Treatment of hydroxyquinone-containing wastewater using precipitation method with barium salt
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摘要
Hydroxyquinone compounds, such as 1,4-dihydroxyanthraquinone and alizarin sulfonate, are widely used in dye manufacturing, pharmaceutical manufacturing, and other industries. However, the treatment of hydroxyquinone-containing wastewater has seldom been examined. This study used a precipitation method with barium salt to treat nano-silver industrial wastewater. The results show that barium chloride was a suitable reagent for significantly degrading COD and color from nano-silver wastewater. When the initial pH value was 10.5, 8 g of BaCl_2·2 H_2 O were added to 100 mL of wastewater. After reaction at 15℃ for 1 h, the removal efficiencies of COD and color in the nano-silver wastewater were 85.6% and 97.1%, respectively. Simulated wastewater containing sodium alizarin-3-sulfonate(ARS) or purpurin was used to further investigate the removal mechanism of hydroxyquinone compounds. Fourier transform infrared spectroscopy, X-ray diffraction, and some related experiments showed that hydroxyquinone compounds can directly react with barium ions in the solution so as to transfer from wastewater to precipitate. In addition, the newly produced barium sulfate particles have positive surface charges, which can improve the removal efficiency of hydroxyquinone compounds due to electrostatic attraction.
Hydroxyquinone compounds, such as 1,4-dihydroxyanthraquinone and alizarin sulfonate, are widely used in dye manufacturing, pharmaceutical manufacturing, and other industries. However, the treatment of hydroxyquinone-containing wastewater has seldom been examined. This study used a precipitation method with barium salt to treat nano-silver industrial wastewater. The results show that barium chloride was a suitable reagent for significantly degrading COD and color from nano-silver wastewater. When the initial pH value was 10.5, 8 g of BaCl_2·2 H_2 O were added to 100 mL of wastewater. After reaction at 15℃ for 1 h, the removal efficiencies of COD and color in the nano-silver wastewater were 85.6% and 97.1%, respectively. Simulated wastewater containing sodium alizarin-3-sulfonate(ARS) or purpurin was used to further investigate the removal mechanism of hydroxyquinone compounds. Fourier transform infrared spectroscopy, X-ray diffraction, and some related experiments showed that hydroxyquinone compounds can directly react with barium ions in the solution so as to transfer from wastewater to precipitate. In addition, the newly produced barium sulfate particles have positive surface charges, which can improve the removal efficiency of hydroxyquinone compounds due to electrostatic attraction.
Hydroxyquinone compounds, such as 1,4-dihydroxyanthraquinone and alizarin sulfonate, are widely used in dye manufacturing, pharmaceutical manufacturing, and other industries. However, the treatment of hydroxyquinone-containing wastewater has seldom been examined. This study used a precipitation method with barium salt to treat nano-silver industrial wastewater. The results show that barium chloride was a suitable reagent for significantly degrading COD and color from nano-silver wastewater. When the initial pH value was 10.5, 8 g of BaCl_2·2 H_2 O were added to 100 mL of wastewater. After reaction at 15℃ for 1 h, the removal efficiencies of COD and color in the nano-silver wastewater were 85.6% and 97.1%, respectively. Simulated wastewater containing sodium alizarin-3-sulfonate(ARS) or purpurin was used to further investigate the removal mechanism of hydroxyquinone compounds. Fourier transform infrared spectroscopy, X-ray diffraction, and some related experiments showed that hydroxyquinone compounds can directly react with barium ions in the solution so as to transfer from wastewater to precipitate. In addition, the newly produced barium sulfate particles have positive surface charges, which can improve the removal efficiency of hydroxyquinone compounds due to electrostatic attraction.
引文
Anjaneyulu, Y., Chary, N.S., Raj, D.S.S., 2005. Decolourization of industrial effluents-available methods and emerging technologies:A review. Rev.Environ. Sci. Biotechnol. 4(4), 245-273. https://doi.org/10.1007/s11157-005-1246-z.
Ayed, L., Mahdhi, A., Cheref, A., Bakhrouf, A., 2011. Decolorization and degradation of azo dye Methyl Red by an isolated Sphingomonas paucimobilis:Biotoxicity and metabolites characterization. Desalination274(1-3), 272-277. https://doi.org/10.1016/j.desal.2011.02.024.
Bilinska, L., Gmurek, M., Ledakowicz, S., 2016. Comparison between industrial and simulated textile wastewater treatment by AOPs:Biodegradability, toxicity and cost assessment. Chem. Eng. J. 306, 550-559. https://doi.org/10.1016/j.cej.2016.07.100.
