典型聚醚的封端研究
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摘要
本文所说的典型聚醚是指由活泼氢引发的分子链末端带有活性基团的聚氧链烯基共聚物,这类带有活性基团的未封端的聚醚,由于活性基团的存在,其耐酸碱性、耐盐性和耐温性受到一定限制,而封端聚醚由于链末端羟基被取代,具有较高的化学稳定性,而且此类封端聚醚还具有浊点下降、发泡能力降低、去油性能力增强、临界胶束浓度下降和化学性质更为稳定等特点,适用于不同pH值下、高温长时间使用,由此拓宽了聚醚使用范围。聚醚的封端方法主要可分为醚化封端、酯化封端和交联封端,是指聚醚上的羟基通过各种有机小分子化合物进行醚化、酯化或者交联反应,羟基上的活泼氢被各种短链的烷基、芳烷基、酯基或其它基团取代。封端后,改变了其物理化学性质,增加了某些新的功能。本文对典型聚醚的封端合成技术及典型封端聚醚的性能进行了系统的研究,并将合成的典型封端聚醚进行了原油的降摩阻性能的应用研究。
另外一类含有不饱和键的聚醚因为具有反应性,一般把其视为非典型聚醚,由于羟基的存在影响不饱和键与环境体系的反应。链末端羟基必须封端改性,而这一类封端聚醚由于具有特殊的化学稳定性和可反应的性质,所以本文就该类活性聚醚的封端也进行了部分研究。
石油作为工业的血脉,随着“能源危机”时代的到来,石油的开采和输运日益得到人们的广泛重视,尤其是高粘稠油的开采显得尤为重要,但是解决高粘稠油的开采输送是全世界石油行业的最大难题。但是关于原油降摩阻的机理不论是从经典的学术著作还是近年来发表的学术论文,都认为其机理复杂,很难表述清楚。原油的降摩阻与降粘和流动改进的机理既有类同之处,又有本质的不同。乳化降粘需要至少20%以上的水才能形成O/W,而流动改进剂仅对不含水原油有效,如果原油含水,流动改进剂效果反而不好。实验中笔者曾发现双环咪唑啉衍生物封端聚醚对原油具有降摩阻作用,特别是在含水量较大的原油中,能减小原油的流动阻力。本文研究中发现,利用合成的典型双环咪唑啉衍生物封端聚醚与活性高聚物复配制备的复合降摩阻剂,拓宽了含水原油的使用范围,由原来对含水10%以上原油能有效降低流动阻力,拓宽到对原油含水5%以上也可有效降摩阻。就此问题,笔者在典型封端聚醚的研究基础上,我们重点研究了这种复合降摩剂的降摩阻机理。关于降摩阻剂的降摩阻机理比较复杂,它涉及到流变学、流体动力学、摩擦学、聚合物的物理化学等学科,降摩阻剂的相关机理有很多不同的说。我们主要从界面化学、微观动力学及微观状态的角度研究了降摩阻剂的降摩阻机理。我们在通过此种复合降摩阻剂与一般降粘剂和单一双环咪唑啉衍生物封端聚醚进行性能对比的基础上,我们得出了原油微观状态的改变可能是导致原油流动阻力大大下降的原因,复合降摩阻剂的加入使原油的微观流动状态由原来的平动转化为“轴动”状态,而这种轴动状态无论是从摩擦学还是动力学角度,都可以很好的减小原油与介质以及原油本体之间的相互作用力。实验证明我们发现了一种更有效的降低原油流动阻力的石油降摩阻剂。
本文研究的主要工作和贡献如下:
(1)介绍了国内外聚醚型表面活性剂的研究进展及应用。
(2)介绍了典型封端聚醚的合成技术。
(3)合成典型双环咪唑啉衍生物封端聚醚,并与活性高聚物复配制备了一种复合原油降摩阻剂。
(4)该复合降摩阻剂在高粘稠油开采和输送中具有很好的降摩阻降粘效果。
(5)从界面化学、微观动力学的角度以及流变学的角度入手,研究了加入复合降摩阻剂前后原油流动阻力的变化、原油粘度、原油表面张力、吸附力以及原油微观形态的变化。
(6)初步认为原油复合降摩阻剂的降摩阻机理为原油的微观状态发生了改变,导致原油流动状态由平动转变为“轴动”,进而大大降低了其在流动过程中的流动阻力。
The typical polyether in this paper refers initiation molecular chain terminal has the active group to gather the oxygen alkene base copolymer caused by reactive hydrogen.This kind of polyether without sealed end which has the hydroxyl, as a result of existence of the active hydroxyl, its acidproof alkalinity, the salt endurance and the heat resistance was limited.Moreover, if the initiator includes unsaturated linkage polyether and other active group reaction, the existence of hydroxyl can influence the response between unsaturated linkage and system.The closure-linked polyether as the end of hydroxy be replaced, has a high chemical stability, but such letters have also polyether-cloud point decline in the ability to reduce foam, to enhance the capacity of oil, critical micelle concentration dropped and chemical More stable nature of the characteristics apply to different pH value, high-temperature prolonged use, which widened the scope of the use of polyether.Polyether-way closure can be divided into ether-capped, esterification and cross-linked closed-end closure, polyether is on the hydroxyl molecules through a variety of small organic compounds ether, esterification or cross-linking reaction, Hydroxy hydrogen was lively on the various short-chain alkyl, Fong alkyl, ester-based or other groups to replace.Terminated, has changed its physical and chemical properties, an increase of some new features. In this paper, the closure of the typical polyether-synthesis technology and the performance of typical capped polyether are researched, and the terminal polyether is applied in research of crude oil down the friction.
