内陆水体CDOM光学特性与遥感反演研究进展
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摘要
内陆水体(湖泊、水库、河流)在全球碳循环过程中起着重要作用,其中有色溶解有机物(CDOM)是内陆水体中溶解态有机物质,对水体的光学特性和生物地球化学过程具有重要的影响.由于受到时空变化和人类活动的影响,内陆水体的CDOM组分、来源与光学性质较为复杂.不同区域内或者同一研究区不同的水体类型,CDOM光学特性之间存在着较大差异,通常选取CDOM的吸收系数表征CDOM浓度,通过三维荧光光谱(EEM)表征CDOM荧光组分与来源.首先论述了CDOM的重要作用,并从文献计量学的角度分析了CDOM近20多年的研究进展;其次阐述了CDOM吸收与荧光特性的变化特征,进而分析CDOM荧光组分或者吸收系数变化的驱动因素,阐明了光化学作用与微生物作用对其组分与吸收的影响;最后根据CDOM与溶解有机碳(DOC)的关系,简述了遥感在估算内陆水体CDOM及DOC方面的作用,并讨论了CDOM研究的不足与展望.
Inland waters( including lakes,reservoirs and rivers) play significant roles in global carbon cycles.Colored dissolved organic matter( CDOM) is the dissolved organic matter in inland waters,which have important effect on the optical characteristics and biogeochemical process of waters. The compositions,sources and optical features of CDOM for inland waters could be influenced by the spatial variation and human activities. There are large variations of CDOM characteristics in different regions or the various types of waters in the same regions,CDOM absorption coefficient is generally used to represent CDOM concentration and fluorescence excitation-emission matrix( EEMs) was used to represent CDOM fluorescent compositions and sources. Firstly,in this study the significance of CDOM is demonstrated and the research progress of CDOM study for recent 20 years is analyzed through bibliometrics method. Secondly,the variations of CDOM absorption and fluorescence characteristics are analyzed and then the factors for the variation of CDOM fluorescent compositions and absorption coefficients are also analyzed and the effect of photo-chemical process and microbial process on CDOM absorption and fluorescence are demonstrated. Finally,according to the relationship between CDOM and DOC,the role of remote sensing techniques for the estimation of CDOM and DOC for inland waters is described and the shortage and prospect of CDOM study is discussed as well.
Inland waters( including lakes,reservoirs and rivers) play significant roles in global carbon cycles.Colored dissolved organic matter( CDOM) is the dissolved organic matter in inland waters,which have important effect on the optical characteristics and biogeochemical process of waters. The compositions,sources and optical features of CDOM for inland waters could be influenced by the spatial variation and human activities. There are large variations of CDOM characteristics in different regions or the various types of waters in the same regions,CDOM absorption coefficient is generally used to represent CDOM concentration and fluorescence excitation-emission matrix( EEMs) was used to represent CDOM fluorescent compositions and sources. Firstly,in this study the significance of CDOM is demonstrated and the research progress of CDOM study for recent 20 years is analyzed through bibliometrics method. Secondly,the variations of CDOM absorption and fluorescence characteristics are analyzed and then the factors for the variation of CDOM fluorescent compositions and absorption coefficients are also analyzed and the effect of photo-chemical process and microbial process on CDOM absorption and fluorescence are demonstrated. Finally,according to the relationship between CDOM and DOC,the role of remote sensing techniques for the estimation of CDOM and DOC for inland waters is described and the shortage and prospect of CDOM study is discussed as well.
引文
[1]BATTIN T J,LUYSSAERT S,KAPLAN L A,et al. The boundless carbon cycle[J]. Nat Geosci,2009,2(9):598-600.
[2]ZHANG Y,ZHANG E,YIN Y,et al. Characteristics and sources of chromophoric dissolved organic matter in lakes of the Yungui Plateau,China,differing in trophic state and altitude[J]. Limnol Oceanogr,2010,55(6):2645-2659.
[3]KIRK J T O. Light and photosynthesis in aquatic ecosystems[M]. UK:Cambridge University Press,1994.
[4]LEENHEER J A,CROUE J P. Characterizing aquatic dissolved organic matter[J]. Environ Sci Technol,2003,37(1):18A-26A.
[5]张运林,秦伯强,杨龙元.太湖梅梁湾有色可溶性有机物的空间分布及光学行为[J].湖泊科学,2006,18(4):319-326.