Cai, L., Xu, T., Shen, J.Y., Xiang, W.X., 2015. Highly efficient photocatalytic treatment of mixed dyes wastewater via visible-light-driven AgI-Ag3P04/MWCNTs. Mater. Sci. Semicond. Process. 37, 19-28. https://doi.org/10.1016/j.mssp.2014.12.064.
Fang, Z.D., Zhang, K., Liu, J., Fan, J.Y., Zhao, Z.W., 2017. Fenton-like oxidation of azo dye in aqueous solution using magnetic Fe_3O_4-MnO_2nanocomposites as catalysts. Water Sci. Eng. 11(1), 17-22. https://doi.org/10.1016/j.wse.2017.10.005.
Furkan, M., Alama, M.T., Rizvi, A., Khana, K., Naeem, A., 2017. Aloe emodin, an anthroquinone from Aloe vera acts as an anti aggregatory agent to the thermally aggregated hemoglobin. Spectrochim. Acta Part A Mol.Biomol. Spectrosc. 179, 188-193. https://doi.org/10.1016/j.saa.2017.02.014.
Ge, Y.Z., Jin, H., 1995. Recovery of phenols from coal tar and waste water by precipitation. J. China Coal Soc. 5, 545-550(in Chinese).
Holkar, C.R., Pandit, A.B., Pinjari, D.V., 2014. Kinetics of biological decolorisation of anthraquinone based Reactive Blue 19 using an isolated strain of Enterobacter sp. F NCIM 5545. Bioresour. Technol. 173, 342-351.https://doi.org/10.1016/j.biortech.2014.09.108.
Huma, H., Qaisar, M., Arshid, P., Zulfiqar, A.B., Shams, A.B., 2015.Comparative decolorization of dyes in textile wastewater using biological and chemical treatment. Sep. Purif. Technol. 154, 149-153. https://doi.org/10.1016/j.seppur.2015.09.025.
Kim, K.H., Ihm, S.K., 2011. Heterogeneous catalytic wet air oxidation of refractory organic pollutants in industrial wastewaters:A review. J. Hazard Mater. 186. 16-34. https://doi.org/10.1016/j.jhazmat.2010.11.011.
Lemlikchi, W., Sharrock, P., Fiallo, M., Nzihouc, A., Mecherria, M.O., 2014.Hydroxyapatite and Alizarin sulfonate ARS modeling interactions for textile dyes removal from wastewaters. Proc. Eng. 83, 378-385. https://doi.org/10.1016/j.proeng.2014.09.032.
Li, H.Y., Liu, S.Y., Zhao, J.H., Feng, N., 2016. Removal of reactive dyes from wastewater assisted with kaolin clay by magnesium hydroxide coagulation process. Colloid. Surf. A Physicochem. Eng. Asp. 494, 222-227. https://doi.org/10.1016/j.colsurfa.2016.01.048.
Li, M.L., Zhou, Y.S., Ji, S., 2010. Preparation and microstructure of silver nanopowder with spheric morphology. Ordnance Mater. Sci. Eng. 33, 1-3(in Chinese).
Li, T.. Ma, G.H., Peng, T.J., 2015. Mechanism of preparing spherical nanosized silver particles via o-phenylenediamine reduction process in waterNMPD mixed solution system. Rare Metal Mater. Eng. 44(5),1071-1074. https://doi.org/10.1016/S1875-5372(15)30069-2.
Liang, C.Z., Sun, S.P., Li, F.Y., Ong, Y.K., Chung, T.S., 2014. Treatment of highly concentrated wastewater containing multiple synthetic dyes by a combined process of coagulation/flocculation and nanofiltration. J. Membr.Sci. 469. 306-315. https://doi.org/10.1016/j.memsci.2014.06.057.
Marletta, A., Nascimento, N.D., Eiras, S.P., Andrade, A.A., Pilla, V.P.,Cruz, W.O., 2017. Synthesis optimization of guest/host poly(styrenesulphonate)doped neodymium(III)films. J. Non Cryst. Solids 456, 1-6.https://doi.org/10.1016/j.jnoncrysol.2016.10.034.
Misra, D.N., 1992. Reaction of alizarin red S with hydroxyapatite:Stoichiometry and surface effect. Colloids Surf. 66(3), 181-187. https://doi.org/10.1016/0166-6622(92)80191-4.
Moriguchi, T., Yano, K., Nakagawa, S., Kaji, F., 2003. Elucidation of adsorption mechanism of bone-staining agent alizarin red S on hydroxyapatite by FT-IR microspectroscopy. J. Colloid Interface Sci. 260(1),19-25. https://doi.org/10.1016/S0021-9797(02)00157-1.
