In vitro corrosion resistance and antibacterial performance of noveltin dioxide-doped calcium phosphate coating on degradable Mg-1Li-1Ca alloy
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  • 英文篇名:In vitro corrosion resistance and antibacterial performance of noveltin dioxide-doped calcium phosphate coating on degradable Mg-1Li-1Ca alloy
  • 作者:Lan-Yue ; Cui ; Guang-Bin ; Wei ; Zhuang-Zhuang ; Han ; Rong-Chang ; Zeng ; Lei ; Wang ; Yu-Hong ; Zou ; Shuo-Qi ; Li ; Dao-Kui ; Xu ; Shao-Kang ; Guan
  • 英文作者:Lan-Yue Cui;Guang-Bin Wei;Zhuang-Zhuang Han;Rong-Chang Zeng;Lei Wang;Yu-Hong Zou;Shuo-Qi Li;Dao-Kui Xu;Shao-Kang Guan;College of Materials Science and Engineering, Shandong University of Science and Technology;College of Chemical and Environmental Engineering, Shandong University of Science and Technology;CAS Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences;School of Materials Science and Engineering, Zhengzhou University;
  • 英文关键词:Magnesium alloys;;Coatings;;Corrosion;;Biomedical materials
  • 中文刊名:CLKJ
  • 英文刊名:材料科学技术(英文版)
  • 机构:College of Materials Science and Engineering, Shandong University of Science and Technology;College of Chemical and Environmental Engineering, Shandong University of Science and Technology;CAS Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences;School of Materials Science and Engineering, Zhengzhou University;
  • 出版日期:2019-03-15
  • 出版单位:Journal of Materials Science & Technology
  • 年:2019
  • 期:v.35
  • 基金:supported by the National Natural Science Foundation of China (51571134);; the Research Fund of Shandong University of Science and Technology (2014TDJH104)
  • 语种:英文;
  • 页:CLKJ201903005
  • 页数:12
  • CN:03
  • ISSN:21-1315/TG
  • 分类号:28-39
摘要
A SnO_2-doped calcium phosphate(Ca-P-Sn) coating was constructed on Mg-1 Li-1 Ca alloy by a hydrothermal process. The fabricated functional coatings were investigated using scanning electron microscopy(SEM), X-ray diffraction(XRD) and Fourier transform infrared spectroscopy(FT-IR). A triple-layered structure, which is composed of Ca_3(PO_4)_2,(Ca, Mg)_3(PO_4)_2, SnO_2, and MgHPO_4·3 H_2O, is evident and leads to the formation of Ca_(10)(PO_4)_6(OH)_2 in Hank's solution. Electrochemical measurements, hydrogen evolution tests and plating counts reveal that the corrosion resistance and antibacterial activity were improved through the coating treatment. The embedded SnO_2 nanoparticles enhanced crystallisation of the coating.The formation and degradation mechanisms of the coating were discussed.
        A SnO_2-doped calcium phosphate(Ca-P-Sn) coating was constructed on Mg-1 Li-1 Ca alloy by a hydrothermal process. The fabricated functional coatings were investigated using scanning electron microscopy(SEM), X-ray diffraction(XRD) and Fourier transform infrared spectroscopy(FT-IR). A triple-layered structure, which is composed of Ca_3(PO_4)_2,(Ca, Mg)_3(PO_4)_2, SnO_2, and MgHPO_4·3 H_2O, is evident and leads to the formation of Ca_(10)(PO_4)_6(OH)_2 in Hank's solution. Electrochemical measurements, hydrogen evolution tests and plating counts reveal that the corrosion resistance and antibacterial activity were improved through the coating treatment. The embedded SnO_2 nanoparticles enhanced crystallisation of the coating.The formation and degradation mechanisms of the coating were discussed.
引文
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