无溶剂锌粉促进下三组分“一锅法”合成1,2-二芳基乙酯
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摘要
在锌粉的促进下,以芳香醛、溴化苄和酸酐为原料,在无溶剂条件下三组分"一锅法"反应合成了一系列1,2-二芳基乙酯类化合物.该方法具有反应条件温和、操作简单、产率高、原料易得、反应迅速的特点,为合成1,2-二芳基乙酯类化合物提供了一种"绿色"、方便的方法.
A series of 1,2-diaryl acetates were synthesized by one-pot three-component reaction of aromatic aldehydes, benzyl bromide and anhydrides promoted by zinc powder under solvent-free conditions. This protocol has advantages of mild conditions, simple operation, high yields, easily available starting materials and fast reaction rate, which provides a convenient and "green" method for the synthesis of 1,2-diaryl acetates.
A series of 1,2-diaryl acetates were synthesized by one-pot three-component reaction of aromatic aldehydes, benzyl bromide and anhydrides promoted by zinc powder under solvent-free conditions. This protocol has advantages of mild conditions, simple operation, high yields, easily available starting materials and fast reaction rate, which provides a convenient and "green" method for the synthesis of 1,2-diaryl acetates.
引文
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[7]Chakraborty,S.;Krause,J.-A.;Guan,H.Organometallics 2009,28,582.
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