基于半刚性双(噻唑基苯并咪唑)和不同羧酸的五个一维配合物的合成和表征（英文）

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英文篇名：Syntheses, Characterization and Crystal Structures of Five 1D Complexes Based on Semi-rigid Bis(thiazolylbenzimidazole) and Different Types of Carboxylic Acid Linkers 作者：刘露 ; 靳平宁 ; 李英 ; 娄慧慧 ; 王键吉 ; 张裕平 ; 侯红卫 ; 杜锦阁 英文作者：LIU Lu;JIN Ping-Ning;LI Ying;LOU Hui-Hui;WANG Jian-Ji;ZHANG Yu-Ping;HOU Hong-Wei;DU Jin-Ge;School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology;Xinxiang Medical University;School of Chemistry and Chemical Engineering, Henan Normal University;College of Chemistry and Molecular Engineering, Zhengzhou University;Department of Chemistry, Sanquan College of Xinxiang Medical University; 关键词：配合物 ; 半刚性配体 ; 羧酸 ; 晶体结构 英文关键词：complex;;semi-rigid ligand;;carboxylate;;crystal structure 中文刊名：WJHX 英文刊名：Chinese Journal of Inorganic Chemistry 机构：河南科技学院化学化工学院;新乡医学院;河南师范大学化学化工学院;郑州大学化学与分子工程学院;新乡医学院三全学院; 出版日期：2019-06-10 出版单位：无机化学学报 年：2019 期：v.35 基金：河南科技学院高层次人才科研启动项目;; 河南师范大学博士后科研项目;; 河南省博士后科研项目;; 河南省高等学校重点科研项目(No.16A150007);河南省高等学校重点科研项目(No.16A150060);; 河南科技学院标志性创新工程项目(No.2015BZ02)资助 语种：中文; 页：WJHX201906018 页数：9 CN：06 ISSN：32-1185/O6 分类号：150-158

摘要

通过水热或溶剂热合成的方法制备了5个一维配合物{[Zn(btbb)_(0.5)(m-phda)]·0.5H_2O}_n(1),{[Cd_2(btbb)(adtda)_2(H_2O)]·H_2O}_n(2),[Mn_2(btbb)(tbi)_2]_n(3),{[Cd(btbb)_(0.5)(3-Nitro-o-bdc)(H_2O)]·H_2O}_n(4)和[Cd_2(btbb)(tbi)_2]_n(5)(btbb=1,4-双(2-(4-噻唑基)苯并咪唑-1-基甲基)苯,m-H_2phda=间苯二甲酸,H_2adtda=1,3-金刚烷二羧酸,H_2tbi=5-叔丁基间苯二甲酸,3-Nitro-o-H_2bdc=3-硝基-1,2-苯二甲酸)。配合物1是一个包含22元环的一维链。配合物2是一个包含8元环的一维链,并且氮配体在这个一维链中仅仅起到装饰作用。配合物3是一个一维双链结构。配合物4是一个包含14元环的一维链。配合物5是一个阶梯状的一维双链结构。
        Five coordination complexes,formulated as{[Zn(btbb)_(0.5)(m-phda)]·0.5H_2O}_n(1),{[Cd_2(btbb)(adtda)_2(H_2O)]·H_2O}_n(2),[Mn_2(btbb)(tbi)_2]_n(3),{[Cd(btbb)_(0.5)(3-Nitro-o-bdc)(H_2O)]·H_2O}_n(4)and[Cd_2(btbb)(tbi)_2]_n(5)(btbb=1,4-bis(2-(4-thiazolyl)benzimidazole-1-ylmethyl)benzene,m-H_2phda=m-phenylenediacetic acid,H_2adtda=1,3-adamantanedicarboxylic acid,H_2tbi=5-tert-butylisophthalic acid,3-Nitro-o-H_2bdc=3-Nitro-1,2-benzenedicarboxylic acid),have been obtained by hydro(solv)thermal reactions and structurally characterized.Complex 1 exhibits a 1D chain structure containing 22-membered rings.Complex 2 features a 1D chain structure having an 8-membered rings and btbb serves only as an ornament here.Complex 3 is a 1D double chain structure.Complex 4 possesses a 1D chain structure containing 14-membered rings.Complex 5 shows a 1D double chain taking on stair-step.CCDC:1883643,1;1883644,2;1883645,3;1883646,4;1883647,5.

引文

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