锂离子电池热失效机理和致爆时间研究综述
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摘要
随着锂离子电池的不断推广,锂离子电池的安全性越来越受到关注。由于工作条件以及工作环境等的原因,锂离子电池可能工作在一些极端条件如高温、低温下;或者未按规定使用电池,使其工作在过充、过放、短路、冲击等极端条件下,这些可能导致电池发生意外如着火或者爆炸等。从导致锂离子电池爆炸的原因着手,分类综述研究了锂离子电池致爆机理和爆炸时间。
With the continuous promotion of lithium-ion batteries,their safety are attracting more and more attention. When they work under extreme environment conditions,such as high and low temperature,or when they are not used according to regulations,such that they are over-charged,over-discharged,under short-circuit or impact, there will be accidents, e.g., explosion or fire. In this paper, the explosion mechanism and explosion time of lithium-ion batteries are classified and reviewed according to several causes to explosion.
With the continuous promotion of lithium-ion batteries,their safety are attracting more and more attention. When they work under extreme environment conditions,such as high and low temperature,or when they are not used according to regulations,such that they are over-charged,over-discharged,under short-circuit or impact, there will be accidents, e.g., explosion or fire. In this paper, the explosion mechanism and explosion time of lithium-ion batteries are classified and reviewed according to several causes to explosion.
引文
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[16]刘丽华,莫梁君.锂离子电池过充电保护实验中着火、爆炸原因分析[J].科技资讯,2009(17):9-10.
[17]单明新,王松岑,朱艳丽,等.锂离子电池过充爆炸强度试验研究[J].安全与环境学报,2005,15(5):116-118.Shan Mingxin,Wang Songcen,Zhu Yanli,et al.Study on the burst intensity of lithium-ion batteries due to overcharge[J].Journal of Safety and Environment,2005,15(5):116-118(in Chinese).
[18]Ye Jiana,Chen Haodong,Wang Qingsong,et al.Thermal behavior and failure mechanism of lithium ion cells during overcharge under adiabatic conditions[J].Applied Energy,2016,182:464-474.
[19]Kitoh K,Nemoto H.100 Wh large size Li-ion batteries and safetytests[J].Journal of Power Sources,1999,s81-82(9):887-890.
[20]王莉,李建军,高剑,等.钴酸锂正极锂离子电池的过充电安全性[J].电池,2012,42(6):299-301.Wang Li,Li Jianjun,Gao Jian,et al.Overcharge safety of Li-ion battery with lithium cobalt oxide cathode[J].Battery Bimonthly,2012,42(6):299-301(in Chinese).
[21]Qian Guannan,Wang Li,Shang Yuming,et al.Polyimide binder:A facile way to improve safety of lithium ion batteries[J].Electrochimica Acta,2015,187:113-118.
[22]Li Xinrui,Koseki H.A study on hazard of lithium and lithium-ion batteries[J].Explosive Materials,2013,42(5):1-5.
[2]杨晖.锂离子电池热爆炸机理的研究[C].第二十七届全国化学与物理电源学术年会.广州,中国,2006:245-246.Yang Hui.Study on thermal explosion mechanism of lithium-ion batteries[C].Proceedings of the Twenty-seventh Annual Conference on Chemistry and physics.Guangzhou,China,2006:245-246(in Chinese).
[3]Yayathi S,Walker W,Doughty D,et al.Energy distribution exhibited during thermal runaway of commercial lithium ion batteries used for human spaceflight applications[J].Journal of Power Sources,2016,329:197-206.
[4]雷治国,张承宁,李军求.电动车辆用锂离子电池热特性研究[J].电源学报,2014,12(4):83-87.Lei Zhiguo,Zhang Chengning,Li Junqiu.Research on thermal characteristics of EVs lithium-ion battery[J].Journal of Power Supply,2014,12(4):83-87(in Chinese).
[5]陈玉红,唐致远,卢星河,等.锂离子电池爆炸机理研究[J].化学进展,2006,18(6):823-831.Chen Yuhong,Tang Zhiyuan,Lu Xinghe,et al.Research of explosion mechanism of lithium-ion battery[J].Progress in Chemistry,2006,18(6):823-831(in Chinese).
