摘要
<正>反离子的Manning凝聚效应[1]是聚电解质体系的重要现象之一,也普遍存在于生物体系。在先前的研究中,研究对象为表面带电的圆柱,这里我们将体系拓展为柱状的聚电解质刷,考察新的理论模型能否发生Manning凝聚,其凝聚行为和经典理论相比存在哪些不同,以
引文
[1]Manning,G.S.Limiting Laws and Counterion Condensation in Polyelectrolyte Solutions II.Self‐Diffusion of the Small Ions.The Journal of Chemical Physics 1969,51,934-938.
[2]Deserno,M.;Holm,C.;May,S.Fraction of condensed counterions around a charged rod:Comparison of Poisson-Boltzmann theory and computer simulations.Macromolecules 2000,33,199-206.