四川省氮氧化物排放现状及控制对策研究
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摘要
随着我国经济的快速发展和能源生产与消费量的急速增长,氮氧化物排放量也随之增加。有关研究表明,氮氧化物排放加剧了大气酸沉降、光化学烟雾和城市灰霾的污染。由于氮氧化物可以在大气层中长距离输送,引起的全球性或区域性污染问题也日渐突出。如果对此不加以控制,氮氧化物的持续增加将会明显抵消掉二氧化硫减排所取得的重大环境效益。
     “十二五”期间,国家新增氮氧化物为主要污染物总量减排考核指标,根据国家初步下达的考核目标任务,四川省“十二五”总量减排任务极为艰巨。对四川省氮氧化物排放在不同地区的总量分布和不同行业的总量结构现状进行整理、分析,并对其控制对策进行研究,有助于行政主管部门从可持续发展的要求出发,制定适当的政策和采取有效的控制措施,加强节能,提高能效,改善能源结构和能源利用技术,在未来能以较低的能源消费增长支持较高的经济增长,从而减少氮氧化物的排放增长量,对全省乃至全国的环境都起到积极作用。
     根据2010年度四川省污染源普查动态更新数据,对氮氧化物排放进行了统计分析,归纳出氮氧化物排放特征。并根据《四川省环境质量报告书2006~2010》中2010年度大气环境质量数据,分析了氮氧化物排放对环境空气质量中二氧化氮浓度和大气降水pH值、降水氮沉降的相关性,由此整理出氮氧化物排放对大气环境质量的影响。根据氮氧化物的排放特征和对环境的影响情况,确定了四川省氮氧化物重点控制行业和控制地区。
     对现行氮氧化物控制手段进行了整理,找出对其监控和管理存在的不足,从而提出了四川省氮氧化物的宏观控制对策。由于氮氧化物控制的重点行业——火电行业、水泥制品业、机动车污染源的氮氧化物排放来源均是来自燃烧过程,因此,对氮氧化物的形成机理进行分析,对氮氧化物控制技术进行讨论,从而提出氮氧化物重点控制行业的具体控制技术和控制政策。最后,设计出四川省氮氧化物减排方案。宏观管理和技术治理两方面相辅相成,能够为政府和企业在环境保护方面提供具有现实意义的启发和有效的导向,为氮氧化物的控制优化提供一个全新的视角。
With the rapid growth of China's rapid energy production and consumption, nitrogen oxide emissions have increased. The study showed that nitrogen oxide emissions contribute to atmospheric acid deposition, photochemical smog and urban haze pollution. Due to long-range transport of nitrogen oxides in the atmosphere which caused by global or regional pollution problems have become increasingly prominent. If this is left unchecked, the continued increase of the nitrogen oxides will be significantly offset by the significant environmental benefits achieved by the sulfur dioxide emission reduction.
     During the12th Five-Year Plan, China added nitrogen oxides for the total amount of major pollutants emission reduction assessment indicators. According to the preliminary assessment issued, Sichuan's12th Five-Year Plan total emission reduction task is extremely difficult. Our province analyze, and control measures Nitrogen oxide emissions of the total amount of distribution in different regions and different sectors of the total amount of actuality organize to contribute to the administrative department of the departure from the requirements of sustainable development, which appropriate policies and take effective control measures to enhance energy conservation, energy efficiency. Also, it can improve the energy structure and energy utilization technology to support high economic growth in the future at a lower energy consumption growth. Thereby reducing nitrogen oxide emissions growth play a positive role on the environment of the province and the country.
     In this thesis, according to the2010census of pollution sources in Sichuan Province, nitrogen oxide emissions statistical analysis and summed up the characteristics of nitrogen oxide emissions. According to the Sichuan Environmental Quality Report2006to2010, in the year2010the, we analyzed the nitrogen oxide emissions of nitrogen dioxide concentration in the ambient air quality and atmospheric precipitation pH value. Then we finishing the nitrogen oxide emissions of atmospheric environmental quality and derivatives of nitrogen oxide emissions which impact on the water environment, soil, plants and human. According to the characteristics of nitrogen oxide emissions and the impact on the environment, the province nitrogen oxides Critical Control Point (HACCP) industry and controlled areas.