As“the energy crisis”the time coming, the petroleum takes the industry blood vessels, petroleum mining and the transportation attracts people’s widely day by day, particularly viscous crude oil mining appears high especially important, but how to the problem of viscous crude oil the mining and transportation is the biggest difficult problem in the petroleum profession world. At present,domestic and foreign generally add high polymer surface active agent or the viscosity reducer to reduce the flowing resistance in the mining and the transportation process of crude oil,in order to enhancing the transportation efficiency.
In view of some questions that the rude oil reduction agent and the thinner exists in thick oil mining and the transportation, and caused the crude oil resistance primary cause in the crude oil flowing process, this article mainly conducts the research to a kind of sealed end polyether synthesis and the performance, the experiment has discovered one kind of the bicycloimidazoline derivative sealed end polyether. The research discovered that this kind of sealed end polyether duplicate matches with one kind of active high polymer as the crude oil frictional resistance reducer, can reduce the crude oil flow resistance effectively, and this kind compound frictional resistance reducer expand the applicable scope of crude oil that contain water ,from contain water 10% above the crude oil expanded to contains water 5% above the crude oil also fall the frictional resistance effectively.
We mainly studied from the interfacial and surface chemistry angle to explain the mechanism of frictional resistance.In library using had the oxygen nitrogen structure alkene base imidazoline derivatives terminated linear polyurethane,synthesized bicyloimidazoline derivatices polyesters. Using the bicycloimidazoline derivative sealed end polyether to match the active polymer, prepared the frictional resistance reducer. Carring on the laboratory appraisal, and Discovered that the compound frictional resistance reducer compare to the bicyloimidazoline derivatives teriminated polyesters, the compound frictional resistance reducer can wide the using scope of crude oil water contenting . and it can strengthen the ability of reducing the crude oil the flow resistance. Moreover, using micro-photography method, discovered that, when adding the compound frictional resistance reducer into the different water contents oil, the flow resistance of the crude oil greatly drops, and the microscopic shape of the crude oil has the characteristic change. The experiment proved that we had discovered one kind more effective the frictional resistance reducer .
The article includes five aspects as following:
(1) Introduced development and the application of polyether surfactants research about the domestic and foreign.
(2) Introduced the typical sealed end polyether synthesis technology
(3)Using the bicycloimidazoline derivative sealed end polyether to match the active polymer, prepared the frictional resistance reducer.
(4) This frictional resistance reducer has the very good effect of reducing the crude oil flowing resistance in mining and transportation process.
(5) From the contact surfaces interface collides and rheology study the flowing resistance, surface tension and superficial adsorptive viscosity changes of crude oil before and after adding frictional reducer.
(6) using micro-photography method, discovered that, when adding the compound frictional resistance reducer into the different water contents oil, the flow resistance of the crude oil greatly drops, and the microscopic shape of the crude oil has the characteristic change.
另外一类含有不饱和键的聚醚因为具有反应性,一般把其视为非典型聚醚,由于羟基的存在影响不饱和键与环境体系的反应。链末端羟基必须封端改性,而这一类封端聚醚由于具有特殊的化学稳定性和可反应的性质,所以本文就该类活性聚醚的封端也进行了部分研究。
石油作为工业的血脉,随着“能源危机”时代的到来,石油的开采和输运日益得到人们的广泛重视,尤其是高粘稠油的开采显得尤为重要,但是解决高粘稠油的开采输送是全世界石油行业的最大难题。但是关于原油降摩阻的机理不论是从经典的学术著作还是近年来发表的学术论文,都认为其机理复杂,很难表述清楚。原油的降摩阻与降粘和流动改进的机理既有类同之处,又有本质的不同。乳化降粘需要至少20%以上的水才能形成O/W,而流动改进剂仅对不含水原油有效,如果原油含水,流动改进剂效果反而不好。实验中笔者曾发现双环咪唑啉衍生物封端聚醚对原油具有降摩阻作用,特别是在含水量较大的原油中,能减小原油的流动阻力。本文研究中发现,利用合成的典型双环咪唑啉衍生物封端聚醚与活性高聚物复配制备的复合降摩阻剂,拓宽了含水原油的使用范围,由原来对含水10%以上原油能有效降低流动阻力,拓宽到对原油含水5%以上也可有效降摩阻。就此问题,笔者在典型封端聚醚的研究基础上,我们重点研究了这种复合降摩剂的降摩阻机理。关于降摩阻剂的降摩阻机理比较复杂,它涉及到流变学、流体动力学、摩擦学、聚合物的物理化学等学科,降摩阻剂的相关机理有很多不同的说。我们主要从界面化学、微观动力学及微观状态的角度研究了降摩阻剂的降摩阻机理。我们在通过此种复合降摩阻剂与一般降粘剂和单一双环咪唑啉衍生物封端聚醚进行性能对比的基础上,我们得出了原油微观状态的改变可能是导致原油流动阻力大大下降的原因,复合降摩阻剂的加入使原油的微观流动状态由原来的平动转化为“轴动”状态,而这种轴动状态无论是从摩擦学还是动力学角度,都可以很好的减小原油与介质以及原油本体之间的相互作用力。实验证明我们发现了一种更有效的降低原油流动阻力的石油降摩阻剂。
本文研究的主要工作和贡献如下:
(1)介绍了国内外聚醚型表面活性剂的研究进展及应用。
(2)介绍了典型封端聚醚的合成技术。
(3)合成典型双环咪唑啉衍生物封端聚醚,并与活性高聚物复配制备了一种复合原油降摩阻剂。
(4)该复合降摩阻剂在高粘稠油开采和输送中具有很好的降摩阻降粘效果。
(5)从界面化学、微观动力学的角度以及流变学的角度入手,研究了加入复合降摩阻剂前后原油流动阻力的变化、原油粘度、原油表面张力、吸附力以及原油微观形态的变化。
(6)初步认为原油复合降摩阻剂的降摩阻机理为原油的微观状态发生了改变,导致原油流动状态由平动转变为“轴动”,进而大大降低了其在流动过程中的流动阻力。
The typical polyether in this paper refers initiation molecular chain terminal has the active group to gather the oxygen alkene base copolymer caused by reactive hydrogen.This kind of polyether without sealed end which has the hydroxyl, as a result of existence of the active hydroxyl, its acidproof alkalinity, the salt endurance and the heat resistance was limited.Moreover, if the initiator includes unsaturated linkage polyether and other active group reaction, the existence of hydroxyl can influence the response between unsaturated linkage and system.The closure-linked polyether as the end of hydroxy be replaced, has a high chemical stability, but such letters have also polyether-cloud point decline in the ability to reduce foam, to enhance the capacity of oil, critical micelle concentration dropped and chemical More stable nature of the characteristics apply to different pH value, high-temperature prolonged use, which widened the scope of the use of polyether.Polyether-way closure can be divided into ether-capped, esterification and cross-linked closed-end closure, polyether is on the hydroxyl molecules through a variety of small organic compounds ether, esterification or cross-linking reaction, Hydroxy hydrogen was lively on the various short-chain alkyl, Fong alkyl, ester-based or other groups to replace.Terminated, has changed its physical and chemical properties, an increase of some new features. In this paper, the closure of the typical polyether-synthesis technology and the performance of typical capped polyether are researched, and the terminal polyether is applied in research of crude oil down the friction.
