进口葡萄酒相关农药污染物的筛查及其本底值的定量分析
|
摘要
应用静电场轨道阱高分辨液相色谱质谱联用仪筛查葡萄酒相关的145种农药残留,确定出42种葡萄酒中常见污染物。采用液相色谱-串联质谱(LC-MS-MS)对黄埔口岸采集的318个进口葡萄酒样品进行该类污染物的本底值测定。分析讨论发现,近76%的样品中检出2~8种农药残留,多数进口葡萄酒中农药残留的种类集中在5种(检出率为13.52%)。检出农药残留含量在0.02~392.5μg/kg之间,样品检出率高达94.65%,说明进口葡萄酒中农药残留普遍存在。
145 kinds of wine-related pesticides residue were screened by Q-Exactive high-resolution mass spectrometer and 42 kinds of common pollutants were found to occur in wine. 318 imported grape wine samples from Huangpu entry port were analyzed by LC-MS-MS for these 42 kinds of pesticide residues. The results suggested that 2- 8 kinds of pesticides were detected over 76% of those wine samples,and 5 kinds of pesticides were found in most of them with detection rate of 13. 52%. Concentrations of detected pesticides ranged between 0. 02- 392. 5 μg/kg and the overall sample detection rate was high up to 94. 65%,which suggested the wide spread presence of pesticide residues in imported wine.
145 kinds of wine-related pesticides residue were screened by Q-Exactive high-resolution mass spectrometer and 42 kinds of common pollutants were found to occur in wine. 318 imported grape wine samples from Huangpu entry port were analyzed by LC-MS-MS for these 42 kinds of pesticide residues. The results suggested that 2- 8 kinds of pesticides were detected over 76% of those wine samples,and 5 kinds of pesticides were found in most of them with detection rate of 13. 52%. Concentrations of detected pesticides ranged between 0. 02- 392. 5 μg/kg and the overall sample detection rate was high up to 94. 65%,which suggested the wide spread presence of pesticide residues in imported wine.
引文
[1]International Organisation of Vine and Wine.Statistical Report on World Vitiviniculture[R].Paris OIV,2014.
[2]贺普超.葡萄学[M].北京:中国农业出版社,1999:348.
[3]张立功,李丙智.葡萄常见病虫害防治农药[J].西北园艺,2006(4):33-34.
[4]郭晶晶,朱克卫,田玲等.葡萄酒酿造过程中农药残留的变化[J].中国酿造,2015,34(6):19-24.
[5]王玉路,王宗义,贾昌喜,等.葡萄酒酿造过程中12种残留杀菌剂的归趋追踪[J].食品与发酵工业,2016,42(3):114-118.
[6]BAJVA U,SANDHU,K S.Effect of handling and processing on pesticide residues in food-a review[J].Journal of Food Science and Technology-Mysore,2014,51(2):201-220.
[7]STOYCTHEVA M.Pesticides:formulation,effects,fate[M].Greece:In Tech,2011:575-594.
[8]国家卫生和计划生育委员会,农业部.GB 2763—2014食品中农药最大残留限量[S].北京:中国标准出版社,2014.
[9]United States Department of Agriculture,Foreign Agricultural Service,Pesticide MRL Database[R/OL].http://www.Mrldata-base.com
[10]Australian Pesticides and Veterinary Medicines Authority.The MRL Standard Maximum Residue Limits in Food and Animal Feedstuff[R/OL].http://www.justice.gc.ca/eng/index.html
[11]Food Standards Australia New Zealand.FSANZ Regulatory Plan[R/OL].[2009-07-09].http://www.foodstandards.gov.au
[12]Minister of Health Canada.Pest Control Products Act.EMRL2008-01 Maximum Residue Limits for Pesticides[S].Ottawa,Pest Management Regulatory Agency,2008
[13]Codex Alimentarius Commission.Codex Committee On Pesticide Residues.Maximum Residue Limits(MRLs)for Pesticides[S/OL].CAC/MRL1 http://www.fao.org/fao-who-codex alimentarius/standards/pestres/pesticides/en/
[14]European Parliament,Council,Regulation,EC:149/2008[S].Official Journal of the European Union,2008.
