摘要
通过水热或溶剂热合成的方法制备了5个一维配合物{[Zn(btbb)_(0.5)(m-phda)]·0.5H_2O}_n(1),{[Cd_2(btbb)(adtda)_2(H_2O)]·H_2O}_n(2),[Mn_2(btbb)(tbi)_2]_n(3),{[Cd(btbb)_(0.5)(3-Nitro-o-bdc)(H_2O)]·H_2O}_n(4)和[Cd_2(btbb)(tbi)_2]_n(5)(btbb=1,4-双(2-(4-噻唑基)苯并咪唑-1-基甲基)苯,m-H_2phda=间苯二甲酸,H_2adtda=1,3-金刚烷二羧酸,H_2tbi=5-叔丁基间苯二甲酸,3-Nitro-o-H_2bdc=3-硝基-1,2-苯二甲酸)。配合物1是一个包含22元环的一维链。配合物2是一个包含8元环的一维链,并且氮配体在这个一维链中仅仅起到装饰作用。配合物3是一个一维双链结构。配合物4是一个包含14元环的一维链。配合物5是一个阶梯状的一维双链结构。
Five coordination complexes,formulated as{[Zn(btbb)_(0.5)(m-phda)]·0.5H_2O}_n(1),{[Cd_2(btbb)(adtda)_2(H_2O)]·H_2O}_n(2),[Mn_2(btbb)(tbi)_2]_n(3),{[Cd(btbb)_(0.5)(3-Nitro-o-bdc)(H_2O)]·H_2O}_n(4)and[Cd_2(btbb)(tbi)_2]_n(5)(btbb=1,4-bis(2-(4-thiazolyl)benzimidazole-1-ylmethyl)benzene,m-H_2phda=m-phenylenediacetic acid,H_2adtda=1,3-adamantanedicarboxylic acid,H_2tbi=5-tert-butylisophthalic acid,3-Nitro-o-H_2bdc=3-Nitro-1,2-benzenedicarboxylic acid),have been obtained by hydro(solv)thermal reactions and structurally characterized.Complex 1 exhibits a 1D chain structure containing 22-membered rings.Complex 2 features a 1D chain structure having an 8-membered rings and btbb serves only as an ornament here.Complex 3 is a 1D double chain structure.Complex 4 possesses a 1D chain structure containing 14-membered rings.Complex 5 shows a 1D double chain taking on stair-step.CCDC:1883643,1;1883644,2;1883645,3;1883646,4;1883647,5.
引文
[1] Lu Z Z, Zhang R, Li Y Z, et al. J. Am. Chem. Soc., 2011,133:4172-4174
[2] Leininger S, Olenyuk B, Stang P J. Chem. Rev., 2000,100:853-908
[3] Hou L, Shi W J, Wang Y Y, et al. Chem. Commun., 2011,47:5464-5466
[4] Blake K M, Johnston L L, Nettleman J H, et al. CrystEngComm,2010,12:1927-1934
[5] Du J L, Hu T L, Zhang S M, et al. CrystEngComm, 2008,10:1866-1874
[6] YU Min(喻敏), XUAN Fang(宣芳), LIU Guang-Xiang(刘光祥). Chinese J. Inorg. Chem.(无机化学学报), 2019,35(1):133-140
[7] LIANG Li-Li(梁丽丽), LIU Cong-Sen(刘从森), ZONG ZhiHui(宗智慧), et al. Chinese J. Inorg. Chem.(无机化学学报), 2018,34(7):1365-1372
[8] LI Yu(黎彧), ZOU Xun-Zhong(邹训重), GU Jin-Zhong(顾金忠), et al. Chinese J. Inorg. Chem.(无机化学学报), 2018,34(6):1159-1165
[9] Hu J S, Shang Y J, Yao X Q, et al. Cryst. Growth Des.,2010,10:4135-4142
[10]Habib H A, Sanchiz J, Janiak C. Dalton Trans., 2008:1734-1744
[11]Yang E C, Liu Z Y, Shi X J, et al. Inorg. Chem., 2010,49:7969-7995
[12]Huang S L, Lin Y J, Andy Hor T S, et al. J. Am. Chem.Soc., 2013,135:8125-8128
[13]Bronisz R. Inorg. Chem., 2005,44:4463-4465
[14]Sheldrick G M. Acta Crystallogr. Sect. A:Found. Crystallogr.,2008,64:112-122