As“the energy crisis”the time coming, the petroleum takes the industry blood vessels, petroleum mining and the transportation attracts people’s widely day by day, particularly viscous crude oil mining appears high especially important, but how to the problem of viscous crude oil the mining and transportation is the biggest difficult problem in the petroleum profession world. At present,domestic and foreign generally add high polymer surface active agent or the viscosity reducer to reduce the flowing resistance in the mining and the transportation process of crude oil,in order to enhancing the transportation efficiency.
In view of some questions that the rude oil reduction agent and the thinner exists in thick oil mining and the transportation, and caused the crude oil resistance primary cause in the crude oil flowing process, this article mainly conducts the research to a kind of sealed end polyether synthesis and the performance, the experiment has discovered one kind of the bicycloimidazoline derivative sealed end polyether. The research discovered that this kind of sealed end polyether duplicate matches with one kind of active high polymer as the crude oil frictional resistance reducer, can reduce the crude oil flow resistance effectively, and this kind compound frictional resistance reducer expand the applicable scope of crude oil that contain water ,from contain water 10% above the crude oil expanded to contains water 5% above the crude oil also fall the frictional resistance effectively.
We mainly studied from the interfacial and surface chemistry angle to explain the mechanism of frictional resistance.In library using had the oxygen nitrogen structure alkene base imidazoline derivatives terminated linear polyurethane,synthesized bicyloimidazoline derivatices polyesters. Using the bicycloimidazoline derivative sealed end polyether to match the active polymer, prepared the frictional resistance reducer. Carring on the laboratory appraisal, and Discovered that the compound frictional resistance reducer compare to the bicyloimidazoline derivatives teriminated polyesters, the compound frictional resistance reducer can wide the using scope of crude oil water contenting . and it can strengthen the ability of reducing the crude oil the flow resistance. Moreover, using micro-photography method, discovered that, when adding the compound frictional resistance reducer into the different water contents oil, the flow resistance of the crude oil greatly drops, and the microscopic shape of the crude oil has the characteristic change. The experiment proved that we had discovered one kind more effective the frictional resistance reducer .
The article includes five aspects as following:
(1) Introduced development and the application of polyether surfactants research about the domestic and foreign.
(2) Introduced the typical sealed end polyether synthesis technology
(3)Using the bicycloimidazoline derivative sealed end polyether to match the active polymer, prepared the frictional resistance reducer.
(4) This frictional resistance reducer has the very good effect of reducing the crude oil flowing resistance in mining and transportation process.
(5) From the contact surfaces interface collides and rheology study the flowing resistance, surface tension and superficial adsorptive viscosity changes of crude oil before and after adding frictional reducer.
(6) using micro-photography method, discovered that, when adding the compound frictional resistance reducer into the different water contents oil, the flow resistance of the crude oil greatly drops, and the microscopic shape of the crude oil has the characteristic change.
引文
[1]梁治齐,宗惠娟,李金华.功能性表面活性剂.中国轻工业出版社[M].2002:l.
[2]邢其毅,徐瑞英,周政,等.基础有机化学(第二版)[M].北京:高等教育出版社,2000.106-109.
[3]徐燕莉.表面活性剂的功能[M].北京:化学工业出版社,2000.164-189.
[4]陈福良,王仪,郑斐能,等.农药微乳剂及其浊点问题的探讨和初步研究[J],农药.1999,38(3):9-10.
[5]杨树良.嵌段型非离子表面活性剂在微乳剂制备中的应用[J].农药,2006,45(2):106-110.
[6]刘建强,李玉香,马骏,等.表面活性剂在新型清洗剂中的应用研究[J].山东大学学报(理学版),2003,38(2):64-66.
[7]杨树良.非离子型高分子表面活性剂及其应用[J].日用化学工业,1990,(5):16-20.
[8]Patricia N,Hurter T,Alan Hatton.Solubilization of polycyclic aromatic hydrocarbons by poly(ethylene oxide-propylene oxide)block copolymer micelles:effects of polymerstructure[J].Langmuir,1992,8(5):1291~1299.