     This paper finishing the existing nitrogen oxides control means to identify the shortcomings of its monitoring and management, which made the macro-control measures of the nitrogen oxides in our province. Thus derived key industries-thermal power industry, cement products industry, mobile source emissions control technology and control policies were discussed. Finally, a nitrogen oxides emission reduction program is designed to provide important reference for government decision-making, and to improve the execution of the government environmental management policies. Macroeconomic management and technical management of two complementary has practical significance inspired and effective guide to government and industry in the area of environmental protection, optimized to provide a new perspective for the control of nitrogen oxides.
引文
[1]吴晓青.我国大气氮氧化物污染控制现状存在的问题与对策建议[R].中国科技产业,2009.
    [2]环境保护部网站.环境保护部副部长吴晓青介绍中国环境状况等方面情况发布会文字实录[EB/OL]. http://www.zhb.gov.cn/zhxx/hjyw/201206/t20120606_231024.htm,2012-06-06.
    [3]中国化肥网. 四川欲 4 年削减氮氧化物15.68%[EB/OL]. http://www.cheminfo.gov.cn/ZXZX/page_info.aspx?id=386222&Tname=hgyw&c=10,2012-04-06.
    [4]华西都市报.四川省今年减排任务出炉氮氧化物将实现零增长[EB/OL]. http://www.chinadaily.com.cn/hqcj/zgjj/2012-03-31/content_5584117.html,2012-03-31.
    [5]杜譞,朱留财.氮氧化物污染防治的国外经验与国内应对措施[J].环境保护与循环经济,2011,,12(2):37-39.
    [6]张勇.沈阳市“十二五”期间NOx总量控制对策与建议[J].环境保护科学,2011,37(2):75-78.
    [7]郝吉明.中国氮氧化物的排放及控制[R].北京:2003年中国环境科学研究院学术年会报告,2003.
    [8]赵济强.氮氧化物(NOX)废气治理工程实例[J].环境工程,2010,28(3).
    [9]李少敏.空气中氮氧化物的污染物分析及治理技术[J].河南科技,2010,24(6).
    [10]张月琴.气体中氮氧化物分析方法进展[J].现代科学仪器,2009,6(3).
    [11]张华,赵由才.生物法处理氮氧化物废气的原理与技术研究进展[J].山东建筑工程学院学报,2005,8(3).
    [12]郝吉明,马广大.大气污染控制工程[M].2版.北京:高等教育出版社,2002.
    [13]化工百科编辑委员会.化工百科全书[M].北京:化学工业出版社,1998,17:1107-1108.
    [14]徐青,郑章靖,凌长明,李军.氮氧化物污染现状和控制措施[J].安徽农业科学,2011,38(29):16388-16391.
    [15]熊振湖,费学宁,池勇志等编.大气污染防治技术及工程应用[M].北京:机械工业出版社,2003,7:218-222.
    [16]Bradford M. & R.Grover & P.Paul.Controlling NOx emissions part 1[J].Chemical,2003,32(4): 297-336.
    [17]孙克勤,韩祥.燃煤电厂烟气脱硝设备及运行[M].北京:机械工业出版社,2011,6.
    [18]周松,肖友洪,朱元清.内燃机排放与污染物控制[M].北京:北京航空航天大学出版社,2010.
    [19]赵炜,常丽萍,谢克昌,李春柱.煤燃烧过程生成氮氧化物前躯体的研究[J].燃料化学学报,2004,32(4):385-388.
    [20]Kalyan Annamalai, William ryan.Interactive processes in gasification and combustion II.Isolated carbon, coal and porous char particles, Prog[J].Energy Combust Sci.1993,19: 383-446.
    [21]Kamabara S, Takarada T, Yamamoto Y, Kato K.Reaction between functional forms of coal nitrogon and formation of NOx precursors during rapid pyrolysis[J].Energy and Fuels,1993,7(6): 1013-1020.
    [22]毛健雄,毛健全,赵树民编著.煤的清洁燃烧[M].北京:科学出版社,1998,218-223.
    [23]James A.Miller, Craig T.Bowman.Mechanism and modeling of nitrogen chemistry in combustion[J].Energy Combust.Sci,1989,Vol.15.pp.287-338.
    [24]岑可法,姚强,骆仲泱.高等燃烧学[M].杭州:浙江大学出版社,2000.
    [25]董洪彬,曹欣玉,牛志刚,应凌俏,周俊虎,刘建忠,岑可法.烟煤挥发分和焦炭分解燃烧过程中NO释放特性[J].煤炭学报,2005,30(1):95-99.
    [26]环境保护部网站.环境保护部副部长吴晓青介绍环境空气质量标准等方面情况并答记者问[EB/OL]. http://www.zhb.gov.cn/zhxx/hjyw/201203/t20120302_224179.htm,2012-03-02.
