锂离子电池电化学阻抗谱研究综述
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摘要
自电动汽车问世以来,锂离子电池一直是制约其发展的瓶颈。电化学阻抗谱是一种电化学测量手段,在锂离子电池的性能研究中越来越受重视。综述了锂离子电池阻抗谱动力学参数随SOC、充放电倍率、温度等影响因素的变化规律,以及在锂离子电池状态检测中的应用,并展望了电化学阻抗谱在锂离子电池研究上的发展方向。
Since the birth of electric vehicle, lithium-ion batteries are the bottleneck restricting the development of electric vehicle all the time. Electrochemical impedance spectroscopy(EIS) is one of the methods used in the measurement of electrochemical performance, and getting more and more attention in the research of lithium-ion batteries. The law between dynamic parameter of EIS and SOC, charge/discharge rate, temperature were reviewed and the application in detection of lithium-ion batteries state was summarized. The prospects of the EIS research on lithium-ion batteries were also discussed.
Since the birth of electric vehicle, lithium-ion batteries are the bottleneck restricting the development of electric vehicle all the time. Electrochemical impedance spectroscopy(EIS) is one of the methods used in the measurement of electrochemical performance, and getting more and more attention in the research of lithium-ion batteries. The law between dynamic parameter of EIS and SOC, charge/discharge rate, temperature were reviewed and the application in detection of lithium-ion batteries state was summarized. The prospects of the EIS research on lithium-ion batteries were also discussed.
引文
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[2]郭凯.基于模型的锂离子电池SOC估计研究[D].北京:北京工业大学,2013.
[3] FARMANN A, WAAG W, SAUER D U. Application-specific electrical characterization of high power batteries with lithium titanate anodes for electric vehicles[J]. Energy, 2016, 112:294-306.
[4]朱基亮,杜翀,何亮明,等.锂离子电池的热稳定性和大电流充放电稳定性研究[J].四川大学学报:工程科学版, 2011, 43(4):205-208.
[5]席安静,田光宇,白鹏.磷酸铁锂锂离子电池EIS参数随SOC变化的规律[J].电池,2012, 42(2):77-80.
[6]张文华,裴锋,刘平,等.磷酸铁锂电池循环过程中电化学交流阻抗研究[J].电源技术, 2015, 39(1):54-57.
[7]姜久春,时玮,张言茹,等.磷酸铁锂动力电池阻抗谱参数分析[J].北京理工大学学报, 2014(5):470-474.
[8]袁翔,张毅.动力锂电池阻抗特性的分析与验证[J].汽车工程学报, 2014, 4(6):447-454.
[9] XIE Y, LI J, YUAN C. Mathematical modeling of the electrochemical impedance spectroscopy in lithium ion battery cycling[J]. Electrochimica Acta, 2014, 127:266-275.
[10]王惠娟,郭利健.电化学阻抗谱在锂电池状态检测中的应用[J].电源技术, 2014, 38(1):73-74.
[11] ZHU J G, SUN Z C, WEI X Z, et al. A new lithium-ion battery internal temperature on-line estimate method based on electrochemical impedance spectroscopy measurement[J]. Journal of Power Sources, 2014, 274:990-1004.
[12] BEELEN H P G J, RAIJMAKERS L H J, DONKERS M C F, et al.A comparison and accuracy analysis of impedance-based temperature estimation methods for Li-ion batteries[J]. Applied Energy,2016, 175:128-140.
[13] ANDRE D, MEILER M, STEINER K, et al. Characterization of high-power lithium-ion batteries by electrochemical impedance spectroscopy. I. Experimental investigation[J]. Journal of Power Sources, 2011, 196(12):5349-5356.
[14] ITAGAKI M, HONDA K, HOSHI Y, et al. In-situ EIS to determine impedance spectra of lithium-ion rechargeable batteries during charge and discharge cycle[J]. Journal of Electroanalytical Chemistry, 2015, 737:78-84.
[15]成少安,张鉴清,刘鸿,等. MH-Ni电池循环衰退的电化学阻抗谱分析[J].电源技术, 1999,23(s1):62-63.
[16]张彩萍,姜久春,张维戈,等.梯次利用锂离子电池电化学阻抗模型及特性参数分析[J].电力系统自动化, 2013, 37(1):54-58.
[17]徐鑫珉,王练,史慧玲.基于电化学阻抗谱的电池老化寿命研究[J].电源技术, 2015, 39(12):2579-2583.
[2]郭凯.基于模型的锂离子电池SOC估计研究[D].北京:北京工业大学,2013.
[3] FARMANN A, WAAG W, SAUER D U. Application-specific electrical characterization of high power batteries with lithium titanate anodes for electric vehicles[J]. Energy, 2016, 112:294-306.
[4]朱基亮,杜翀,何亮明,等.锂离子电池的热稳定性和大电流充放电稳定性研究[J].四川大学学报:工程科学版, 2011, 43(4):205-208.
[5]席安静,田光宇,白鹏.磷酸铁锂锂离子电池EIS参数随SOC变化的规律[J].电池,2012, 42(2):77-80.
[6]张文华,裴锋,刘平,等.磷酸铁锂电池循环过程中电化学交流阻抗研究[J].电源技术, 2015, 39(1):54-57.
[7]姜久春,时玮,张言茹,等.磷酸铁锂动力电池阻抗谱参数分析[J].北京理工大学学报, 2014(5):470-474.
[8]袁翔,张毅.动力锂电池阻抗特性的分析与验证[J].汽车工程学报, 2014, 4(6):447-454.
[9] XIE Y, LI J, YUAN C. Mathematical modeling of the electrochemical impedance spectroscopy in lithium ion battery cycling[J]. Electrochimica Acta, 2014, 127:266-275.
[10]王惠娟,郭利健.电化学阻抗谱在锂电池状态检测中的应用[J].电源技术, 2014, 38(1):73-74.
[11] ZHU J G, SUN Z C, WEI X Z, et al. A new lithium-ion battery internal temperature on-line estimate method based on electrochemical impedance spectroscopy measurement[J]. Journal of Power Sources, 2014, 274:990-1004.
[12] BEELEN H P G J, RAIJMAKERS L H J, DONKERS M C F, et al.A comparison and accuracy analysis of impedance-based temperature estimation methods for Li-ion batteries[J]. Applied Energy,2016, 175:128-140.
[13] ANDRE D, MEILER M, STEINER K, et al. Characterization of high-power lithium-ion batteries by electrochemical impedance spectroscopy. I. Experimental investigation[J]. Journal of Power Sources, 2011, 196(12):5349-5356.
[14] ITAGAKI M, HONDA K, HOSHI Y, et al. In-situ EIS to determine impedance spectra of lithium-ion rechargeable batteries during charge and discharge cycle[J]. Journal of Electroanalytical Chemistry, 2015, 737:78-84.
[15]成少安,张鉴清,刘鸿,等. MH-Ni电池循环衰退的电化学阻抗谱分析[J].电源技术, 1999,23(s1):62-63.
[16]张彩萍,姜久春,张维戈,等.梯次利用锂离子电池电化学阻抗模型及特性参数分析[J].电力系统自动化, 2013, 37(1):54-58.
[17]徐鑫珉,王练,史慧玲.基于电化学阻抗谱的电池老化寿命研究[J].电源技术, 2015, 39(12):2579-2583.