石墨烯/聚合物功能化复合材料的研究进展
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摘要
石墨烯是一种具有二维结构的纳米碳材料,具有独特的物理性能,如比表面积大、导电导热性好、机械强度高等,因此在材料的轻质高强、导热、导电、电磁屏蔽等领域均备受关注。本文主要侧重介绍石墨烯/聚合物功能化复合材料的代表性研究成果,并对目前石墨烯复合材料的规模化应用进行评述,综合分析石墨烯/聚合物复合材料存在的关键问题及未来发展趋势。
Graphene is a kind of nanocarbon material with two-dimensional structure, which has unique physical properties, with largest specific surface area, excellent electrical conductivity, thermal conductivity and mechanical properties. Graphene becomes a study hot spot in the functional material, including lightweight and high strength material, heat conduction material, conductive material, and electromagnetic shielding material. This paper mainly focuses on the representative research achievements of graphene/polymer functional composites, and reviews on the large-scale application of graphene/polymer composites. Lastly, the key problems and the future development trend of graphene/polymer composites are comprehensively analyzed.
Graphene is a kind of nanocarbon material with two-dimensional structure, which has unique physical properties, with largest specific surface area, excellent electrical conductivity, thermal conductivity and mechanical properties. Graphene becomes a study hot spot in the functional material, including lightweight and high strength material, heat conduction material, conductive material, and electromagnetic shielding material. This paper mainly focuses on the representative research achievements of graphene/polymer functional composites, and reviews on the large-scale application of graphene/polymer composites. Lastly, the key problems and the future development trend of graphene/polymer composites are comprehensively analyzed.
引文
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[2]CHAE H K,SIBERIO-PEREZ D Y,KIM J,et a1.A route to high surface area,porosity and inclusion of large molecules in crystals[J].Nature,2004,427(6974):523-527.
[3]CHEN J H,JIANG C,XIAO S D,et al.Intrinsic and extrinsic performance limits of graphene devices on Si O2[J].Nat Nanotechnol,2008,3(4):206-209.
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[5]BALANDIN A A,GHOSH S,BAO W,et a1.Superior thermal conductivity of single-layer grapheme[J].Nano Lett,2008,8(3):902.
[6]STANKOVICH S,DIKIN D,DOMMETT G,et a1.Graphene-based composite materials[J].Nature,2006,442:282-286.
[7]DU J H,CHENG H M.The fabrication,properties,and uses of graphene/polymer composites[J].Macromol Chem Phys,2012,213(10/11):1060-1077.
[8]GREIL P.Perspectives of nano-carbon based engineering materials[J].Adv Eng Mater,2015,17(2):124-137.
[9]WANG X Z,LIU N,HU H,et al.Fabrication of three-dimensional Mo S2-graphene hybrid monoliths and their catalytic performance for hydrodesulfurization[J].New Carbon Mater,2014,29(2):81-88.
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[12]HU N T,WEI L M,WANG Y Y,et al.Graphene oxide reinforced polyimide nanocomposites via in situ polymerization[J].J Nanosci Nanotechnol,2012,12(1):173-178.
[13]ISTRATE O M,PATON K R,KHAN U,et al.Reinforcement in meltprocessed polymer-graphene composites at extremely low graphene loading level[J].Carbon,2014,78:243-249.
[14]WANG H,XIE G Y,YING Z,et al.Enhanced mechanical properties of multi-layer graphene filled poly(vinyl chloride)composite films[J].J Mater Sci Technol,2015,31(4):340-344.
[15]BASTWROS M,KIM G Y,ZHU C,et a1.Effect of ball milling on graphene reinforced Al6061 composite fabricated by semi-solid sintering[J].Compos Part B,2014,60:111-118.
[16]JEON C H,JEONG Y H,SEO J J,et a1.Material properties of graphene/aluminum metal matrix composites fabricated by friction stir processing[J].Int J Precis Eng Manuf,2014,15(6):1235-1239.
[17]AITHAL S.Business strategy for nanotechnology based products and services[J].Int J Manage Sci Bus Res,2016,5(4):139-149.
[18]BIAN J,LIN H L,HE F X,et al.Processing and assessment of high-performance poly(butylene terephthalate)nanocomposites reinforced with microwave exfoliated graphite oxide nanosheets[J].Eur Polym J,2013,49(6):1406-1423.
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[20]ZHAO X,ZHANG Q,CHEN D,et al.Enhanced mechanical properties of graphene-based poly(vinyl alcohol)composites[J].Macromolecules,2010,43(5):2357-2363.
[21]WANG H,XIE G,FANG M,et al.Electrical and mechanical properties of antistatic PVC films containing multi-layer graphene[J].Compos Part B-Eng,2015,79:444-450.
[22]ZANG J,RYU S,PUGNO N,et al.Multifunctionality and control of the crumpling and unfolding of large-area graphene[J].Nat Mater,2013,12(4):321-325.
[23]WANG H,XIE G Y,ZHU Z G,et al.Enhanced tribological performance of the multi-layer graphene filled poly(vinyl chloride)composites[J].Compos Part A-Appl Sci Manuf,2014,67:268-273.