[9]Paterson I F,Chowdhry B Z,Leharne S A.Investigations of naphthalene solubilization in aqueous solutions of ethylene oxide-b-propylene oxide-b-ethylene oxide copolymers[J].Langmuir,1999,15(19):6187~6194.
[10]于飞.树枝状聚醚表面活性剂的合成与性能研究[M].大庆石油学院硕士学位论文,2007,3.
[11]周莉,吴奕光,戴旭映.PEP 聚醚型非离子表面活性剂的合成与性能研究[J].表面活性剂工业,1998,(4):23-26
[12]袁浩明.精细石油化工,1991,(3):29
[13]K.Koswsing.日用化学工业译丛.1956,13(1):7 一 11
[14]焦宇.双烷基 EO\PO 共聚醚的合成与表征[M].郑州大学硕士学位论文,2006,6.
[15]言敏达.聚醚的功能化[J].精细化工,2000,17(12)
[16]黄银霞.聚醚封端方法探讨[J].金陵石油化,1992,11(4):15-27
[17]黄银霞.不饱和聚醚封端方法探讨[J].聚氨酯工业,15(l):18-20
[18]尹红,黎松.醚化封端聚醚的技术进展.精细化工,2002,19:19-22
[19]晋心文.H 一 420 软泡匀泡剂[J].聚氨醋工业,2000,15(1):35-37
[20]NukinaShogo,KotaniEisaku.PreParationofglyeoldiether[P].jP:8228019 ,1982-02-15.
[21]YoshimuraNoriaki,TamuraMasuhiko.PreParationoftherifiedPolyoxyalkyleneComPounds of high quality[P].JP:7846905,1978,4
[22]辛寅昌,张盛军,邱增中.醚化封端聚醚的研究进展及应用[J].精细与专用化学品,2007,15(14).
[23]张士福,李迎,宋建平.烷基封端聚醚的制备及应用[J]. 上海化工,2001,26(2):24-26.
[24] Karl S M,Horst B L,et a1.Aqueous foam —inhibiting eo mpo si—tions containing alkyl polyethylene glycol alkyl ethers[P].US, US 4 548 729(1985).
[25] Joaqllim B L,Nuria B,et a1.Pmcess for the production of end一capped nonionic surfactants[P].US,US 5 847 229(1998).
[26] Bernd W K,Faize S D.Mercerizing and/or causticizing wetting a—gent:2 一ethyl— hexyl—sulfate and mixturc of alkyl end —blocked polyethers[P].US,US 5 013 327(1991).
[27] 张士福.ω -烷氧基聚醚的用途[J]. 金山油化纤,2003,(1.):25-29.
[28] Karl H S,Alfred M M ,et a1.Process for controUing foam in foodprocesingand production[P].US,US 4 942 049(1991).
[29] 杨颖霞,李永德. 有机硅在聚氨酯中的应用[J]. 聚氨酯工业,2002,17(3):31-33.
[30] 李玉松. 聚氨酯泡沫用有机硅匀泡剂的合成及应用[J]. 聚氨酯工业,2004,19(2):1-4.
[31] 黄文润. 特殊结构的有机硅表面活性剂[J]. 有机硅材料,2005,19(2):38-41.
[32] 李姜娜,尚丙坤,张杰. 建筑密封胶用有机硅改性聚醚的研究进展[J]. 聚氨酯工业,2004,19(4):1-4.
[33] 冯光炫,崔英德,卢奎,李和平. 油酸封端的C36--聚酸/PEG/PPG聚醋的合成及其消泡抑泡性能[J]. 日用化学工业,2006,36(2):76-80.
[34]李雅丽. 聚氨酯有机硅匀泡剂的研究及应用[J]. 应用化工,2006,35(2):84-85.
[35] 梁书恩,王建华,田春蓉,周秋明,芦艾. 匀泡剂对硬质聚氨酯泡沫孔径及冲击性能的影响[J]. 塑料助剂,2005,(3):25-27.
[36] 宋虹霞,郑银才,邓爱华. 高相对分子质量聚醚多元醇的环氧乙烷封端[J]. 高桥石化,2006,3( 21):1-5.
[37] 殷宁,亢茂青,冯月兰,张清运,瞿波,王心葵. 高活性超低单醇含量聚醚多元醇合成高回弹聚氨酯泡沫塑料的研究[J].化工新型材料,2003,5(31):31-34.
[38]K.Krossing.乙氧基化物.日用化学工业译丛.1986,(4):7 一 11
[39]PazosJoseF.ProeessForMakingEthyleneOxideeaPPedPolyosFromDoubleMetalCyanide CatalyzcdPolyols.US:5563221,1996,10
[40]颜再荣,吴立传,杨淑英等.用小分子调竹剂合成 DMC 聚醚.高分子材料科学与 l:程,2004,20(3):57 一 63
[41]王志新.DMC 催化剂及其在聚醚多元醇生产中的应用.聚氨酉旨 l 一业,2002,17(3):41-43
[42]秦旭东,秦怡生,王德和.双烷基封端聚醚的合成与应用.1999 年表面活性剂经济技术信息论文集,p223
[43]宋幸炜,王世普.新型封端聚醚的合成及应用.1999 年表面活性剂经济技术洁忘、沦文果,P251
[44]屈增录.硅改性聚醚的制法及在密封剂、胶粘剂中的应用[]z.黎明化工,1994,(40):1-4
[45]尹红.环氧乙烷环氧丙烷无规聚醚分子结构控制方法研究.浙江大学博士论文,1999
[46] 尹艳红,黎松. 醚化封端聚醚的技术进展[J]. 精细化工,2002,19(增):19-22.
[47]李玉松,徐敬宇,冯云.α-烯丙基齐聚氧化乙烯-氧化丙烯加密的合成[J]. 聚氨酯工业,2002,17(1):15-18.