[6]TRANVIK L J,DOWNING J A,COTNER J B,et al. Lakes and reservoirs as regulators of carbon cycling and climate[J]. Limnol Oceanogr,2009,54(6):2298-2314.
[7]ZHANG Y,HUANG W,RAN Y,et al. Compositions and constituents of freshwater dissolved organic matter isolated by reverse osmosis[J]. Mar Pollut Bull,2014,85(1):60-66.
[8]PARA J,COBLE P G,CHARRIERE B,et al. Fluorescence and absorption properties of chromophoric dissolved organic matter(CDOM)in coastal surface waters of the northwestern Mediterranean Sea,influence of the Rhone River[J]. Biogeosciences,2010,7(12):4083-4103.
[9]ORGANELLI E,BRICAUD A,ANTOINE D,et al. Seasonal dynamics of light absorption by chromophoric dissolved organic matter(CDOM)in the NW Mediterranean Sea(BOUSSOLE site)[J]. Deep-Sea Res Pt I-Oceanogra Res Pap,2014,91:72-85.
[10]SCHALLES J F. Optical remote sensing techniques to estimate phytoplankton chlorophyll a concentrations in coastal waters with varying suspended matter and CDOM concentrations[J]. Remote Sens Aquat Coast Ecosyst Process:Sci Manage Appl,2006,9:27-79.
[11]王远东,刘殿伟,宋开山,等.吉林省查干湖水体悬浮颗粒物光谱吸收特性研究[J].光谱学与光谱分析,2011,31(1):162-167.
[12]RECHE I,PACE M L,COLE J J. Relationship of trophic and chemical conditions to photobleaching of dissolved organic matter in lake ecosystems[J]. Biogeochemistry,1999,44(3):259-280.
[13]马荣华,唐军武,段洪涛,等.湖泊水色遥感研究进展[J].湖泊科学,2009,21(2):3-18.
[14]SONG K,LI L,TEDESCO L P,et al. Remote quantification of phycocyanin in potable water sources through an adaptive model[J]. ISPRS J Photogramm Remote Sens,2014,95:68-80.
[15]时志强,张运林,殷燕,等.博斯腾湖夏季水下光场特征分析及影响因素探讨[J].环境科学学报,2012,32(12):2969-2977.
[16]乐成峰,李云梅,张运林,等.太湖水色因子空间分布特征及其对水生植物光合作用的影响[J].应用生态学报,2007,18(11):2491-2496.
[17]赵冬至,罗虎,傅云娜,等.辽东湾黄色物质吸收光谱模型的建立[C].全国遥感技术学术交流会,2003.
[18]COBLE P G,GREEN S A,BLOUGH N V,et al. Characterization of dissolved organic matter in the black sea using fluorescence spectroscopy[J]. Nature,1990,348:432-435.
[19]STEDMON C A,MARKAGER S,BRO R. Tracing dissolved organic matter in aquatic environments using a new approach to fluorescence spectroscopy[J]. Mar Chem,2003,82(3-4):239-254.
[20]MORAN M A,SHELDON W M,ZEPP R G. Carbon loss and optical property changes during long-term photochemical and biological degradation of estuarine dissolved organic matter[J]. Limnol Oceanogr,2000,45(6):1254-1264.
[21]ZEPP R G,CALLAGHAN T V,ERICKSON D J. Effects of enhanced solar ultraviolet radiation on biogeochemical cycles[J]. J Photoch Photobio B-Biology,1998,46(1-3):69-82. J
[22]ROCHELLE-NEWALL E J,FISHER T R. Production of chromophoric dissolved organic matter fluorescence in marine and estuarine environments:an investigation into the role of phytoplankton[J]. Mar Chem,2002,77(1):7-21.
[23]NELSON N B,CARLSON C A,STEINBERG D K. Production of chromophoric dissolved organic matter by Sargasso Sea microbes[J]. Mar Chem,2004,89(1-4):273-287.
[24]ZHANG Y,QIN B,ZHU G,et al. Chromophoric dissolved organic matter(CDOM)absorption characteristics in relation to fluorescence in Lake Taihu,China,a large shallow subtropical lake[J]. Hydrobiologia,2007,581:43-52.
