环胶州湾河流入海口CDOM吸收光谱特征
|
摘要
为深入认识河流对胶州湾水体有机碳的贡献,于2016年4月—2017年2月对环胶州湾河流入海口进行双月采样,通过分析水体中DOC(溶解有机碳)和POC(颗粒有机碳)质量浓度及CDOM(有色溶解有机物)的吸收光谱特征,揭示环胶州湾入海口有机碳的分布特征,辨析CDOM的组成和来源,探讨其与主要环境因素的关系.结果表明:(1)环胶州湾河流入海口DOC和POC质量浓度范围分别为0.98~32.75和0.13~22.40 mg/L,其中李村河口最高,轮渡和大港相对较小.(2)a(355)(CDOM的吸收系数)变化范围为0.23~16.35 m-1,存在明显的季节性差异,与盐度成反比,其分布与DOC和POC基本一致.(3)研究区域水体中,表征CDOM分子组成、来源及芳香化程度的SR[光谱斜率比,Sg(275~295 nm)/Sg(350~400 nm)]和A250 nm/A365 nm存在显著的时空差异.(4)夏季、秋季CDOM的整体分子量水平高于春季、冬季;轮渡、大港、板桥坊河和娄山河SR相对较高,CDOM组成趋向于蛋白类或富里酸类物质.(5)轮渡、大港和镰湾河A250 nm/A365 nm相对较高,类腐殖质的芳香化程度较低,受海源控制;其他河口A250 nm/A365 nm相对较低,CDOM以陆源输入为主,其类腐殖质的芳香化程度较高,结构相对稳定而不易降解.(6)CCA(Canonical Correspond Analysis,典范对应分析)结果表明,DOC与CDOM吸收特性存在较好的相关性,河口CDOM主要来自地表径流,温度和DO是影响CDOM时空分布的主要因素.研究显示,CDOM的组成、降解的难易程度与来源密切相关,秋季生物量丰富,水体中腐殖酸所占比例增大,CDOM芳香度较高,不容易被降解.
In order to demonstrate the relative contribution of organic carbon from rivers to the Jiaozhou Bay and associated environmental factors,water samples were collected in each two months,and dissolved organic carbon(DOC),particle organic carbon(POC) and UV-vis absorption of chromophoric dissolved organic matter(CDOM) were analyzed from April 2016 to February 2017 at the estuaries of Jiaozhou Bay. The results showed that:(1) DOC and POC ranged at 0. 98-32. 75 and 0. 13-22. 40 mg/L at the estuaries of Jiaozhou Bay,respectively,in which higher contents were located in Licun estuary and lower contents in Lundu and Dagang areas.(2) The absorption coefficient(a(355)) is between 0. 23 and 16. 35 m-1,obvious seasonal differences among them,and negatively related with salinity,which presented similar patterns with those of DOC and POC.(3) Being used to indicate the molecular compositions,sources and aromatization degree of CDOM,the parameters of spectral slope ratio SR(Sg(275-295 nm)/Sg(350-400 nm)) and absorbance ratio A250 nm/A365 nmsignificantly varied in space and time.(4) SRvalues were relative higher in Lundu,Dagang,Banqiaofang estuary and Loushan estuary,where CDOM tended to be composed by protein or fulvic acid substances. Meanwhile,the whole molecular weight of CDOM in summer and autumn is higher than that in spring and winter.(5) A250 nm/A365 nmratios stayed higher in Lundu,Dagang and Lianwan estuary,where like-humus presented in lower aromatization degrees and CDOM compositions were primarily controlled byproduction in situ in seawaters. A250 nm/A365 nmat the other estuaries were relative low,where CDOM compositions were mostly contributed by the terrestrial input with higher aromatization degrees,implying that CDOM were more stable and hard to be degraded.(6) CCA analysis show that CDOM absorption closely correlated with environmental factors. It was suggested that,CDOM at the estuaries of Jiaozhou Bay were significantly contributed by riverine input,and temperature and DO greatly impacted on the CDOM special and temporal distributions. The research shows,it existed closely relationship among the composition and degradation degree and sources of CDOM. In autumn,the proportion of humic acid in water increased because of abundant biomass,and the aromaticity of CDOM increased,and not easy to be degraded.