Paz, A., Carballo, J., Perez, M.J., Dominguez, J.M., 2017. Biological treatment of model dyes and textile wastewaters. Chemosphere 181, 168-177.https://doi.org/10.1016/j.chemosphere.2017.04.046.
Rosenkranz, F., Cabrol, L., Carballa, M., 2013. Relationship between phenol degradation efficiency and microbial community structure in an anaerobic SBR. Wat. Res. 47(17), 6739-6749. https://doi.org/10.1016/j.watres.2013.09.004.
Song, H.Y., You, J.A., Chen, C.X., Zhang, H., Ji, X.Z., Li, C.Y., Yang, Y.,Xu, N.D., Huang, J., 2016a. Manganese functionalized mesoporous molecular sieves Ti-HMS as a Fenton-like catalyst for dyes wastewater purification by advanced oxidation processes. J. Environ. Chem. Eng. 4(4),4653-4660. https://doi.org/10.1016/j.jece.2016.09.039.
Song, Y.F., Chen, X.Y., Zhao, Z.W., Zhang, J.L., He, L.H., 2016b. Theoretical basis for the separation of W and Mo with manganese dioxide:A speciation-based approach. Metall. Mater. Trans. B 47(1), 675-685.https://doi.org/10.1007/s11663-015-0516-6.
Srinivasan, A., Viraraghavan, T., 2010. Decolorization of dye wastewaters by biosorbents:A review. J. Environ. Manag. 91(10), 1915-1929. https://doi.org/10.1016/j.jenvman.2010.05.003.
State Environmental Protection Administration of China(SEPAC), 2002.Analytical and Monitoring Methods of Water and Wastewater, fourth ed.China Environmental Science Press, Beijing(in Chinese).
Tan, F., Liu, M., Li, K., Wang, Y., Wang, J., Guo, X.W., Zhang, G.L.,Song, C.S., 2015. Facile synthesis of size-controlled MIL-100(Fe)with excellent adsorption capacity for methylene blue. J. Chem. Eng. 281,360-367. https://doi.org/10.1016/j.cej.2015.06.044.
Tehrani-Bagha, A.R., Singh, R.G., Holmberg, K., 2013. Solubilization of two organic dyes by anionic, cationic and nonionic surfactants. Colloid. Surf. A Physicochem. Eng. Asp. 417, 133-139. https://doi.org/10.1016/j.colsurfa.2012.10.006.
Uygur, A., Kok, E., 1999. Decolorisation treatments of azo dye waste waters including dichlorotriazinyl reactive groups by using advanced oxidation method. Color. Technol. 115(11), 350-354. https://doi.org/10.1111/j.1478-4408.1999.tb00325.x.
Wang, G.X., Hu, L.N., He, Y.J., 2015. Study on morphology and size distribution controlling of BaS04 particles by PAAS. Inorg. Chem. Ind. 47,35-38(in Chinese).
Watanabe, K., Oshio, N., Kawakami, T., Kimura, T., 2004. Isomerization reactions with sulfur-containing pentane over Metal/SO4~(2-)/ZrO_2 catalysts.Appl. Catal. A Gen. 272(1-21)281-287. https://doi.org/10.1016/j.apcata.2004.05.052.
Weng, S.F., Xu, Y.Z., 2016. Fourier Transform Infrared Spectrometry, third ed.Chemical Industry Press, Beijing(in Chinese).
Zangeneh, H., Zinatizadeh, A.A.L., Habibi, M., Akia, M., 2015. Photocatalytic oxidation of organic dyes and pollutants in wastewater using different modified titanium dioxides:A comparative review. J. Ind. Eng. Chem. 26,1-36. https://doi.org/10.1016/j.jiec.2014.10.043.
Zhang, D.A., 1994. Determination of the color in wastewater using spectrophotometry. Chin. J. Prev. Med. 28, 370-371(in Chinese).
Zhu, M.X., Lee, L., Wang, H.H., Wang, Z., 2007. Removal of an anionic dye by adsorption/precipitation processes using alkaline white mud. J. Hazard Mater. 149(3), 735-741. https://doi.org/10.1016/j.jhazmat.2007.04.037.
Ayed, L., Mahdhi, A., Cheref, A., Bakhrouf, A., 2011. Decolorization and degradation of azo dye Methyl Red by an isolated Sphingomonas paucimobilis:Biotoxicity and metabolites characterization. Desalination274(1-3), 272-277. https://doi.org/10.1016/j.desal.2011.02.024.