    [27]尹辉,赵明斌,刘强,朱丽.氮氧化物治理现状及发展趋势[J].江西化工,2011,2:41-43.
    [28]Bosch H, Janssen F.Catalytic Reduction of Nitrogen Oxides-A Review on the Fundamental and Technology[J].Catalysis Today,1988,2(4):369-531.
    [29]贾双燕,陆涛.选择性催化还原烟气脱硝技术及其在我国的应用研究[J].电力环境保护,2004,20(1):19-21.
    [30]朱炳辰.化学反应工程[M].4版.北京:化学工业出版社,2006:37-40.
    [31]Anupamm S, William E, Ellison C.Lessons learned from SCR experience of coal fired units in Japan, Europe and USA[C].2002 conference on SCR and Non-Catalytic Reduction for NOx control, 2002:15-16.
    [32]田柳青,叶代启.以堇青石蜂窝陶瓷为载体的新型钒氧化物脱氮催化剂研究[J].环境科学,2004,25(1):7-8.
    [33]苏涛.大气中氮氧化物的形成及防治[J].科技视野,2009,N011:43-44.
    [34]孙承绪.全氧燃烧池窑中若干技术问题的讨论[J].玻璃与搪瓷,2002,30(1):47-53.
    [35]高风,杨嘉谟.燃煤烟气脱硝技术的应用与进展[J].环境保护科学,2007,33(3):11-13.
    [36]Long X L, Xiao W D, Yuan W K.Removal of iitric oxide and sulfur dioxide from flue gas using a hexamminecobalt(Ⅱ)/Iodide solution[J].Industrial and Engineering Chemistry Research, 2004,43:4048-4053.
    [37]J.A.Miller, C.T.B.Mechanism and Modeling of Nitrogen Chemistry in Combustion.Progress in Energy and Combustion Science,1989,15:287-338.
    [38]王志轩.论我国火电厂氮氧化物控制[J].中国电力企业管理,2009,(8):16-19.
    [39]曲虹霞,钟秦.、/2O5/TiO2催化剂选择性催化还原脱除NOX的研究[J].安全与环境学报,2004,4(2):16-18.
    [40]Arve K, Backman H, Klingstedt F, et al.Kinetic considerations of H2 assisted hydrocarbon selective catalytic reduction of NO over Ag/Al2O3:JJ.Kinetic modelling[J].Applied Catalysis A:General, 2006,303(1):96-102.
    [41]Kondratenko E V, Kondratenko V A, Rjchter M, et al.Influence of O2 and H2 on NO reduction by NH3 over Ag/Al2O3:A transient isotopic approach[J].Journal of Catalysis,2006,239(1):23-33.
    [42]钟秦.选择性非催化还原法脱除NOX的实验研究[J].南京理工大学学报,2004,4(2):16-18.
    [43]孙德荣,吴星五.我国氮氧化物烟气治理技术现状及发展趋势[J].云南环境科学,2003,22(3): 47-50.
    [44]黄少仪.降水和天气形势对大气污染的影响[J].环境技术,2000,04(4):24-30.
    [45]何志桥,王家德,陈建孟.生物法处理NOX废气的研究进展[J].环境污染防治与设备,2002,3(9):59-62.
    [46]Okuno K, Hirai M, Sugiyama M, et al.Microbial removal of nitrogen monoxide(NO) under aerobic conditions [J].Biotechnology Letters,2000,22:77-79.
    [47]井鹏,岳涛,李晓岩,高晓晶,张迎春.火电厂氮氧化物控制标准、政策分析及研究[J].中国环保产业,2009,4:19-23.
    [48]张倩.我国机动车保有量31年增30倍尾气排放增14倍[N].人民日报,2012-12-28.
    [49]中国新闻网.“黄标车”退出为何步履维艰 能否强制淘汰[EB/OL]. http://www.chinanews.com/ny/2011/10-28/3421624.shtml,2011-10-28.
    [50]杜譞,朱留财.氮氧化物污染防治的国外经验与国内应对措施[J].环境保护与循环经济.2011(04):68-69
    [51]宁德正.常规燃煤发电厂氮氧化物排放控制技术综述[J].云南电力技术.2008(02):14-15
    [52]贾世昌.水泥窑炉SNCR脱硝技术探析[J].环境科技.2012(02):32-36.
    [53]何洪,王洪兵,李坚,梁文俊.水泥炉窑选择性(非)催化还原脱硝技术[J].四川水泥.2012(01):18-21