In order to demonstrate the relative contribution of organic carbon from rivers to the Jiaozhou Bay and associated environmental factors,water samples were collected in each two months,and dissolved organic carbon(DOC),particle organic carbon(POC) and UV-vis absorption of chromophoric dissolved organic matter(CDOM) were analyzed from April 2016 to February 2017 at the estuaries of Jiaozhou Bay. The results showed that:(1) DOC and POC ranged at 0. 98-32. 75 and 0. 13-22. 40 mg/L at the estuaries of Jiaozhou Bay,respectively,in which higher contents were located in Licun estuary and lower contents in Lundu and Dagang areas.(2) The absorption coefficient(a(355)) is between 0. 23 and 16. 35 m-1,obvious seasonal differences among them,and negatively related with salinity,which presented similar patterns with those of DOC and POC.(3) Being used to indicate the molecular compositions,sources and aromatization degree of CDOM,the parameters of spectral slope ratio SR(Sg(275-295 nm)/Sg(350-400 nm)) and absorbance ratio A250 nm/A365 nmsignificantly varied in space and time.(4) SRvalues were relative higher in Lundu,Dagang,Banqiaofang estuary and Loushan estuary,where CDOM tended to be composed by protein or fulvic acid substances. Meanwhile,the whole molecular weight of CDOM in summer and autumn is higher than that in spring and winter.(5) A250 nm/A365 nmratios stayed higher in Lundu,Dagang and Lianwan estuary,where like-humus presented in lower aromatization degrees and CDOM compositions were primarily controlled byproduction in situ in seawaters. A250 nm/A365 nmat the other estuaries were relative low,where CDOM compositions were mostly contributed by the terrestrial input with higher aromatization degrees,implying that CDOM were more stable and hard to be degraded.(6) CCA analysis show that CDOM absorption closely correlated with environmental factors. It was suggested that,CDOM at the estuaries of Jiaozhou Bay were significantly contributed by riverine input,and temperature and DO greatly impacted on the CDOM special and temporal distributions. The research shows,it existed closely relationship among the composition and degradation degree and sources of CDOM. In autumn,the proportion of humic acid in water increased because of abundant biomass,and the aromaticity of CDOM increased,and not easy to be degraded.
引文
[1]COBLE P G.Marine optical biogeochemistry:the chemistry of ocean color[J].Chemical reviews,2007,107(2):402-418.
[2]ROCHELLE-NEWALL E J,FISHER T R.Chromophoric dissolved organic matter and dissolved organic carbon in Chesapeake Bay[J].Marine Chemistry,2002,77(1):23-41.
[3]FERRARI G M,DOWELL M D,GROSSI S,et al.Relationship between the optical properties of chromophoric dissolved organic matter and total concentration of dissolved organic carbon in the southern Baltic Sea Region[J].Marine Chemistry,1996,55(3/4):299-316.
[4]KIRK J T O.Light and photosynthesis in aquatic ecosystems[M].England:Cambridge University Press,1994.
[5]FERRARI G M.The relationship between chromophoric dissolved organic matter and dissolved organic carbon in the European Atlantic Coastal Area and in the West Mediterranean Sea(Gulf of Lions)[J].Marine Chemistry,2000,70(4):339-357.
[6]CARDER K L,STEWARD R G,HARVEY G R,et al.Marine humic and fulvic acids:their effects on remote sensing of ocean chlorophyll[J].Limnology and oceanography,1989,34(1):68-81.
[7]DE SOUZA SIERRA M M,DONARD O F X,LAMOTTE M.Spectral identification and behaviour of dissolved organic fluorescent material during estuarine mixing processes[J].Marine Chemistry,1997,58(1/2):51-58.
[8]陈欣,张霄宇,雷惠.长江口CDOM的光谱吸收特征以及DOC物源示踪意义[J].海洋环境科学,2012(5):625-630.CHEN Xin,ZHANG Xiaoyu,LEI Hui.Optical absorption properties of CDOM and tracing implication of DOC in the Changjiang Estuary[J].Marine Environmental Science,2012(5):625-630.