[48]李玉松. 端烯丙基混嵌段聚氧化烯基甲醚的合成[J]. 精细石油化工,2004,(5):44-45.
[49]辛寅昌,张盛军,邱增中,赵明方.原油微观装态与降摩阻性能的研究[J].石油学报(石油加工),2008,4
[50]许东彬. 高粘原油的降摩阻性能研究[M].山东师范大学硕士论文,2007,4
[51]关中原,李春漫,尹国栋.EP 系列减阻剂的研制与应用[J].油气储运,2001,20(3):32～34
[52] 邵雪明,林建忠. 高聚物减阻机理的研究综述[J]. 浙江工程学院学报,2001,18(1):15-19. (SHAO Xue-ming,LIN Jian-zhong. Review of research on mechanism of drag reduction by polymer additives[J]. Joumal of Zhejiang Institute of Science and Technology,2001,18(1):15-19. )
[53] 马卫嵘,谭芳,赵玲莉,赵光勇. 减阻剂的发展与应用[J]. 新疆石油天然气,2005,1(1):71-74.
[54] 尹国栋,高淮民‘陈少春,赵帆. 聚合物减阻机理研究[J]. 油气储运,2002,21(7):1-3.
[55]Hunston D . W . Drag reduction characteristic of polymer additives[J].Polym.Sci,1976,14:713～716
[56]宋波.应当重视减阻剂的开发[J].现代化工,1988,2:35～36
[57]Motier,J F and Prilutskl,D.J.Case histories of polymer drag reduction in crude oil lines[J].Pipe Line Industry,1985,(6):33～37
[58]宋昭峥,葛际江,张贵才.高蜡原油降凝剂发展概况[J].石油大学学报,2001,25(6):117～122
[59]邸进申,张诚,李英杰.原油流动改性剂的制备及应用[J].石油炼制与化工,1997,28(8):43～46
[60]樱井俊男.石油产品添加剂[M].石油产品添加剂翻译组译.北京石油工业出版社 1982:127～131
[61]周英兵.降凝剂结构与性能关系的研究[M].北京:石油大学,1990,99～123
[62]赵荣祥,曹祖宾,岳坤霞.降凝剂的应用概况.当代化工[J].2003,32(4):55～57
[63]Mendell,John L,Jessen,etal.Mechanism of inhihition of paraffin deposition in crude oil systems.American.SPE 2868-MS.1970
[64]王彪.原油降凝剂发展概况[J].精细石油化工,1989,(5);43～53
[65]汤建华,徐立群,潘浪胜等.原油降凝剂的研制与初步应用试验[J].精细石油化工,2001,(5):4～7
[65]Bott T R,Gudmundsson J S.Deposition of Paraffin Wax from Kerosene in Cooled Heat Exchangers[J].Chem.Eng.1997,381~385
[67]Smith.Bil1.Guidelines Set Out for Pum ping Heavy Crudes Oil and Gas[J].1995, 111~115
[68]敬加强,罗平亚,朱毅飞.原油组成对其粘度影响的灰色关联分析[J].油气田地面工程,2000,19(6):12～13
[69]赵福麟.采油化学[M].山东东营:石油大学出版社,1989:147～151
[70]赵国玺.表面活性剂物理化学[M].北京:北京大学出版社,1984:382～408
[71]张付生,王彪.几种原油降凝降粘剂作用机理的红外光谱合 X 射线衍射研究.油田化学[J].1995,12(4):345～352
[73]霍建中,郝金库,赵小军等.大港原油高效降凝剂的研制[J].精细石油化工,2002,(5):8～10
[74]刘清林,权忠舆.含蜡原油热处理过程中若于组分的作用[J].石油学报,1986,7(1):119～126
[75]庞万忠.原油降凝剂的作用机理及应用[J].石油学报,1995,16(2):125～128
[76]李传宪,张春光,孙德军.降凝剂结构性质对原油化学改性的影响及流变学改进机理[J].化学通报,2002,65(11):762～766
[77]刘忠晖.降凝剂的筛选、评价及机理探讨[J].油气储运,1994,13(6):20～23
[78] 吴志均,王浩. 固体润滑剂在中深定向并中降摩阻的现场试验[J]. 钻采工艺,2002,25(5):68-70.
[79] 辛寅昌,许动彬,康峰. 双环咪唑啉衍生物封端聚醚降摩阻性能研究[J]. 石油学报,2007,23(4):68-71.
