摘要
太阳能光化学转换是发展可再生能源,解决能源问题的理想途径。模拟自然界光合作用是太阳能光化学利用的重要手段之一。天然和人工模拟光合作用体系中的能量转换均涉及光能的捕获、能量传递、电子转移和分离,以及催化反应等物理和化学过程。构筑人工模拟光捕获体系并研究其中的能量转换过程和调控机制,对发展高效人工模拟光合作用体系,实现太阳能光化学转换有着重要的意义。本报告将汇报和讨论我们近年来在人工模拟光捕获体系构筑和体系中能量转换研究的进展,为构筑高效人工模拟光捕获体系和能量有效利用提供理论和实验依据。
Photochemical conversion of solar energy is of great importance to deal with energy crisis. Mimicking natural photosynthesis is one of the most important means to convert solar energy into chemical energy. Natural and artificial photosynthesis involve processes including light-harvesting, energy transfer, electron transfer and charge separation, and catalytic reactions. Preparation of light-harvesting systems and investigation of the energy conversion processes involved are significant to the development of efficient light-harvesting systems and consequent photochemical conversion of solar energy. In this presentation, recent efforts in our lab on the construction of artificial light-harvesting systems and the investigation on the energy conversion will be presented.
引文
[1]X.H.Zhang,Y.Zeng,T.J.Yu,J.P.Chen,G.Q.Yang,Y.Li,J.Phys.Chem.Lett.2014,5,2340.
[2]Y.Zeng,P.Li,X.Y.Liu,T.J.Yu,J.P.Chen,G.Q.Yang,Y.Li,Polym.Chem.2014,5,5978.
[3]Z.Q.Xun,T.J.Yu,Y.Zeng,J.P.Chen,X.H.Zhang,G.Q.Yang,Y.Li,J.Mater.Chem.A 2015,3,12965.