[9]COBLE P G,DEL CASTILLO C E,AVRIL B,et al.Distribution and optical properties of CDOM in the Arabian Sea during the 1995southwest Monsoon[J].Deep Sea Research Part II:Topical Studies in Oceanography,1998,45(1011):2195-2223.
[10]KIEBER R J,ZHOU X,MOPPER K.Formation of carbonyl compounds from UV-induced photodegradation of humic substances in natural waters:fate of riverine carbon in the sea[J].Limnology and Oceanography,1990,35(7):1503-1515.
[11]王福利,郭卫东.秋季南海珠江口和北部湾溶解有机物的光降解[J].环境科学学报,2010,30(3):606-613.WANG Fuli,GUO Weidong.Photodegradation of DOM in the Pearl River Estuary and the Beibu Gulf of the South China sea in autumn[J].Acta Scientiae Circumstantiae,2010,30(3):606-613.
[12]张运林,秦伯强.梅梁湾.大太湖夏季和冬季CDOM特征及可能来源分析[J].水科学进展,2007,18(3):415-423.ZHANG Yunlin,QIN Boqiang.Feature of CDOM and its possible source in Meiliang Bay and Da Taihu Lake in Taihu Lake in summer and winter[J].Advances in Water Science,2007,18(3):415-423.
[13]NELSON N B,SIEGEL D A,MICHAELS A F.Seasonal dynamics of colored dissolved material in the Sargasso Sea[J].Deep Sea Research PartⅠ:Oceanographic Research Papers,1998,45(6):931-957.
[14]DEL CASTILLO C E,COBLEA P G,MORELL J M,et al.Analysis of the optical properties of the Orinoco River plume by absorption and fluorescence spectroscopy[J].Marine Chemistry,1999,66(1/2):35-51.
[15]杨阳,邹立,简慧敏.辽河口秋季有色溶解有机物的光谱特征研究[J].海洋环境科学,2017,36(1):94-100.YANG Yang,ZOU Li,JIAN Huimin.Spectral characteristics of chromophoric dissolved organic matter in Liaohe River estuary in autumn[J].Marine Environmental Science,2017,36(1):94-100.
[16]郭卫东,黄建平,洪华生,等.河口区溶解有机物三维荧光光谱的平行因子分析及其示踪特性[J].环境科学,2010,31(6):1419-1427.GUO Weidong,HUANG Jianping,HONG Huasheng,et al.Resolving excitation emission matrix spectroscopy of estuarine CDOM with parallel factor analysis and its application in organic pollution monitoring[J].Environmental Science,2010,31(6):1419-1427.
[17]VIGNUDELLI S,SANTINELLI C,MURRU E,et al.Distributions of dissolved organic carbon(DOC)and chromophoric dissolved organic matter(CDOM)in coastal waters of the northern Tyrrhenian Sea(Italy)[J].Estuarine,Coastal and Shelf Science,2004,60(1):133-149.
[18]COBLE P G.Characterization of marine and terrestrial DOM in seawater using excitation-emission matrix spectroscopy[J].Marine Chemistry,1996,51(4):325-346.
[19]郭卫东,程远月,吴芳.海洋荧光溶解有机物研究进展[J].海洋通报,2007,26(6):98-106.GUO Weidong,CHENG Yuanyue,WU Fang.An overview of marine fluorescent dissolved organic matter[J].Journal of Marine Science Bulletin,2007,26(6):98-106.
[20]程远月,郭卫东,胡明辉.近岸沉积物再悬浮期间所释放溶解有机物的荧光特征[J].地球化学,2008,37(1):51-58.CHEN Yuanyue,GUO Weidong,HU Minghui.Fluorescence characteristics of dissolved organic matter released from estuarine sediments during resuspension[J].Geochimica,2008,37(1):51-58.
[21]BURDIGE D J,KLINE S W,CHEN W.Fluorescent dissolved organic matter in marine sediment pore waters[J].Marine Chemistry,2004,89(1):289-311.