[25]SPENCER R G M,BUTLER K D,AIKEN G R. Dissolved organic carbon and chromophoric dissolved organic matter properties of rivers in the USA[J]. J Geophys Res-Biogeosci,2012,117:G03001-1-G03001-14.
[26]SONG K S,ZANG S Y,ZHAO Y,et al. Spatiotemporal characterization of dissolved carbon for inland waters in semi-humid/semi-arid region,China[J]. Hydrol Earth Syst Sci,2013,17(10):4269-4281.
[27]ROCHELLE-NEWALL E,HULOT F D,JANEAU J L,et al. CDOM fluorescence as a proxy of DOC concentration in natural waters:a comparison of four contrasting tropical systems[J]. Environ Monit Assess,2014,186(5):3303-3304.
[28]GREEN S A,BLOUGH N V. Optical absorption and fluorescence properties of chromophoric dissolved organic matter in natural waters[J].Limnol Oceanogr,1994,39(8):1903-1916.
[29]HESTIR E L,BRANDO V,CAMPBELL G,et al. The relationship between dissolved organic matter absorption and dissolved organic carbon in reservoirs along a temperate to tropical gradient[J]. Remote Sens Environ,2015,156:395-402.
[30]YACOBI Y,ALBERTS J. Absorption spectroscopy of colored dissolved organic carbon in Georgia(USA)rivers:The impact of molecular size distribution[M]. 2003.
[31]ZHANG Y,YIN Y,FENG L,et al. Characterizing chromophoric dissolved organic matter in Lake Tianmuhu and its catchment basin using excitation-emission matrix fluorescence and parallel factor analysis[J]. Water Res,2011,45(16):5110-5122.
[32]ZHAO Y,SONG K,LI S,et al. Characterization of CDOM from urban waters in Northern-Northeastern China using excitation-emission matrix fluorescence and parallel factor analysis[J]. Environ Sci Pollut Res,2016,23(15):15381-15394.
[33]YU Q,TIAN Y Q,CHEN R F,et al. Functional linear analysis of in situ hyperspectral data for assessing CDOM in rivers[J]. Photogramm Eng Remote S,2010,76(10):1147-1158.
[34]GRIFFIN C G,FREY K E,ROGAN J,et al. Spatial and interannual variability of dissolved organic matter in the Kolyma River,East Siberia,observed using satellite imagery[J]. J Geophys Res-Biogeosci,2011,116(G3):165-176.
[35]ZHU W,YU Q. Inversion of chromophoric dissolved organic matter from EO-1 hyperion imagery for turbid estuarine and coastal waters[J].IEEE Trans Geosci Remote Sens,2013,51(6):3286-3298.
[36]SONG K S,ZHAO Y,WEN Z D,et al. A systematic examination of the relationships between CDOM and DOC in inland waters in China[J].Hydrol Earth Syst Sci,2017,21(10):5127-5141.
[37]HELMS J R,STUBBINS A,RITCHIE J D,et al. Absorption spectral slopes and slope ratios as indicators of molecular weight,source,and photobleaching of chromophoric dissolved organic matter[J]. Limnol Oceanogr,2008,53(3):955-969.
[38]CHEN R F,ZHANG Y,VLAHOS P,et al. The fluorescence of dissolved organic matter in the Mid-Atlantic Bight[J]. Deep-Sea Res Pt Ii,2002,49(20):4439-4459.
[39]LAPIERRE J F,DEL GIORGIO P A. Geographical and environmental drivers of regional differences in the lake pCO(2)versus DOC relationship across northern landscapes[J]. J Geophys Res-Biogeosci,2012,117:1-10.
[40]MONSALLIER J M,SCHERBAUM F J,BUCKAU G,et al. Influence of photochemical reactions on the complexation of humic acid with europium(Ⅲ)[J]. J Photoch Photobio a,2001,138(1):55-63.
[41]TAKAO S,IIDA T,ISADA T,et al. Bio-optical properties during the summer season in the Sea of Okhotsk[J]. Prog Oceanogr,2014,126:233-241.
[42]HELBLING W,ZAGARESE H,OSBURN L,et al. Photochemistry of chromophoric dissolved organic matter in natural waters,Uv Effects in Aquatic Organisms and Ecosystems[M],UK:RSC Press,2003.
