腐植酸螯合剂研究现状与应用前景
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摘要
从阻垢剂发展现状,对比传统氮磷阻垢剂新型阻垢剂的优势,腐植酸具有多种官能团,能够与Ca2+、Mg2+等金属进行络合、吸附,同时具有分散的特性。能够作为农业溶水肥助剂用于水肥一体化。从腐植酸类抗固化剂抗垢机理、发展趋势、腐植酸类抗固化剂的研究现状进行论述。未来针对性抗垢剂的研究将会得到越来越多的体现。
This paper starts from the development status of scale inhibitors,and compares the characteristics of traditional nitrogen and phosphorus scale inhibitors and new scale inhibitors. Humic acid has a variety of functional groups and can complex and adsorb with metals such as Ca2 +and Mg2 +,and has dispersed properties,as an agricultural soluble fertilizer additive will be a well choice. This article discusses the anti-fouling mechanism,development trend of humic acid anti-curing agents and research status of humic acid anticuring agents. In the future,the research of targeted anti-fouling agents will be increasingly reflected.
This paper starts from the development status of scale inhibitors,and compares the characteristics of traditional nitrogen and phosphorus scale inhibitors and new scale inhibitors. Humic acid has a variety of functional groups and can complex and adsorb with metals such as Ca2 +and Mg2 +,and has dispersed properties,as an agricultural soluble fertilizer additive will be a well choice. This article discusses the anti-fouling mechanism,development trend of humic acid anti-curing agents and research status of humic acid anticuring agents. In the future,the research of targeted anti-fouling agents will be increasingly reflected.
引文
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[8] Yang Lan,Yang Wenzhong,Xu Bin,et al. Synthesis and scale inhibition performance of a novel environmental friendly and hydrophilic terpolymer inhibitor[J]. Desalination,2017,416(15):166-174.
[9] Liu Yuan,Zou Changjun,Li Chaoqun,et al. Evaluation ofβ-cyclodextrin-polyethylene glycol as green scale inhibitors for produced-water in shale gas well[J]. Desalination,2016,377(1):28-33.
[10] Chauhana K,Kumara R,Kumar M,et al. Modified pectinbased polymers as green antiscalants for calcium sulfate scale inhibition[J]. Desalination,2012,305:31-37.
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[13]王曰鑫,李成学.绿色环保型腐植酸磷肥[M].北京:化学工业出版社,2009.
[14] Ewa L K. Humic substances,their microbial interactions and effects on biological transformations of organic pollutants in water and soil[J]. Chemosphere,2018,202:420-437.
[15] Canellas L P,Olivares F L,Aguiar N O,et al. Humic and fulvic acids as biostimulants in horticulture[J]. Scientia Horticulturae,2015,196(9):15-27.
[16] Steinberg C E W. Humic substances in the environment with an emphasis on freshwater systems[J]. Environmental Science and Pollution Research,2008,15(1):15-16.
[17] Perassia I,Borgnino L. Adsorption and surface precipitation of phosphate onto Ca CO3-montmorillonite:effect of p H,ionic strength and competition with humic acid[J].Geoderma,2014,232:600-608.
[18] Benecke J,rozova J,ernst M. Anti-scale effects of select organic macromolecules on gypsum bulk and surface crystallization during reverse osmosis desalination[J]. Separation and Purification Technology,2018,198:68-78.
[19] Murillo A T C,Dominguez A M. Precipitation control of calcium carbonate by humic matter,in cooling water systems[J]. Ingenieria Hidraulica En Mexico,2002,17(3):65-78.
[20]樊明明.腐植酸阻垢、分散和缓蚀性能及机理研究[D].太原:太原理工大学,2005.
[21] Gauthier G,Chao Y J,Horner O,et al. Application of the fast controlled precipitation method to assess the scaleforming ability of raw river waters[J]. Desalination,2012,299:89-95.
[22] Efrem C,Ji X S,Gianluca D P,et al. Membrane distillation operated at high seawater concentration factors:Role of the membrane on Ca CO3scaling in presence of humic acid[J]. Journal of Membrane Science,2009,346(2):263-269.
[23] Park C M,Han J H,Chu K H. Influence of solution p H,ionic strength,and humic acid on cadmium adsorption onto activated biochar[J]. Journal of Industrial and Engineering Chemistry,2017,48:186-193.
[24] Alvarez-Puebla R A,Garrido J J. Effect of p H on the aggregation of a gray humic acid in colloidal and solid states[J]. Chemosphere,2005,59(5):659-667.
[25]邱广明,邱广亮.改性腐植酸新型阻垢缓蚀剂的制备及应用[J].水处理技术,2002,28(2):112-114.
[26] Hao Y,Moriva A,Maruyama T,et al. Effect of metal ions on humic acid fouling of hollow fiber ultrafiltration membrane[J]. Journal of Membrane Science,2011,376(1):247-253.
[27] Zhu J,Li M,Whelan M. Phosphorus activators contribute to legacy phosphorus availability inagricultural soils[J].Science of the Total Environment,2018,612:522-537.