[22]蒋凤华,杨黄浩,黎先春,等,胶州湾海水溶解有机物三维荧光特征研究[J].光谱学与光谱分析,2007,27(9):1765-1769.JIANG Fenghua,YANG Huanghao,LI Xianchun,et al.Excitationemission-matrix spectral property of dissolved organic matter in seawater of Jiaozhou Bay,China[J].Spectroscopy and Spectral Analysis,2007,27(9):1765-1769.
[23]季乃云,赵卫红,王江涛,等.大沽河-胶州湾段溶解有机物类腐殖质荧光特征变化[J].环境科学,2006,27(6):1073-1077.JI Naiyun,ZHAO Weihong,WANG Jiangtao,et al.Change of humic-like fluorescence characteristics of dissolved organic matter from Dagu River to Jiaozhou Bay[J].Environmental Science,2006,27(6):1073-1077.
[24]鲁景亮.胶州湾溶解有机物荧光特征解析及水母暴发的潜在影响研究[D].青岛:中国科学院海洋研究所,2013.
[25]刘瑛,周倩倩,王江涛.秋季胶州湾有色溶解有机物荧光特性研究及其来源分析[J].中国海洋大学学报:自然科学版,2014(6):60-66.LIU Ying,ZHOU Qianqian,WANG Jiangtao.Source and fluorescence characteristics of chromophoric dissolved organic matter in Jiaozhou Bay in autumn[J].Periodical of Ocean University of China,2014(6):60-66.
[26]SHARP J H,CARLSON C A,PELTZER E T,et al.Final dissolved organic carbon broad community intercalibration and preliminary use of DOC reference materials[J].Marine Chemistry,2002,77(4):239-253.
[27]GREEN S A,BLOUGH N V.Optical absorption and fluorescence properties of chromophoric dissolved organic matter in natural waters[J].Limnology and Oceanography,1994,39(8):1903-1916.
[28]BROWN M.Transmission spectroscopy examinations of natural waters:C.Ultraviolet spectral characteristics of the transition from terrestrial humus to marine yellow substance[J].Estuarine and Coastal Marine Science,1977,5(3):309-317.
[29]STEDMON C A,MARKAGER S,KAAS H.Optical properties and signatures of chromophoric dissolved organic matter(CDOM)in Danish coastal waters[J].Estuarine,Coastal and Shelf Science,2000,51(2):267-278.
[30]李宁.长江口与胶州湾海水有机碳的分布,来源及与氮,磷的耦合关系[D].青岛:中国科学院海洋研究所,2006.
[31]梁成菊.青岛近海有机碳的分布特征及影响因素[D].青岛:中国海洋大学,2008.
[32]PEACOCK M,BURDEN A,COOPER M,et al.Quantifying dissolved organic carbon concentrations in upland catchments using phenolic proxy measurements[J].Journal of Hydrology,2013,477(1):251-260.
[33]OSBURN C L,BOYD T J,MONTGOMERY M T,et al.Optical proxies for terrestrial dissolved organic matter in estuaries and coastal waters[J].Frontiers in Marine Science,2016,2(127):1-15.
[34]GUGUEN C,GUO L,TANAKA N.Distributions and characteristics of colored dissolved organic matter in the western Arctic Ocean[J].Continental Shelf Research,2005,25(10):1195-1207.
[35]HOGE F E,VODACEK A,BLOUGH N V.Inherent optical properties of the ocean:retrieval of the absorption coefficient of chromophoric dissolved organic matter from fluorescence measurements[J].Limnology and Oceanography,1993,38(7):1394-1402.
[36]GUO W,YANG L,ZHAI W,et al.Runoff-mediated seasonal oscillation in the dynamics of dissolved organic matter in different branches of a large bifurcated estuary:the Changjiang Estuary[J].Journal of Geophysical Research:Biogeosciences,2014,119(5):776-793.
[37]江俊武,李帅东,沈胤胤,等.夏季太湖CDOM光学特性空间差异及其来源解析[J].环境科学研究,2017,30(7):1020-1030.JIANG Junwu,LI Shuaidong,SHEN Yinyin,et al.Spatial differences of optical properties of CDOM and their source apportionment in Taihu Lake in summer[J].Research of Environmental Sciences,2017,30(7):1020-1030.