[43]GRAEBER D,GELBRECHT J,PUSCH M T,et al. Agriculture has changed the amount and composition of dissolved organic matter in Central European headwater streams[J]. Sci Total Environ,2012,438:435-446.
[44]GUEGUEN C,GRANSKOG M A,MCCULLOUGH G,et al. Characterisation of colored dissolved organic matter in Hudson Bay and Hudson Strait using parallel factor analysis[J]. J Mar Syst,2011,88(3):423-433.
[45]MAVI M S,SANDERMAN J,CHITTLEBOROUGH D J,et al. Sorption of dissolved organic matter in salt-affected soils:Effect of salinity,sodicity and texture[J]. Sci Total Environ,2012,435:337-344.
[46]HUR J,LEE B-M,LEE S,et al. Characterization of chromophoric dissolved organic matter and trihalomethane formation potential in a recently constructed reservoir and the surrounding areas-Impoundment effects[J]. J Hydrol,2014,515:71-80.
[47]OSBURN C L,WIGDAHL C R,FRITZ S C,et al. Dissolved organic matter composition and photoreactivity in prairie lakes of the U. S. Great Plains[J]. Limnol Oceanogr,2011,56(6):2371-2390.
[48]COBLE P G. Characterization of marine and terrestrial DOM in seawater using excitation emission matrix spectroscopy[J]. Mar Chem,1996,51(4):325-346.
[49]HENDERSON R K,BAKER A,MURPHY K R,et al. Fluorescence as a potential monitoring tool for recycled water systems:A review[J].Water Res,2009,43(4):863-881.
[50]HUDSON N,BAKER A,REYNOLDS D. Fluorescence analysis of dissolved organic matter in natural,waste and polluted waters-A review[J].River Res Appl,2007,23(6):631-649.
[51]BAKER A. Fluorescence excitation-emission matrix characterization of some sewage-impacted rivers[J]. EnvironSciTechnol,2001,35(5):948-953.
[52]GUO W,XU J,WANG J,et al. Characterization of dissolved organic matter in urban sewage using excitation emission matrix fluorescence spectroscopy and parallel factor analysis[J]. J Environ Sci-China,2010,22(11):1728-1734.
[53]吴静,崔硕,苏伟,等.北京城市水体的三维荧光特征[J].光谱学与光谱分析,2011,31(6):1562-1566.
[54]YAO X,ZHANG Y,ZHU G,et al. Resolving the variability of CDOM fluorescence to differentiate the sources and fate of DOM in Lake Taihu and its tributaries[J]. Chemosphere,2011,82(2):145-155.
[55]YAMASHITA Y,JAFFE R,MAIE N,et al. Assessing the dynamics of dissolved organic matter(DOM)in coastal environments by excitation emission matrix fluorescence and parallel factor analysis(EEM-PARAFAC)[J]. Limnol Oceanogr,2008,53(5):1900-1908.
[56]STEDMON C A,MARKAGER S. Tracing the production and degradation of autochthonous fractions of dissolved organic matter by fluorescence analysis[J]. Limnol Oceanogr,2005,50(5):1415-1426.
[57]CORY R Mand MCKNIGHT D M. Fluorescence spectroscopy reveals ubiquitous presence of oxidized and reduced quinones in dissolved organic matter[J]. EnvironSciTechnol,2005,39(21):8142-8149.
[58]ZHANG Y,LIU X,OSBURN C L,et al. Photobleaching Response of Different Sources of Chromophoric Dissolved Organic Matter Exposed to Natural Solar Radiation Using Absorption and Excitation-Emission Matrix Spectra[J]. PLo S One,2013,8(10):e77515.
[59]CHEN W,WESTERHOFF P,LEENHEER J A,et al. Fluorescence excitation-Emission matrix regional integration to quantify spectra for dissolved organic matter[J]. EnvironSciTechnol,2003,37(24):5701-5710.
[60]ZHAO Y,SONG K,WEN Z,et al. Seasonal characterization of CDOM for lakes in semiarid regions of Northeast China using excitation-emission matrix fluorescence and parallel factor analysis(EEM-PARAFAC)[J]. Biogeosciences,2016,13(5):1635-1645.
[61]OGAWA H,AMAGAI Y,KOIKE I,et al. Production of refractory dissolved organic matter by bacteria[J]. Science,2001,292(5518):917-920.