[6]Zhang Zhengming,Ramadass P,Fang Weifeng.Safety of lithium-ion batteries[J].Chapter,2014(18):409-435.
[7]Doughty D H.Li-ion battery abuse tolerance testing-an overview[J].USA:Sandia National Laboratories,2006.
[8]Spotnitz R,Franklin J.Abuse behavior of high-power lithium-ion cells[J].Journal of Power Sources,2003,113(1):81-100.
[9]陈玉红,唐致远,贺艳兵,等.锂离子电池爆炸机理分析[J].电化学,2006,12(3):266-270.Chen Yuhong,Tang Zhiyuan,He Yanbing,et al.Research of explosion mechanism of lithium-ion battery[J].Electrochemistry,2006,12(3):266-270(in Chinese).
[10]杨中发,王庆杰,石斌,等.锂亚硫酰氯电池的高温性能研究[J].电池,2013,43(4):215-218.Yang Zhongfa,Wang Qingjie,Shi Bin,et al.Study on high temperature performance of lithium thionyl chloride battery[J].Battery Bimonthly,2013,43(4):215-218(in Chinese).
[11]罗庆凯,王志荣,刘婧婧,等.18650型锂离子电池热失控影响因素[J].电源技术,2016,40(2):277-279.Luo Qingkai,Wang Zhirong,Liu Jingjing,et al.Influencing factors of thermal runaway of 18650 lithium ion battery[J].Chinese Journal of Power Sources,2016,40(2):277-279(in Chinese).
[12]Tobishima S,Takei K,Sakurai Y,et al.Lithium ion cell safety[J].Journal of Power sources,2000,90(2):188-195.
[13]Tobishima S,Yamaki J.A consideration of lithium cell safety[J].Journal of Power Sources,1999,s81-82(9):882-886.
[14]Ohsaki T,Kishi T,Kuboki T,et al.Overcharge reaction of lithium-ion batteries[J].Journal of Power Sources,2005,146(1):97-100.
[15]杨娟玉,卢世刚,刘莎,等.混合电动汽车用锂离子电池的研究[J].电池,2007,37(2):104-106.Yang Juanyu,Lu Shigang,Liu Sha,et al.Study on the Liion battery for HEV[J].Battery Bimonthly,2007,37(2):104-106(in Chinese).
[16]刘丽华,莫梁君.锂离子电池过充电保护实验中着火、爆炸原因分析[J].科技资讯,2009(17):9-10.
[17]单明新,王松岑,朱艳丽,等.锂离子电池过充爆炸强度试验研究[J].安全与环境学报,2005,15(5):116-118.Shan Mingxin,Wang Songcen,Zhu Yanli,et al.Study on the burst intensity of lithium-ion batteries due to overcharge[J].Journal of Safety and Environment,2005,15(5):116-118(in Chinese).
[18]Ye Jiana,Chen Haodong,Wang Qingsong,et al.Thermal behavior and failure mechanism of lithium ion cells during overcharge under adiabatic conditions[J].Applied Energy,2016,182:464-474.
[19]Kitoh K,Nemoto H.100 Wh large size Li-ion batteries and safetytests[J].Journal of Power Sources,1999,s81-82(9):887-890.
[20]王莉,李建军,高剑,等.钴酸锂正极锂离子电池的过充电安全性[J].电池,2012,42(6):299-301.Wang Li,Li Jianjun,Gao Jian,et al.Overcharge safety of Li-ion battery with lithium cobalt oxide cathode[J].Battery Bimonthly,2012,42(6):299-301(in Chinese).
[21]Qian Guannan,Wang Li,Shang Yuming,et al.Polyimide binder:A facile way to improve safety of lithium ion batteries[J].Electrochimica Acta,2015,187:113-118.
[22]Li Xinrui,Koseki H.A study on hazard of lithium and lithium-ion batteries[J].Explosive Materials,2013,42(5):1-5.