[38]DEL VECCHIO R,BLOUGH N V.Spatial and seasonal distribution of chromophoric dissolved organic matter and dissolved organic carbon in the Middle Atlantic Bight[J].Marine Chemistry,2004,89(1):169-187.
[39]HELMS J R,STUBBINS A,RITCHIE J D,et al.Absorption spectral slopes and slope ratios as indicators of molecular weight,source,and photobleaching of chromophoric dissolved organic matter[J].Limnology and Oceanography,2008,53(3):955-969.
[40]李会杰.腐殖酸和富里酸的提取与表征研究[D].武汉:华中科技大学,2012.
[41]牛城,张运林,朱广伟,等.天目湖流域DOM和CDOM光学特性的对比[J].环境科学研究,2014,27(9):998-1007.NIU Cheng,ZHANG Yunlin,ZHU Guangwei,et al.Comparison of optical properties of DOM and CDOM in Lake Tianmuhu Catchment[J].Research of Environmental Sciences,2014,27(9):998-1007.
[42]张运林,陈伟民,周万平,等.2001-2002年天目湖(沙河水库)浮游植物的生态学研究[J].海洋湖沼通报,2006(2):31-37.ZHANG Yunlin,CHEN Weimin,ZHOU Wanping,et al.Ecological study on the phytoplankton in Lake Tianmu from 2001 to 2002[J].Transactions of Oceanology and Limnology,2006(2):31-37.
[43]SPENCER R G M,STUBBINS A,HERNES P J,et al.Photochemical degradation of dissolved organic matter and dissolved lignin phenols from the Congo River[J].Journal of Geophysical Research:Biogeosciences,2009.doi.10.1029/2009JG000968.
[44]胡素征,李桂菊,李奕洁,等.长江口有色溶解有机物光谱特性及其示踪溶解有机碳研究[J].天津科技大学学报,2015(3):57-61.HU Suzheng,LI Guiju,LI Yijie,et al.Optical absorption properties of chromophoric dissolved organic matter and the tracing implication of dissolved organic carbon in the Yangtze River Estuary[J].Journal of Tianjin University of Science&Technology,2015(3):57-61.
[45]PEURAVUORI J,PIHLAIA K.Molecular size distribution and spectroscopic properties of aquatic humic substances[J].Analytica Chimica Acta,1997,337(2):133-149.
[46]SANTOS L,PINTO A,FILIPE O,et al.Insights on the optical properties of estuarine DOM-hydrological and biological influences[J].Plos One,2016,11(5):1-26.
[47]LI P,HUR J.Utilization of UV-Vis spectroscopy and related data analyses for dissolved organic matter(DOM)studies:a review[J].Critical Reviews in Environmental Science and Technology,2017,47(3):131-154.
[48]HARVEY G R,BORAN D A,CHESAL L A,et al.The structure of marine fulvic and humic acids[J].Marine Chemistry,1983,12(2/3):119-132.
[49]RODRGUEZ F J,SCHLENGER P,GARCA-VALVERDE M.Monitoring changes in the structure and properties of humic substances following ozonation using UV-Vis,FTIR and1H NMR techniques[J].Science of the Total Environment,2016,541:623-637.
[2]ROCHELLE-NEWALL E J,FISHER T R.Chromophoric dissolved organic matter and dissolved organic carbon in Chesapeake Bay[J].Marine Chemistry,2002,77(1):23-41.
[3]FERRARI G M,DOWELL M D,GROSSI S,et al.Relationship between the optical properties of chromophoric dissolved organic matter and total concentration of dissolved organic carbon in the southern Baltic Sea Region[J].Marine Chemistry,1996,55(3/4):299-316.
[4]KIRK J T O.Light and photosynthesis in aquatic ecosystems[M].England:Cambridge University Press,1994.
[5]FERRARI G M.The relationship between chromophoric dissolved organic matter and dissolved organic carbon in the European Atlantic Coastal Area and in the West Mediterranean Sea(Gulf of Lions)[J].Marine Chemistry,2000,70(4):339-357.