Bilinska, L., Gmurek, M., Ledakowicz, S., 2016. Comparison between industrial and simulated textile wastewater treatment by AOPs:Biodegradability, toxicity and cost assessment. Chem. Eng. J. 306, 550-559. https://doi.org/10.1016/j.cej.2016.07.100.
Cai, L., Xu, T., Shen, J.Y., Xiang, W.X., 2015. Highly efficient photocatalytic treatment of mixed dyes wastewater via visible-light-driven AgI-Ag3P04/MWCNTs. Mater. Sci. Semicond. Process. 37, 19-28. https://doi.org/10.1016/j.mssp.2014.12.064.
Fang, Z.D., Zhang, K., Liu, J., Fan, J.Y., Zhao, Z.W., 2017. Fenton-like oxidation of azo dye in aqueous solution using magnetic Fe_3O_4-MnO_2nanocomposites as catalysts. Water Sci. Eng. 11(1), 17-22. https://doi.org/10.1016/j.wse.2017.10.005.
Furkan, M., Alama, M.T., Rizvi, A., Khana, K., Naeem, A., 2017. Aloe emodin, an anthroquinone from Aloe vera acts as an anti aggregatory agent to the thermally aggregated hemoglobin. Spectrochim. Acta Part A Mol.Biomol. Spectrosc. 179, 188-193. https://doi.org/10.1016/j.saa.2017.02.014.
Ge, Y.Z., Jin, H., 1995. Recovery of phenols from coal tar and waste water by precipitation. J. China Coal Soc. 5, 545-550(in Chinese).
Holkar, C.R., Pandit, A.B., Pinjari, D.V., 2014. Kinetics of biological decolorisation of anthraquinone based Reactive Blue 19 using an isolated strain of Enterobacter sp. F NCIM 5545. Bioresour. Technol. 173, 342-351.https://doi.org/10.1016/j.biortech.2014.09.108.
Huma, H., Qaisar, M., Arshid, P., Zulfiqar, A.B., Shams, A.B., 2015.Comparative decolorization of dyes in textile wastewater using biological and chemical treatment. Sep. Purif. Technol. 154, 149-153. https://doi.org/10.1016/j.seppur.2015.09.025.
Kim, K.H., Ihm, S.K., 2011. Heterogeneous catalytic wet air oxidation of refractory organic pollutants in industrial wastewaters:A review. J. Hazard Mater. 186. 16-34. https://doi.org/10.1016/j.jhazmat.2010.11.011.
Lemlikchi, W., Sharrock, P., Fiallo, M., Nzihouc, A., Mecherria, M.O., 2014.Hydroxyapatite and Alizarin sulfonate ARS modeling interactions for textile dyes removal from wastewaters. Proc. Eng. 83, 378-385. https://doi.org/10.1016/j.proeng.2014.09.032.
Li, H.Y., Liu, S.Y., Zhao, J.H., Feng, N., 2016. Removal of reactive dyes from wastewater assisted with kaolin clay by magnesium hydroxide coagulation process. Colloid. Surf. A Physicochem. Eng. Asp. 494, 222-227. https://doi.org/10.1016/j.colsurfa.2016.01.048.
Li, M.L., Zhou, Y.S., Ji, S., 2010. Preparation and microstructure of silver nanopowder with spheric morphology. Ordnance Mater. Sci. Eng. 33, 1-3(in Chinese).
Li, T.. Ma, G.H., Peng, T.J., 2015. Mechanism of preparing spherical nanosized silver particles via o-phenylenediamine reduction process in waterNMPD mixed solution system. Rare Metal Mater. Eng. 44(5),1071-1074. https://doi.org/10.1016/S1875-5372(15)30069-2.
Liang, C.Z., Sun, S.P., Li, F.Y., Ong, Y.K., Chung, T.S., 2014. Treatment of highly concentrated wastewater containing multiple synthetic dyes by a combined process of coagulation/flocculation and nanofiltration. J. Membr.Sci. 469. 306-315. https://doi.org/10.1016/j.memsci.2014.06.057.
Marletta, A., Nascimento, N.D., Eiras, S.P., Andrade, A.A., Pilla, V.P.,Cruz, W.O., 2017. Synthesis optimization of guest/host poly(styrenesulphonate)doped neodymium(III)films. J. Non Cryst. Solids 456, 1-6.https://doi.org/10.1016/j.jnoncrysol.2016.10.034.
Misra, D.N., 1992. Reaction of alizarin red S with hydroxyapatite:Stoichiometry and surface effect. Colloids Surf. 66(3), 181-187. https://doi.org/10.1016/0166-6622(92)80191-4.