[62]姚昕,张运林,朱广伟,等.湖泊草、藻来源溶解性有机质及其微生物降解的差异[J].环境科学学报,2014,34(3):688-694.
[63]SUN L,PERDUE E M,MEYER J L,et al. Use of elemental composition to predict bioavailability of dissolved organic matter in a Georgia river[J]. Limnol Oceanogr,1997,42(4):714-721.
[64]FINDLAY S,SINSABAUGH R L. Aquatic Ecosystems Interactivity of Dissolved Organic Matter[M]. USA:Academic press,Elsevier Science,2003.
[65]白莹,黄东海.春秋季有色溶解性有机物(CDOM)的分布特征及季节变化的研究[M].青岛:中国海洋大学,2014.
[66]ROMERA-CASTILLO C,SARMENTO H,ALVAREZ-SALGADO X A,et al. Net production and consumption of fluorescent colored dissolved organic matter by natural bacterial assemblages growing on marine phytoplankton exudates[J]. Appl Environ Microbiol,2011,77(21):7490-7498.
[67]CHEN J,ZHU W N,TIAN Y Q,et al. Estimation of colored dissolved organic matter from landsat-8 imagery for complex inland water:case study of lake huron[J]. IEEE Trans Geosci Remote Sens,2017,55(4):2201-2212.
[68]周博天,刘湘南,吴伶,等.基于水色遥感的香港海域黄色物质浓度反演模型[J].海洋环境科学,2013,32(1):115-119.
[69]田野,郭子祺,乔彦超,等.基于遥感的官厅水库水质监测研究[J].生态学报,2015,35(7):2217-2226.
[70]乐成峰,李云梅,查勇,等.太湖水体浮游藻类吸收系数分离方法研究[J].光学学报,2010,30(11):3090-3096.
[71]ZHU W,YU Q,TIAN Y Q,et al. Estimation of chromophoric dissolved organic matter in the Mississippi and Atchafalaya river plume regions using above-surface hyperspectral remote sensing[J]. J GeophysRes-Oceans,2011,116.
[72]WANG Y C,SHEN F,SOKOLETSKY L,et al. Validation and Calibration of QAA Algorithm for CDOM Absorption Retrieval in the Changjiang(Yangtze)Estuarine and Coastal Waters[J]. Remote Sens,2017,9(11).
[73]ARENZ R F,LEWIS W M,SAUNDERS J F. Determination of chlorophyll and dissolved organic carbon from reflectance data for Colorado reservoirs[J]. Int J Remote Sens,1996,17(8):1547-1565.
[74]张运林,黄群芳,马荣华,等.基于反射率的太湖典型湖区溶解性有机碳的反演[J].地球科学进展,2005,20(7):772-777.
[75]陈楚群,施平.应用水色卫星遥感技术估算珠江口海域溶解有机碳浓度[J].环境科学学报,2001,21(6):715-719.
[76]MANNINO A,RUSS M E,HOOKER S B. Algorithm development and validation for satellite-derived distributions of DOC and CDOM in the US Middle Atlantic Bight[J]. J GeophysRes-Oceans,2008,113(C7).
[77]DEL CASTILLO C E,MILLER R L. On the use of ocean color remote sensing to measure the transport of dissolved organic carbon by the Mississippi River Plume[J]. Remote Sens Environ,2008,112(3):836-844.
[78]MATSUOKA A,BABIN M,DOXARAN D,et al. A synthesis of light absorption properties of the Arctic Ocean:application to semianalytical estimates of dissolved organic carbon concentrations from space[J]. Biogeosciences,2014,11(12):3131-3147.
[79]DEL VECCHIO R,SUBRAMANIAM A. Influence of the Amazon River on the surface optical properties of the western tropical North Atlantic Ocean[J]. J Geophys Res-Oceans,2004,109(C11).
[80]PACKARD T,CHEN W,BLASCO D,et al. Dissolved organic carbon in the Gulf of St. Lawrence[J]. Deep-Sea Res Pt Ii,2000,47(3-4):435-459.
[81]LIU D,PAN D,BAI Y,et al. Variation of dissolved organic carbon transported by two Chinese rivers:The Changjiang River and Yellow River[J]. Mar Pollut Bull,2015,100(1):60-69.