[6]CARDER K L,STEWARD R G,HARVEY G R,et al.Marine humic and fulvic acids:their effects on remote sensing of ocean chlorophyll[J].Limnology and oceanography,1989,34(1):68-81.
[7]DE SOUZA SIERRA M M,DONARD O F X,LAMOTTE M.Spectral identification and behaviour of dissolved organic fluorescent material during estuarine mixing processes[J].Marine Chemistry,1997,58(1/2):51-58.
[8]陈欣,张霄宇,雷惠.长江口CDOM的光谱吸收特征以及DOC物源示踪意义[J].海洋环境科学,2012(5):625-630.CHEN Xin,ZHANG Xiaoyu,LEI Hui.Optical absorption properties of CDOM and tracing implication of DOC in the Changjiang Estuary[J].Marine Environmental Science,2012(5):625-630.
[9]COBLE P G,DEL CASTILLO C E,AVRIL B,et al.Distribution and optical properties of CDOM in the Arabian Sea during the 1995southwest Monsoon[J].Deep Sea Research Part II:Topical Studies in Oceanography,1998,45(1011):2195-2223.
[10]KIEBER R J,ZHOU X,MOPPER K.Formation of carbonyl compounds from UV-induced photodegradation of humic substances in natural waters:fate of riverine carbon in the sea[J].Limnology and Oceanography,1990,35(7):1503-1515.
[11]王福利,郭卫东.秋季南海珠江口和北部湾溶解有机物的光降解[J].环境科学学报,2010,30(3):606-613.WANG Fuli,GUO Weidong.Photodegradation of DOM in the Pearl River Estuary and the Beibu Gulf of the South China sea in autumn[J].Acta Scientiae Circumstantiae,2010,30(3):606-613.
[12]张运林,秦伯强.梅梁湾.大太湖夏季和冬季CDOM特征及可能来源分析[J].水科学进展,2007,18(3):415-423.ZHANG Yunlin,QIN Boqiang.Feature of CDOM and its possible source in Meiliang Bay and Da Taihu Lake in Taihu Lake in summer and winter[J].Advances in Water Science,2007,18(3):415-423.
[13]NELSON N B,SIEGEL D A,MICHAELS A F.Seasonal dynamics of colored dissolved material in the Sargasso Sea[J].Deep Sea Research PartⅠ:Oceanographic Research Papers,1998,45(6):931-957.
[14]DEL CASTILLO C E,COBLEA P G,MORELL J M,et al.Analysis of the optical properties of the Orinoco River plume by absorption and fluorescence spectroscopy[J].Marine Chemistry,1999,66(1/2):35-51.
[15]杨阳,邹立,简慧敏.辽河口秋季有色溶解有机物的光谱特征研究[J].海洋环境科学,2017,36(1):94-100.YANG Yang,ZOU Li,JIAN Huimin.Spectral characteristics of chromophoric dissolved organic matter in Liaohe River estuary in autumn[J].Marine Environmental Science,2017,36(1):94-100.
[16]郭卫东,黄建平,洪华生,等.河口区溶解有机物三维荧光光谱的平行因子分析及其示踪特性[J].环境科学,2010,31(6):1419-1427.GUO Weidong,HUANG Jianping,HONG Huasheng,et al.Resolving excitation emission matrix spectroscopy of estuarine CDOM with parallel factor analysis and its application in organic pollution monitoring[J].Environmental Science,2010,31(6):1419-1427.
[17]VIGNUDELLI S,SANTINELLI C,MURRU E,et al.Distributions of dissolved organic carbon(DOC)and chromophoric dissolved organic matter(CDOM)in coastal waters of the northern Tyrrhenian Sea(Italy)[J].Estuarine,Coastal and Shelf Science,2004,60(1):133-149.
[18]COBLE P G.Characterization of marine and terrestrial DOM in seawater using excitation-emission matrix spectroscopy[J].Marine Chemistry,1996,51(4):325-346.