Moriguchi, T., Yano, K., Nakagawa, S., Kaji, F., 2003. Elucidation of adsorption mechanism of bone-staining agent alizarin red S on hydroxyapatite by FT-IR microspectroscopy. J. Colloid Interface Sci. 260(1),19-25. https://doi.org/10.1016/S0021-9797(02)00157-1.
Paz, A., Carballo, J., Perez, M.J., Dominguez, J.M., 2017. Biological treatment of model dyes and textile wastewaters. Chemosphere 181, 168-177.https://doi.org/10.1016/j.chemosphere.2017.04.046.
Rosenkranz, F., Cabrol, L., Carballa, M., 2013. Relationship between phenol degradation efficiency and microbial community structure in an anaerobic SBR. Wat. Res. 47(17), 6739-6749. https://doi.org/10.1016/j.watres.2013.09.004.
Song, H.Y., You, J.A., Chen, C.X., Zhang, H., Ji, X.Z., Li, C.Y., Yang, Y.,Xu, N.D., Huang, J., 2016a. Manganese functionalized mesoporous molecular sieves Ti-HMS as a Fenton-like catalyst for dyes wastewater purification by advanced oxidation processes. J. Environ. Chem. Eng. 4(4),4653-4660. https://doi.org/10.1016/j.jece.2016.09.039.
Song, Y.F., Chen, X.Y., Zhao, Z.W., Zhang, J.L., He, L.H., 2016b. Theoretical basis for the separation of W and Mo with manganese dioxide:A speciation-based approach. Metall. Mater. Trans. B 47(1), 675-685.https://doi.org/10.1007/s11663-015-0516-6.
Srinivasan, A., Viraraghavan, T., 2010. Decolorization of dye wastewaters by biosorbents:A review. J. Environ. Manag. 91(10), 1915-1929. https://doi.org/10.1016/j.jenvman.2010.05.003.
State Environmental Protection Administration of China(SEPAC), 2002.Analytical and Monitoring Methods of Water and Wastewater, fourth ed.China Environmental Science Press, Beijing(in Chinese).
Tan, F., Liu, M., Li, K., Wang, Y., Wang, J., Guo, X.W., Zhang, G.L.,Song, C.S., 2015. Facile synthesis of size-controlled MIL-100(Fe)with excellent adsorption capacity for methylene blue. J. Chem. Eng. 281,360-367. https://doi.org/10.1016/j.cej.2015.06.044.
Tehrani-Bagha, A.R., Singh, R.G., Holmberg, K., 2013. Solubilization of two organic dyes by anionic, cationic and nonionic surfactants. Colloid. Surf. A Physicochem. Eng. Asp. 417, 133-139. https://doi.org/10.1016/j.colsurfa.2012.10.006.
Uygur, A., Kok, E., 1999. Decolorisation treatments of azo dye waste waters including dichlorotriazinyl reactive groups by using advanced oxidation method. Color. Technol. 115(11), 350-354. https://doi.org/10.1111/j.1478-4408.1999.tb00325.x.
Wang, G.X., Hu, L.N., He, Y.J., 2015. Study on morphology and size distribution controlling of BaS04 particles by PAAS. Inorg. Chem. Ind. 47,35-38(in Chinese).
Watanabe, K., Oshio, N., Kawakami, T., Kimura, T., 2004. Isomerization reactions with sulfur-containing pentane over Metal/SO4~(2-)/ZrO_2 catalysts.Appl. Catal. A Gen. 272(1-21)281-287. https://doi.org/10.1016/j.apcata.2004.05.052.
Weng, S.F., Xu, Y.Z., 2016. Fourier Transform Infrared Spectrometry, third ed.Chemical Industry Press, Beijing(in Chinese).
Zangeneh, H., Zinatizadeh, A.A.L., Habibi, M., Akia, M., 2015. Photocatalytic oxidation of organic dyes and pollutants in wastewater using different modified titanium dioxides:A comparative review. J. Ind. Eng. Chem. 26,1-36. https://doi.org/10.1016/j.jiec.2014.10.043.
Zhang, D.A., 1994. Determination of the color in wastewater using spectrophotometry. Chin. J. Prev. Med. 28, 370-371(in Chinese).
Zhu, M.X., Lee, L., Wang, H.H., Wang, Z., 2007. Removal of an anionic dye by adsorption/precipitation processes using alkaline white mud. J. Hazard Mater. 149(3), 735-741. https://doi.org/10.1016/j.jhazmat.2007.04.037.