[80]王丽娟,田军.聚合物型原油降凝剂的作用机理及应用[J].精细石油化工,1997(5):5～9
[81]韩振华.从稠油的流变性谈稠油试油系列工艺技术.油气井测试,1995,4(3)
[82]权忠舆.有关原油流变性与石油化学的讨论.油气储运,1996,15(10)
[83]天津大学化工原理教室.化工原理(上).天津科学技术出版社,1983
[78]尉小明,郑猛,白永林.稠油掺表面活性剂水溶液降粘机理研究[J].特种油气藏,2004,11(4):92～94
[84]ZaKi N N.Surfactant stabilized crude oi1-in-water emulsion for pipeline transportation of viseious crude oil[J].Colloid Surfaces,1997,125:19～25
[85]郭东红,江龙.辽河超稠原油的流变性质及其乳化降粘[J].化学通报,2002,10:
[86]Aiimed NS,NamerAM.ZaKi NN.Stability and theology of heavy oi1-in-water emulsion stabilized by an anionicnonionic surfactant mixture[J].Petrol sci Technol,1999,17:553～576
[87]吴明,申龙涉,杨惠达.含水原油流变规律试验研究[J].西安石油学院学报,2002,17(11):28-31
[88]黄福堂.原油在水中乳状液的特性[J].国外油田工程,1997,13(11):28～34
[89]江延明,李传宪.乳状液的流变性研究[J].油气储运,2000,19(1):10～12
[90]James Michael Jordan,Thomas James Denton.Method of removing dispersed oil from an oil in water emulsion employing aerated solutions within a coalescing media[P].US5656173,1997
[91]曹均合,麻金海,郭省学.乳化降粘剂 SB-2 乳化稠油机理研究[J].油田化学,2004,21(2):124～12
[92]陈宗其,王光信,徐桂英.胶体与界面化学[M].北京:高等教育出版社,2001, 8:34～41
[93] 李继山,姚同玉,刘卫东. 采油中的润湿热、粘附功和吸附焓变[J]. 石油大学学报, 2005,29(5):71-75. (LI Ji-shan,YAO Tong-yu,LIU Wei-dong. Wetting heat,adhesion work and adsorption enthalpy increment in oil recovery[J]. Journal of the University of Petroleum ,2005,29(5):71-75)
[94] 辛寅昌,姚良宏,安骏, 等.不同燃油节能添加剂台架试验节能效率的差别分析[J].节能, 2005, (12):12-18. (XIN Yin-chang, YAO Liang-hong, AN Jun, et al. The difference of fuel oil saving efficiency in bench scale test [J].Energy Conservation, 2005, (12):12-18.)
[95] 陈宗其, 王光信, 徐桂英. 胶体与界面化学[M]. 北京:高等教育出版社, 2001: 34-41.
[96] 李阳初, 王耀斌.石油化学工程基础[M].北京:石油大学出版社, 1997: 20-30.
[97] 庄礼贤,尹协远,马晖扬. 流体力学[M]. 合肥:中国科学技术大学出版社,1997:124-170.
[98] 张也影. 流体力学[M]. 高等教育出版社(第二版),1986:239-313.
[99] 孙寿家,郑彤,等. 减阻功能高分子的合成及其抗剪切稳定性的研究[J].石油学报(石油加工), 1999, 15(4): 57-61. (SUN Shou-jia,ZHENG Tong,CHEN Feng-xiang. Study on the synthesis of drag reduction poiymer plma and the shear stability[J].Acta Petrolei Sinica (Petroleum Processing Section),1999,15 (4):57 - 61.)
[2]邢其毅,徐瑞英,周政,等.基础有机化学(第二版)[M].北京:高等教育出版社,2000.106-109.
[3]徐燕莉.表面活性剂的功能[M].北京:化学工业出版社,2000.164-189.
[4]陈福良,王仪,郑斐能,等.农药微乳剂及其浊点问题的探讨和初步研究[J],农药.1999,38(3):9-10.
[5]杨树良.嵌段型非离子表面活性剂在微乳剂制备中的应用[J].农药,2006,45(2):106-110.
[6]刘建强,李玉香,马骏,等.表面活性剂在新型清洗剂中的应用研究[J].山东大学学报(理学版),2003,38(2):64-66.
[7]杨树良.非离子型高分子表面活性剂及其应用[J].日用化学工业,1990,(5):16-20.
[8]Patricia N,Hurter T,Alan Hatton.Solubilization of polycyclic aromatic hydrocarbons by poly(ethylene oxide-propylene oxide)block copolymer micelles:effects of polymerstructure[J].Langmuir,1992,8(5):1291~1299.
[9]Paterson I F,Chowdhry B Z,Leharne S A.Investigations of naphthalene solubilization in aqueous solutions of ethylene oxide-b-propylene oxide-b-ethylene oxide copolymers[J].Langmuir,1999,15(19):6187~6194.
[10]于飞.树枝状聚醚表面活性剂的合成与性能研究[M].大庆石油学院硕士学位论文,2007,3.
[11]周莉,吴奕光,戴旭映.PEP 聚醚型非离子表面活性剂的合成与性能研究[J].表面活性剂工业,1998,(4):23-26
[12]袁浩明.精细石油化工,1991,(3):29
[13]K.Koswsing.日用化学工业译丛.1956,13(1):7 一 11
[14]焦宇.双烷基 EO\PO 共聚醚的合成与表征[M].郑州大学硕士学位论文,2006,6.
[15]言敏达.聚醚的功能化[J].精细化工,2000,17(12)
[16]黄银霞.聚醚封端方法探讨[J].金陵石油化,1992,11(4):15-27
[17]黄银霞.不饱和聚醚封端方法探讨[J].聚氨酯工业,15(l):18-20
[18]尹红,黎松.醚化封端聚醚的技术进展.精细化工,2002,19:19-22
[19]晋心文.H 一 420 软泡匀泡剂[J].聚氨醋工业,2000,15(1):35-37
[20]NukinaShogo,KotaniEisaku.PreParationofglyeoldiether[P].jP:8228019 ,1982-02-15.
[21]YoshimuraNoriaki,TamuraMasuhiko.PreParationoftherifiedPolyoxyalkyleneComPounds of high quality[P].JP:7846905,1978,4
[22]辛寅昌,张盛军,邱增中.醚化封端聚醚的研究进展及应用[J].精细与专用化学品,2007,15(14).
[23]张士福,李迎,宋建平.烷基封端聚醚的制备及应用[J]. 上海化工,2001,26(2):24-26.
[24] Karl S M,Horst B L,et a1.Aqueous foam —inhibiting eo mpo si—tions containing alkyl polyethylene glycol alkyl ethers[P].US, US 4 548 729(1985).
[25] Joaqllim B L,Nuria B,et a1.Pmcess for the production of end一capped nonionic surfactants[P].US,US 5 847 229(1998).