[19]郭卫东,程远月,吴芳.海洋荧光溶解有机物研究进展[J].海洋通报,2007,26(6):98-106.GUO Weidong,CHENG Yuanyue,WU Fang.An overview of marine fluorescent dissolved organic matter[J].Journal of Marine Science Bulletin,2007,26(6):98-106.
[20]程远月,郭卫东,胡明辉.近岸沉积物再悬浮期间所释放溶解有机物的荧光特征[J].地球化学,2008,37(1):51-58.CHEN Yuanyue,GUO Weidong,HU Minghui.Fluorescence characteristics of dissolved organic matter released from estuarine sediments during resuspension[J].Geochimica,2008,37(1):51-58.
[21]BURDIGE D J,KLINE S W,CHEN W.Fluorescent dissolved organic matter in marine sediment pore waters[J].Marine Chemistry,2004,89(1):289-311.
[22]蒋凤华,杨黄浩,黎先春,等,胶州湾海水溶解有机物三维荧光特征研究[J].光谱学与光谱分析,2007,27(9):1765-1769.JIANG Fenghua,YANG Huanghao,LI Xianchun,et al.Excitationemission-matrix spectral property of dissolved organic matter in seawater of Jiaozhou Bay,China[J].Spectroscopy and Spectral Analysis,2007,27(9):1765-1769.
[23]季乃云,赵卫红,王江涛,等.大沽河-胶州湾段溶解有机物类腐殖质荧光特征变化[J].环境科学,2006,27(6):1073-1077.JI Naiyun,ZHAO Weihong,WANG Jiangtao,et al.Change of humic-like fluorescence characteristics of dissolved organic matter from Dagu River to Jiaozhou Bay[J].Environmental Science,2006,27(6):1073-1077.
[24]鲁景亮.胶州湾溶解有机物荧光特征解析及水母暴发的潜在影响研究[D].青岛:中国科学院海洋研究所,2013.
[25]刘瑛,周倩倩,王江涛.秋季胶州湾有色溶解有机物荧光特性研究及其来源分析[J].中国海洋大学学报:自然科学版,2014(6):60-66.LIU Ying,ZHOU Qianqian,WANG Jiangtao.Source and fluorescence characteristics of chromophoric dissolved organic matter in Jiaozhou Bay in autumn[J].Periodical of Ocean University of China,2014(6):60-66.
[26]SHARP J H,CARLSON C A,PELTZER E T,et al.Final dissolved organic carbon broad community intercalibration and preliminary use of DOC reference materials[J].Marine Chemistry,2002,77(4):239-253.
[27]GREEN S A,BLOUGH N V.Optical absorption and fluorescence properties of chromophoric dissolved organic matter in natural waters[J].Limnology and Oceanography,1994,39(8):1903-1916.
[28]BROWN M.Transmission spectroscopy examinations of natural waters:C.Ultraviolet spectral characteristics of the transition from terrestrial humus to marine yellow substance[J].Estuarine and Coastal Marine Science,1977,5(3):309-317.
[29]STEDMON C A,MARKAGER S,KAAS H.Optical properties and signatures of chromophoric dissolved organic matter(CDOM)in Danish coastal waters[J].Estuarine,Coastal and Shelf Science,2000,51(2):267-278.
[30]李宁.长江口与胶州湾海水有机碳的分布,来源及与氮,磷的耦合关系[D].青岛:中国科学院海洋研究所,2006.
[31]梁成菊.青岛近海有机碳的分布特征及影响因素[D].青岛:中国海洋大学,2008.
[32]PEACOCK M,BURDEN A,COOPER M,et al.Quantifying dissolved organic carbon concentrations in upland catchments using phenolic proxy measurements[J].Journal of Hydrology,2013,477(1):251-260.
[33]OSBURN C L,BOYD T J,MONTGOMERY M T,et al.Optical proxies for terrestrial dissolved organic matter in estuaries and coastal waters[J].Frontiers in Marine Science,2016,2(127):1-15.
[34]GUGUEN C,GUO L,TANAKA N.Distributions and characteristics of colored dissolved organic matter in the western Arctic Ocean[J].Continental Shelf Research,2005,25(10):1195-1207.