[2] Borowiec M,Huculak M,Hoffmann K,et al. Biodegradation of selected substances used in liquid fertilizers as an element of Life Cycle Assessment[J]. Polish Journal of Chemical Technology,2009,11(1):1-3.
[3] Knepper T P. Synthetic chelating agents and compounds exhibiting complexing properties in the aquatic environment[J]. Tr AC Trends in Analytical Chemistry,2003,22(10):708-724.
[4] Bretti C,Majlesi K,Stefano C D,et al. Thermodynamic study on the protonation and complexation of GLDA with Ca2+and Mg2+at different ionic strengths and ionic media at 298. 15 K[J]. Journal of Chemical&Engineering Data,2016,61(5):1895-1903.
[5] Chaussemier M,Pourmohtasham E,Gelus D,et al. State of art of natural inhibitors of calcium carbonate scaling. A review article[J]. Desalination,2015,356(10):47-55.
[6] Ginkel C G V,Geerts R,Nguyen P D. Biodegradation of L-glutamatediacetate by mixed cultures and an isolate[J]. Acs Symposium,2005,910:183-194.
[7] Huculak M,Borowiec M,Skut J,et al. Study on the aerobic biodegradation of chelating agents in water under the static conditions[C]∥In Proc. 18th Annual Central European Conference ECOpole 2009. Piechowice:Proceedings of Ecopole Press,2009.
[8] Yang Lan,Yang Wenzhong,Xu Bin,et al. Synthesis and scale inhibition performance of a novel environmental friendly and hydrophilic terpolymer inhibitor[J]. Desalination,2017,416(15):166-174.
[9] Liu Yuan,Zou Changjun,Li Chaoqun,et al. Evaluation ofβ-cyclodextrin-polyethylene glycol as green scale inhibitors for produced-water in shale gas well[J]. Desalination,2016,377(1):28-33.
[10] Chauhana K,Kumara R,Kumar M,et al. Modified pectinbased polymers as green antiscalants for calcium sulfate scale inhibition[J]. Desalination,2012,305:31-37.
[11] Thurman E M. Aquatic Humic Substances Organic Geochemistry of Natural Waters[M]. USA:United States Geological Survey,1985:273-361.
[12] Opsahl S,Benner R. Distribution and cycling of terrigenous dissolved organic matter in the ocean[J]. Nature,1997,386(6624):480-482.
[13]王曰鑫,李成学.绿色环保型腐植酸磷肥[M].北京:化学工业出版社,2009.
[14] Ewa L K. Humic substances,their microbial interactions and effects on biological transformations of organic pollutants in water and soil[J]. Chemosphere,2018,202:420-437.
[15] Canellas L P,Olivares F L,Aguiar N O,et al. Humic and fulvic acids as biostimulants in horticulture[J]. Scientia Horticulturae,2015,196(9):15-27.
[16] Steinberg C E W. Humic substances in the environment with an emphasis on freshwater systems[J]. Environmental Science and Pollution Research,2008,15(1):15-16.
[17] Perassia I,Borgnino L. Adsorption and surface precipitation of phosphate onto Ca CO3-montmorillonite:effect of p H,ionic strength and competition with humic acid[J].Geoderma,2014,232:600-608.
[18] Benecke J,rozova J,ernst M. Anti-scale effects of select organic macromolecules on gypsum bulk and surface crystallization during reverse osmosis desalination[J]. Separation and Purification Technology,2018,198:68-78.
[19] Murillo A T C,Dominguez A M. Precipitation control of calcium carbonate by humic matter,in cooling water systems[J]. Ingenieria Hidraulica En Mexico,2002,17(3):65-78.
[20]樊明明.腐植酸阻垢、分散和缓蚀性能及机理研究[D].太原:太原理工大学,2005.
[21] Gauthier G,Chao Y J,Horner O,et al. Application of the fast controlled precipitation method to assess the scaleforming ability of raw river waters[J]. Desalination,2012,299:89-95.
[22] Efrem C,Ji X S,Gianluca D P,et al. Membrane distillation operated at high seawater concentration factors:Role of the membrane on Ca CO3scaling in presence of humic acid[J]. Journal of Membrane Science,2009,346(2):263-269.
[23] Park C M,Han J H,Chu K H. Influence of solution p H,ionic strength,and humic acid on cadmium adsorption onto activated biochar[J]. Journal of Industrial and Engineering Chemistry,2017,48:186-193.
[24] Alvarez-Puebla R A,Garrido J J. Effect of p H on the aggregation of a gray humic acid in colloidal and solid states[J]. Chemosphere,2005,59(5):659-667.
[25]邱广明,邱广亮.改性腐植酸新型阻垢缓蚀剂的制备及应用[J].水处理技术,2002,28(2):112-114.
[26] Hao Y,Moriva A,Maruyama T,et al. Effect of metal ions on humic acid fouling of hollow fiber ultrafiltration membrane[J]. Journal of Membrane Science,2011,376(1):247-253.
[27] Zhu J,Li M,Whelan M. Phosphorus activators contribute to legacy phosphorus availability inagricultural soils[J].Science of the Total Environment,2018,612:522-537.