[24]SHANG J,CHEN Y,ZHOU Y,et al.Effect of folded and crumpled morphologies of graphene oxide platelets on the mechanical performances of polymer nanocomposites[J].Polymer,2015,68:131-139.
[25]WANG H,XIE G,YANG C,et al.Enhanced toughness of multilayer graphene filled poly(vinyl chloride)composites preparedusing melt-mixing method[J].Polym Compos,2015,38(1):138-146.
[26]宁波材料所在石墨烯强韧化碳纤维复合材料关键技术研究中取得进展[J].新材料产业,2017(1):91-92.
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[30]LI M H,WAN Y Z,GAO Z F,et al.Preparation and properties of polyamide 6 thermal conductive composites reinforced with fibers[J].Mater Des,2013,51:257-261.
[31]NOH Y J,KIM S Y.Synergistic improvement of thermal conductivity in polymer composites filled with pitch based carbon fiber and graphene nanoplatelets[J].Polym Test,2015,45:l32-138.
[32]蔚永强,汪涛,朱亚林,等.双粒度A1N颗粒增强环氧树脂基复合材料导热性能数值模拟[J].塑料工业,2014,42(2):75-78.
[33]王超,周正发,徐卫兵.Al2O3/PP导热复合材料的制备与性能研究[J].塑料制造,2013(4):58-62.
[34]徐成杰,王家俊.氧化铝填充LLDPE复合材料的导热性能研究[J].浙江理工大学学报,2008,25(5):512-515.
[35]覃碧勋,唐敬海,柯金成,等.玻纤增强PPS/Mg O绝缘导热复合材料的研究[J].工程塑料应用,2008,36(9):l2-l4.
[36]张娜,杨刚,马连湘,等.改性氮化铝/三元乙丙橡胶复合材料导热性能和力学性能的研究[J].青岛科技大学学报(自然科学版),2014,35(2):182-186.
[37]DONNAY M,TZAVALAS S,LOGAKIS E.Boron nitride filled epoxy with improved thermal conductivity and dielectric break down strength[J].Compos Sci Technol,2015,110:152-158.
[38]李明,张凯,杨文彬,等.h-BN/Si Cw/聚砜导热绝缘复合材料的协同导热效应[J].高分子材料科学与工程,2015,31(4):73-77.
[39]韩毓旺,吕素敏,张毅.外加电场制备氮化硼-硅橡胶复合导热材料[J].化工新型材料,2010,38(12):75-76,112.
[40]冯乾军.高导热绝缘环氧树脂基复合材料的研究[D].杭州:浙江工业大学,2014.
[41]刘科,刘颖,吴大鸣,等.鳞片石墨取向对鳞片石墨/聚丙烯、鳞片石墨/尼龙66复合材料导热性能的影响[J].复合材料学报,2014,31(3):610-6 l6.
[42]ZHOU S,CHEN Y,ZOU H,et a1.Thermally conductive composites obtained by flake graphite filling immiscible polyamide 6/polyearbonate blends[J].Thermochim Acta,2013,566:84-91.
[43]刘俊峰,袁华,杜波,等.碳纳米管/导热硅脂复合材料的导热性能[J].材料科学与工程学报,2009,27(2):271-273.
[44]徐任信,单云刚,鲁学林,等.短切碳纤维/A1N/环氧树脂绝缘导热复合材料性能研究[J].绝缘材料,2008,41(3):33-36.
[45]ANNADURAI P,MALLICK A K,TRIPATHY D K.Studies on microwave shielding materials based on ferriteand carbon black-filled EPDM rubber in the X-band frequency[J].J Appl Polym Sci,2002,83(1):145-150.
[46]AL-SALEH M H,SUNDARARAJ U.Electromagnetic interference(EMI)shielding effectiveness of PP/PS polymer blends containing high structure carbon black[J].Macromol Mater Eng,2008,293(9):621-630.
[47]RAHAMAN M,CHAKI T K,KHASTGIR D.Electromagnetic interference(EMI)shielding effectiveness of PP/PS polymer blends containing high structure carbon black[J].J Mater Sci,2011,46(11):3989-3999.
[48]冯猛,曾敏,王新林.两种炭黑导电橡胶复合材料的电磁屏蔽性能[J].安全与电磁兼容,2011(6):65-66.
[49]NAYAK L,KHASTGIR D,CLAAKI T K.A mechanistic study on electromagnetic shielding effectiveness of polysulfone/carbon nanofibers nanocomposites[J].J Mater Sci,2013,48(4):1492-1502.
[50]何和智,杨彪,刘明彤.炭黑聚乙烯复合材料的电磁屏蔽性能[J].塑料,2010,39(3):43-47.
[51]程利.碳纳米管/硅橡胶复合电磁屏蔽材料的研制[D].南昌:南昌大学,2011.
[52]SALEH M H,SUNDARARAJ U.Electromagnetic interference shielding mechanisms of CNT/polymer composites[J].J Polym Sci Part B-Polym Phys,2012,50(19):1356-1362.
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