[35]HOGE F E,VODACEK A,BLOUGH N V.Inherent optical properties of the ocean:retrieval of the absorption coefficient of chromophoric dissolved organic matter from fluorescence measurements[J].Limnology and Oceanography,1993,38(7):1394-1402.
[36]GUO W,YANG L,ZHAI W,et al.Runoff-mediated seasonal oscillation in the dynamics of dissolved organic matter in different branches of a large bifurcated estuary:the Changjiang Estuary[J].Journal of Geophysical Research:Biogeosciences,2014,119(5):776-793.
[37]江俊武,李帅东,沈胤胤,等.夏季太湖CDOM光学特性空间差异及其来源解析[J].环境科学研究,2017,30(7):1020-1030.JIANG Junwu,LI Shuaidong,SHEN Yinyin,et al.Spatial differences of optical properties of CDOM and their source apportionment in Taihu Lake in summer[J].Research of Environmental Sciences,2017,30(7):1020-1030.
[38]DEL VECCHIO R,BLOUGH N V.Spatial and seasonal distribution of chromophoric dissolved organic matter and dissolved organic carbon in the Middle Atlantic Bight[J].Marine Chemistry,2004,89(1):169-187.
[39]HELMS J R,STUBBINS A,RITCHIE J D,et al.Absorption spectral slopes and slope ratios as indicators of molecular weight,source,and photobleaching of chromophoric dissolved organic matter[J].Limnology and Oceanography,2008,53(3):955-969.
[40]李会杰.腐殖酸和富里酸的提取与表征研究[D].武汉:华中科技大学,2012.
[41]牛城,张运林,朱广伟,等.天目湖流域DOM和CDOM光学特性的对比[J].环境科学研究,2014,27(9):998-1007.NIU Cheng,ZHANG Yunlin,ZHU Guangwei,et al.Comparison of optical properties of DOM and CDOM in Lake Tianmuhu Catchment[J].Research of Environmental Sciences,2014,27(9):998-1007.
[42]张运林,陈伟民,周万平,等.2001-2002年天目湖(沙河水库)浮游植物的生态学研究[J].海洋湖沼通报,2006(2):31-37.ZHANG Yunlin,CHEN Weimin,ZHOU Wanping,et al.Ecological study on the phytoplankton in Lake Tianmu from 2001 to 2002[J].Transactions of Oceanology and Limnology,2006(2):31-37.
[43]SPENCER R G M,STUBBINS A,HERNES P J,et al.Photochemical degradation of dissolved organic matter and dissolved lignin phenols from the Congo River[J].Journal of Geophysical Research:Biogeosciences,2009.doi.10.1029/2009JG000968.
[44]胡素征,李桂菊,李奕洁,等.长江口有色溶解有机物光谱特性及其示踪溶解有机碳研究[J].天津科技大学学报,2015(3):57-61.HU Suzheng,LI Guiju,LI Yijie,et al.Optical absorption properties of chromophoric dissolved organic matter and the tracing implication of dissolved organic carbon in the Yangtze River Estuary[J].Journal of Tianjin University of Science&Technology,2015(3):57-61.
[45]PEURAVUORI J,PIHLAIA K.Molecular size distribution and spectroscopic properties of aquatic humic substances[J].Analytica Chimica Acta,1997,337(2):133-149.
[46]SANTOS L,PINTO A,FILIPE O,et al.Insights on the optical properties of estuarine DOM-hydrological and biological influences[J].Plos One,2016,11(5):1-26.
[47]LI P,HUR J.Utilization of UV-Vis spectroscopy and related data analyses for dissolved organic matter(DOM)studies:a review[J].Critical Reviews in Environmental Science and Technology,2017,47(3):131-154.
[48]HARVEY G R,BORAN D A,CHESAL L A,et al.The structure of marine fulvic and humic acids[J].Marine Chemistry,1983,12(2/3):119-132.
[49]RODRGUEZ F J,SCHLENGER P,GARCA-VALVERDE M.Monitoring changes in the structure and properties of humic substances following ozonation using UV-Vis,FTIR and1H NMR techniques[J].Science of the Total Environment,2016,541:623-637.