.一种抗裂混凝土及制备方法:CN104016621A[P].2014-09-03.