[82]CAO F,TZORTZIOU M,HU C,et al. Remote sensing retrievals of colored dissolved organic matter and dissolved organic carbon dynamics in North American estuaries and their margins[J]. Remote Sens Environ,2018,205:151-165.
[83]YU X,SHEN F,LIU Y. Light absorption properties of CDOM in the Changjiang(Yangtze)estuarine and coastal waters:An alternative approach for DOC estimation[J]. Estuar Coast Shelf S,2016,181:302-311.
[84]NELSON N B,SIEGEL D A. The global distribution and dynamics of chromophoric dissolved organic matter[J]. Annu Rev Mar Sci,2013,5:.447-476.
[85]朱伟健,沈芳,洪官林.长江口及邻近海域有色溶解有机物(CDOM)的光学特性[J].环境科学,2010,31(10):2292-2298.
[86]陈晓玲,陈莉琼,于之锋,等.长江中游湖泊CDOM光学特性及其空间分布对比[J].湖泊科学,2009,21(2):248-254.
[2]ZHANG Y,ZHANG E,YIN Y,et al. Characteristics and sources of chromophoric dissolved organic matter in lakes of the Yungui Plateau,China,differing in trophic state and altitude[J]. Limnol Oceanogr,2010,55(6):2645-2659.
[3]KIRK J T O. Light and photosynthesis in aquatic ecosystems[M]. UK:Cambridge University Press,1994.
[4]LEENHEER J A,CROUE J P. Characterizing aquatic dissolved organic matter[J]. Environ Sci Technol,2003,37(1):18A-26A.
[5]张运林,秦伯强,杨龙元.太湖梅梁湾有色可溶性有机物的空间分布及光学行为[J].湖泊科学,2006,18(4):319-326.
[6]TRANVIK L J,DOWNING J A,COTNER J B,et al. Lakes and reservoirs as regulators of carbon cycling and climate[J]. Limnol Oceanogr,2009,54(6):2298-2314.
[7]ZHANG Y,HUANG W,RAN Y,et al. Compositions and constituents of freshwater dissolved organic matter isolated by reverse osmosis[J]. Mar Pollut Bull,2014,85(1):60-66.
[8]PARA J,COBLE P G,CHARRIERE B,et al. Fluorescence and absorption properties of chromophoric dissolved organic matter(CDOM)in coastal surface waters of the northwestern Mediterranean Sea,influence of the Rhone River[J]. Biogeosciences,2010,7(12):4083-4103.
[9]ORGANELLI E,BRICAUD A,ANTOINE D,et al. Seasonal dynamics of light absorption by chromophoric dissolved organic matter(CDOM)in the NW Mediterranean Sea(BOUSSOLE site)[J]. Deep-Sea Res Pt I-Oceanogra Res Pap,2014,91:72-85.
[10]SCHALLES J F. Optical remote sensing techniques to estimate phytoplankton chlorophyll a concentrations in coastal waters with varying suspended matter and CDOM concentrations[J]. Remote Sens Aquat Coast Ecosyst Process:Sci Manage Appl,2006,9:27-79.
[11]王远东,刘殿伟,宋开山,等.吉林省查干湖水体悬浮颗粒物光谱吸收特性研究[J].光谱学与光谱分析,2011,31(1):162-167.
[12]RECHE I,PACE M L,COLE J J. Relationship of trophic and chemical conditions to photobleaching of dissolved organic matter in lake ecosystems[J]. Biogeochemistry,1999,44(3):259-280.
[13]马荣华,唐军武,段洪涛,等.湖泊水色遥感研究进展[J].湖泊科学,2009,21(2):3-18.
[14]SONG K,LI L,TEDESCO L P,et al. Remote quantification of phycocyanin in potable water sources through an adaptive model[J]. ISPRS J Photogramm Remote Sens,2014,95:68-80.
[15]时志强,张运林,殷燕,等.博斯腾湖夏季水下光场特征分析及影响因素探讨[J].环境科学学报,2012,32(12):2969-2977.
[16]乐成峰,李云梅,张运林,等.太湖水色因子空间分布特征及其对水生植物光合作用的影响[J].应用生态学报,2007,18(11):2491-2496.
[17]赵冬至,罗虎,傅云娜,等.辽东湾黄色物质吸收光谱模型的建立[C].全国遥感技术学术交流会,2003.