[26] Bernd W K,Faize S D.Mercerizing and/or causticizing wetting a—gent:2 一ethyl— hexyl—sulfate and mixturc of alkyl end —blocked polyethers[P].US,US 5 013 327(1991).
[27] 张士福.ω -烷氧基聚醚的用途[J]. 金山油化纤,2003,(1.):25-29.
[28] Karl H S,Alfred M M ,et a1.Process for controUing foam in foodprocesingand production[P].US,US 4 942 049(1991).
[29] 杨颖霞,李永德. 有机硅在聚氨酯中的应用[J]. 聚氨酯工业,2002,17(3):31-33.
[30] 李玉松. 聚氨酯泡沫用有机硅匀泡剂的合成及应用[J]. 聚氨酯工业,2004,19(2):1-4.
[31] 黄文润. 特殊结构的有机硅表面活性剂[J]. 有机硅材料,2005,19(2):38-41.
[32] 李姜娜,尚丙坤,张杰. 建筑密封胶用有机硅改性聚醚的研究进展[J]. 聚氨酯工业,2004,19(4):1-4.
[33] 冯光炫,崔英德,卢奎,李和平. 油酸封端的C36--聚酸/PEG/PPG聚醋的合成及其消泡抑泡性能[J]. 日用化学工业,2006,36(2):76-80.
[34]李雅丽. 聚氨酯有机硅匀泡剂的研究及应用[J]. 应用化工,2006,35(2):84-85.
[35] 梁书恩,王建华,田春蓉,周秋明,芦艾. 匀泡剂对硬质聚氨酯泡沫孔径及冲击性能的影响[J]. 塑料助剂,2005,(3):25-27.
[36] 宋虹霞,郑银才,邓爱华. 高相对分子质量聚醚多元醇的环氧乙烷封端[J]. 高桥石化,2006,3( 21):1-5.
[37] 殷宁,亢茂青,冯月兰,张清运,瞿波,王心葵. 高活性超低单醇含量聚醚多元醇合成高回弹聚氨酯泡沫塑料的研究[J].化工新型材料,2003,5(31):31-34.
[38]K.Krossing.乙氧基化物.日用化学工业译丛.1986,(4):7 一 11
[39]PazosJoseF.ProeessForMakingEthyleneOxideeaPPedPolyosFromDoubleMetalCyanide CatalyzcdPolyols.US:5563221,1996,10
[40]颜再荣,吴立传,杨淑英等.用小分子调竹剂合成 DMC 聚醚.高分子材料科学与 l:程,2004,20(3):57 一 63
[41]王志新.DMC 催化剂及其在聚醚多元醇生产中的应用.聚氨酉旨 l 一业,2002,17(3):41-43
[42]秦旭东,秦怡生,王德和.双烷基封端聚醚的合成与应用.1999 年表面活性剂经济技术信息论文集,p223
[43]宋幸炜,王世普.新型封端聚醚的合成及应用.1999 年表面活性剂经济技术洁忘、沦文果,P251
[44]屈增录.硅改性聚醚的制法及在密封剂、胶粘剂中的应用[]z.黎明化工,1994,(40):1-4
[45]尹红.环氧乙烷环氧丙烷无规聚醚分子结构控制方法研究.浙江大学博士论文,1999
[46] 尹艳红,黎松. 醚化封端聚醚的技术进展[J]. 精细化工,2002,19(增):19-22.
[47]李玉松,徐敬宇,冯云.α-烯丙基齐聚氧化乙烯-氧化丙烯加密的合成[J]. 聚氨酯工业,2002,17(1):15-18.
[48]李玉松. 端烯丙基混嵌段聚氧化烯基甲醚的合成[J]. 精细石油化工,2004,(5):44-45.
[49]辛寅昌,张盛军,邱增中,赵明方.原油微观装态与降摩阻性能的研究[J].石油学报(石油加工),2008,4
[50]许东彬. 高粘原油的降摩阻性能研究[M].山东师范大学硕士论文,2007,4
[51]关中原,李春漫,尹国栋.EP 系列减阻剂的研制与应用[J].油气储运,2001,20(3):32～34
[52] 邵雪明,林建忠. 高聚物减阻机理的研究综述[J]. 浙江工程学院学报,2001,18(1):15-19. (SHAO Xue-ming,LIN Jian-zhong. Review of research on mechanism of drag reduction by polymer additives[J]. Joumal of Zhejiang Institute of Science and Technology,2001,18(1):15-19. )
[53] 马卫嵘,谭芳,赵玲莉,赵光勇. 减阻剂的发展与应用[J]. 新疆石油天然气,2005,1(1):71-74.
[54] 尹国栋,高淮民‘陈少春,赵帆. 聚合物减阻机理研究[J]. 油气储运,2002,21(7):1-3.