[15]中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.GB/T 23206—2008果蔬汁、果酒中512种农药及相关化学品残留量的测定液相色谱-质谱法[S].北京:中国标准出版社,2007.
[16]ANASASIOS E,HELEN B,SPYROS A,et al.Determination of multi-class pesticides in wines by solid-phase extraction and liquid chromatography-tandem mass spectrometry[J].Journal of Chromatography A,2009,1216(31)5 856-5 867.
[17]FEDOROVA G,RANDAK T,LINDERG R H,et al.Comparison of the quantitative performance of a Q-Exactive high-resolution mass spectrometer with that of a triple quadrupole tandem mass spectrometer for the analysis of illicit drugs in wastewater[J].Rapid Commun Mass Spectrom,2013,27(15):1 751-1 762.
[18]中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会GB/T 27404—2008实验室质量控制规范食品理化检测[S].北京:中国标准出版社,2008.
[19]ALBERTO A,FABRIZIO D.Three years monitoring survey of pesticide residues in Sardinia wines following integrated pest management strategies[J].Environ Monit Assess,2013,185(5):4 281-4 289.
[2]贺普超.葡萄学[M].北京:中国农业出版社,1999:348.
[3]张立功,李丙智.葡萄常见病虫害防治农药[J].西北园艺,2006(4):33-34.
[4]郭晶晶,朱克卫,田玲等.葡萄酒酿造过程中农药残留的变化[J].中国酿造,2015,34(6):19-24.
[5]王玉路,王宗义,贾昌喜,等.葡萄酒酿造过程中12种残留杀菌剂的归趋追踪[J].食品与发酵工业,2016,42(3):114-118.
[6]BAJVA U,SANDHU,K S.Effect of handling and processing on pesticide residues in food-a review[J].Journal of Food Science and Technology-Mysore,2014,51(2):201-220.
[7]STOYCTHEVA M.Pesticides:formulation,effects,fate[M].Greece:In Tech,2011:575-594.
[8]国家卫生和计划生育委员会,农业部.GB 2763—2014食品中农药最大残留限量[S].北京:中国标准出版社,2014.
[9]United States Department of Agriculture,Foreign Agricultural Service,Pesticide MRL Database[R/OL].http://www.Mrldata-base.com
[10]Australian Pesticides and Veterinary Medicines Authority.The MRL Standard Maximum Residue Limits in Food and Animal Feedstuff[R/OL].http://www.justice.gc.ca/eng/index.html
[11]Food Standards Australia New Zealand.FSANZ Regulatory Plan[R/OL].[2009-07-09].http://www.foodstandards.gov.au
[12]Minister of Health Canada.Pest Control Products Act.EMRL2008-01 Maximum Residue Limits for Pesticides[S].Ottawa,Pest Management Regulatory Agency,2008
[13]Codex Alimentarius Commission.Codex Committee On Pesticide Residues.Maximum Residue Limits(MRLs)for Pesticides[S/OL].CAC/MRL1 http://www.fao.org/fao-who-codex alimentarius/standards/pestres/pesticides/en/
[14]European Parliament,Council,Regulation,EC:149/2008[S].Official Journal of the European Union,2008.
[15]中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.GB/T 23206—2008果蔬汁、果酒中512种农药及相关化学品残留量的测定液相色谱-质谱法[S].北京:中国标准出版社,2007.
[16]ANASASIOS E,HELEN B,SPYROS A,et al.Determination of multi-class pesticides in wines by solid-phase extraction and liquid chromatography-tandem mass spectrometry[J].Journal of Chromatography A,2009,1216(31)5 856-5 867.
[17]FEDOROVA G,RANDAK T,LINDERG R H,et al.Comparison of the quantitative performance of a Q-Exactive high-resolution mass spectrometer with that of a triple quadrupole tandem mass spectrometer for the analysis of illicit drugs in wastewater[J].Rapid Commun Mass Spectrom,2013,27(15):1 751-1 762.
[18]中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会GB/T 27404—2008实验室质量控制规范食品理化检测[S].北京:中国标准出版社,2008.
[19]ALBERTO A,FABRIZIO D.Three years monitoring survey of pesticide residues in Sardinia wines following integrated pest management strategies[J].Environ Monit Assess,2013,185(5):4 281-4 289.