[18]COBLE P G,GREEN S A,BLOUGH N V,et al. Characterization of dissolved organic matter in the black sea using fluorescence spectroscopy[J]. Nature,1990,348:432-435.
[19]STEDMON C A,MARKAGER S,BRO R. Tracing dissolved organic matter in aquatic environments using a new approach to fluorescence spectroscopy[J]. Mar Chem,2003,82(3-4):239-254.
[20]MORAN M A,SHELDON W M,ZEPP R G. Carbon loss and optical property changes during long-term photochemical and biological degradation of estuarine dissolved organic matter[J]. Limnol Oceanogr,2000,45(6):1254-1264.
[21]ZEPP R G,CALLAGHAN T V,ERICKSON D J. Effects of enhanced solar ultraviolet radiation on biogeochemical cycles[J]. J Photoch Photobio B-Biology,1998,46(1-3):69-82. J
[22]ROCHELLE-NEWALL E J,FISHER T R. Production of chromophoric dissolved organic matter fluorescence in marine and estuarine environments:an investigation into the role of phytoplankton[J]. Mar Chem,2002,77(1):7-21.
[23]NELSON N B,CARLSON C A,STEINBERG D K. Production of chromophoric dissolved organic matter by Sargasso Sea microbes[J]. Mar Chem,2004,89(1-4):273-287.
[24]ZHANG Y,QIN B,ZHU G,et al. Chromophoric dissolved organic matter(CDOM)absorption characteristics in relation to fluorescence in Lake Taihu,China,a large shallow subtropical lake[J]. Hydrobiologia,2007,581:43-52.
[25]SPENCER R G M,BUTLER K D,AIKEN G R. Dissolved organic carbon and chromophoric dissolved organic matter properties of rivers in the USA[J]. J Geophys Res-Biogeosci,2012,117:G03001-1-G03001-14.
[26]SONG K S,ZANG S Y,ZHAO Y,et al. Spatiotemporal characterization of dissolved carbon for inland waters in semi-humid/semi-arid region,China[J]. Hydrol Earth Syst Sci,2013,17(10):4269-4281.
[27]ROCHELLE-NEWALL E,HULOT F D,JANEAU J L,et al. CDOM fluorescence as a proxy of DOC concentration in natural waters:a comparison of four contrasting tropical systems[J]. Environ Monit Assess,2014,186(5):3303-3304.
[28]GREEN S A,BLOUGH N V. Optical absorption and fluorescence properties of chromophoric dissolved organic matter in natural waters[J].Limnol Oceanogr,1994,39(8):1903-1916.
[29]HESTIR E L,BRANDO V,CAMPBELL G,et al. The relationship between dissolved organic matter absorption and dissolved organic carbon in reservoirs along a temperate to tropical gradient[J]. Remote Sens Environ,2015,156:395-402.
[30]YACOBI Y,ALBERTS J. Absorption spectroscopy of colored dissolved organic carbon in Georgia(USA)rivers:The impact of molecular size distribution[M]. 2003.
[31]ZHANG Y,YIN Y,FENG L,et al. Characterizing chromophoric dissolved organic matter in Lake Tianmuhu and its catchment basin using excitation-emission matrix fluorescence and parallel factor analysis[J]. Water Res,2011,45(16):5110-5122.
[32]ZHAO Y,SONG K,LI S,et al. Characterization of CDOM from urban waters in Northern-Northeastern China using excitation-emission matrix fluorescence and parallel factor analysis[J]. Environ Sci Pollut Res,2016,23(15):15381-15394.
[33]YU Q,TIAN Y Q,CHEN R F,et al. Functional linear analysis of in situ hyperspectral data for assessing CDOM in rivers[J]. Photogramm Eng Remote S,2010,76(10):1147-1158.
[34]GRIFFIN C G,FREY K E,ROGAN J,et al. Spatial and interannual variability of dissolved organic matter in the Kolyma River,East Siberia,observed using satellite imagery[J]. J Geophys Res-Biogeosci,2011,116(G3):165-176.
[35]ZHU W,YU Q. Inversion of chromophoric dissolved organic matter from EO-1 hyperion imagery for turbid estuarine and coastal waters[J].IEEE Trans Geosci Remote Sens,2013,51(6):3286-3298.