[55]Hunston D . W . Drag reduction characteristic of polymer additives[J].Polym.Sci,1976,14:713～716
[56]宋波.应当重视减阻剂的开发[J].现代化工,1988,2:35～36
[57]Motier,J F and Prilutskl,D.J.Case histories of polymer drag reduction in crude oil lines[J].Pipe Line Industry,1985,(6):33～37
[58]宋昭峥,葛际江,张贵才.高蜡原油降凝剂发展概况[J].石油大学学报,2001,25(6):117～122
[59]邸进申,张诚,李英杰.原油流动改性剂的制备及应用[J].石油炼制与化工,1997,28(8):43～46
[60]樱井俊男.石油产品添加剂[M].石油产品添加剂翻译组译.北京石油工业出版社 1982:127～131
[61]周英兵.降凝剂结构与性能关系的研究[M].北京:石油大学,1990,99～123
[62]赵荣祥,曹祖宾,岳坤霞.降凝剂的应用概况.当代化工[J].2003,32(4):55～57
[63]Mendell,John L,Jessen,etal.Mechanism of inhihition of paraffin deposition in crude oil systems.American.SPE 2868-MS.1970
[64]王彪.原油降凝剂发展概况[J].精细石油化工,1989,(5);43～53
[65]汤建华,徐立群,潘浪胜等.原油降凝剂的研制与初步应用试验[J].精细石油化工,2001,(5):4～7
[65]Bott T R,Gudmundsson J S.Deposition of Paraffin Wax from Kerosene in Cooled Heat Exchangers[J].Chem.Eng.1997,381~385
[67]Smith.Bil1.Guidelines Set Out for Pum ping Heavy Crudes Oil and Gas[J].1995, 111~115
[68]敬加强,罗平亚,朱毅飞.原油组成对其粘度影响的灰色关联分析[J].油气田地面工程,2000,19(6):12～13
[69]赵福麟.采油化学[M].山东东营:石油大学出版社,1989:147～151
[70]赵国玺.表面活性剂物理化学[M].北京:北京大学出版社,1984:382～408
[71]张付生,王彪.几种原油降凝降粘剂作用机理的红外光谱合 X 射线衍射研究.油田化学[J].1995,12(4):345～352
[73]霍建中,郝金库,赵小军等.大港原油高效降凝剂的研制[J].精细石油化工,2002,(5):8～10
[74]刘清林,权忠舆.含蜡原油热处理过程中若于组分的作用[J].石油学报,1986,7(1):119～126
[75]庞万忠.原油降凝剂的作用机理及应用[J].石油学报,1995,16(2):125～128
[76]李传宪,张春光,孙德军.降凝剂结构性质对原油化学改性的影响及流变学改进机理[J].化学通报,2002,65(11):762～766
[77]刘忠晖.降凝剂的筛选、评价及机理探讨[J].油气储运,1994,13(6):20～23
[78] 吴志均,王浩. 固体润滑剂在中深定向并中降摩阻的现场试验[J]. 钻采工艺,2002,25(5):68-70.
[79] 辛寅昌,许动彬,康峰. 双环咪唑啉衍生物封端聚醚降摩阻性能研究[J]. 石油学报,2007,23(4):68-71.
[80]王丽娟,田军.聚合物型原油降凝剂的作用机理及应用[J].精细石油化工,1997(5):5～9
[81]韩振华.从稠油的流变性谈稠油试油系列工艺技术.油气井测试,1995,4(3)
[82]权忠舆.有关原油流变性与石油化学的讨论.油气储运,1996,15(10)
[83]天津大学化工原理教室.化工原理(上).天津科学技术出版社,1983
[78]尉小明,郑猛,白永林.稠油掺表面活性剂水溶液降粘机理研究[J].特种油气藏,2004,11(4):92～94
[84]ZaKi N N.Surfactant stabilized crude oi1-in-water emulsion for pipeline transportation of viseious crude oil[J].Colloid Surfaces,1997,125:19～25
[85]郭东红,江龙.辽河超稠原油的流变性质及其乳化降粘[J].化学通报,2002,10:
[86]Aiimed NS,NamerAM.ZaKi NN.Stability and theology of heavy oi1-in-water emulsion stabilized by an anionicnonionic surfactant mixture[J].Petrol sci Technol,1999,17:553～576
[87]吴明,申龙涉,杨惠达.含水原油流变规律试验研究[J].西安石油学院学报,2002,17(11):28-31
[88]黄福堂.原油在水中乳状液的特性[J].国外油田工程,1997,13(11):28～34
[89]江延明,李传宪.乳状液的流变性研究[J].油气储运,2000,19(1):10～12
[90]James Michael Jordan,Thomas James Denton.Method of removing dispersed oil from an oil in water emulsion employing aerated solutions within a coalescing media[P].US5656173,1997
[91]曹均合,麻金海,郭省学.乳化降粘剂 SB-2 乳化稠油机理研究[J].油田化学,2004,21(2):124～12
[92]陈宗其,王光信,徐桂英.胶体与界面化学[M].北京:高等教育出版社,2001, 8:34～41
[93] 李继山,姚同玉,刘卫东. 采油中的润湿热、粘附功和吸附焓变[J]. 石油大学学报, 2005,29(5):71-75. (LI Ji-shan,YAO Tong-yu,LIU Wei-dong. Wetting heat,adhesion work and adsorption enthalpy increment in oil recovery[J]. Journal of the University of Petroleum ,2005,29(5):71-75)
[94] 辛寅昌,姚良宏,安骏, 等.不同燃油节能添加剂台架试验节能效率的差别分析[J].节能, 2005, (12):12-18. (XIN Yin-chang, YAO Liang-hong, AN Jun, et al. The difference of fuel oil saving efficiency in bench scale test [J].Energy Conservation, 2005, (12):12-18.)
[95] 陈宗其, 王光信, 徐桂英. 胶体与界面化学[M]. 北京:高等教育出版社, 2001: 34-41.
[96] 李阳初, 王耀斌.石油化学工程基础[M].北京:石油大学出版社, 1997: 20-30.
[97] 庄礼贤,尹协远,马晖扬. 流体力学[M]. 合肥:中国科学技术大学出版社,1997:124-170.
[98] 张也影. 流体力学[M]. 高等教育出版社(第二版),1986:239-313.
[99] 孙寿家,郑彤,等. 减阻功能高分子的合成及其抗剪切稳定性的研究[J].石油学报(石油加工), 1999, 15(4): 57-61. (SUN Shou-jia,ZHENG Tong,CHEN Feng-xiang. Study on the synthesis of drag reduction poiymer plma and the shear stability[J].Acta Petrolei Sinica (Petroleum Processing Section),1999,15 (4):57 - 61.)