[36]SONG K S,ZHAO Y,WEN Z D,et al. A systematic examination of the relationships between CDOM and DOC in inland waters in China[J].Hydrol Earth Syst Sci,2017,21(10):5127-5141.
[37]HELMS J R,STUBBINS A,RITCHIE J D,et al. Absorption spectral slopes and slope ratios as indicators of molecular weight,source,and photobleaching of chromophoric dissolved organic matter[J]. Limnol Oceanogr,2008,53(3):955-969.
[38]CHEN R F,ZHANG Y,VLAHOS P,et al. The fluorescence of dissolved organic matter in the Mid-Atlantic Bight[J]. Deep-Sea Res Pt Ii,2002,49(20):4439-4459.
[39]LAPIERRE J F,DEL GIORGIO P A. Geographical and environmental drivers of regional differences in the lake pCO(2)versus DOC relationship across northern landscapes[J]. J Geophys Res-Biogeosci,2012,117:1-10.
[40]MONSALLIER J M,SCHERBAUM F J,BUCKAU G,et al. Influence of photochemical reactions on the complexation of humic acid with europium(Ⅲ)[J]. J Photoch Photobio a,2001,138(1):55-63.
[41]TAKAO S,IIDA T,ISADA T,et al. Bio-optical properties during the summer season in the Sea of Okhotsk[J]. Prog Oceanogr,2014,126:233-241.
[42]HELBLING W,ZAGARESE H,OSBURN L,et al. Photochemistry of chromophoric dissolved organic matter in natural waters,Uv Effects in Aquatic Organisms and Ecosystems[M],UK:RSC Press,2003.
[43]GRAEBER D,GELBRECHT J,PUSCH M T,et al. Agriculture has changed the amount and composition of dissolved organic matter in Central European headwater streams[J]. Sci Total Environ,2012,438:435-446.
[44]GUEGUEN C,GRANSKOG M A,MCCULLOUGH G,et al. Characterisation of colored dissolved organic matter in Hudson Bay and Hudson Strait using parallel factor analysis[J]. J Mar Syst,2011,88(3):423-433.
[45]MAVI M S,SANDERMAN J,CHITTLEBOROUGH D J,et al. Sorption of dissolved organic matter in salt-affected soils:Effect of salinity,sodicity and texture[J]. Sci Total Environ,2012,435:337-344.
[46]HUR J,LEE B-M,LEE S,et al. Characterization of chromophoric dissolved organic matter and trihalomethane formation potential in a recently constructed reservoir and the surrounding areas-Impoundment effects[J]. J Hydrol,2014,515:71-80.
[47]OSBURN C L,WIGDAHL C R,FRITZ S C,et al. Dissolved organic matter composition and photoreactivity in prairie lakes of the U. S. Great Plains[J]. Limnol Oceanogr,2011,56(6):2371-2390.
[48]COBLE P G. Characterization of marine and terrestrial DOM in seawater using excitation emission matrix spectroscopy[J]. Mar Chem,1996,51(4):325-346.
[49]HENDERSON R K,BAKER A,MURPHY K R,et al. Fluorescence as a potential monitoring tool for recycled water systems:A review[J].Water Res,2009,43(4):863-881.
[50]HUDSON N,BAKER A,REYNOLDS D. Fluorescence analysis of dissolved organic matter in natural,waste and polluted waters-A review[J].River Res Appl,2007,23(6):631-649.
[51]BAKER A. Fluorescence excitation-emission matrix characterization of some sewage-impacted rivers[J]. EnvironSciTechnol,2001,35(5):948-953.
[52]GUO W,XU J,WANG J,et al. Characterization of dissolved organic matter in urban sewage using excitation emission matrix fluorescence spectroscopy and parallel factor analysis[J]. J Environ Sci-China,2010,22(11):1728-1734.
[53]吴静,崔硕,苏伟,等.北京城市水体的三维荧光特征[J].光谱学与光谱分析,2011,31(6):1562-1566.
[54]YAO X,ZHANG Y,ZHU G,et al. Resolving the variability of CDOM fluorescence to differentiate the sources and fate of DOM in Lake Taihu and its tributaries[J]. Chemosphere,2011,82(2):145-155.
[55]YAMASHITA Y,JAFFE R,MAIE N,et al. Assessing the dynamics of dissolved organic matter(DOM)in coastal environments by excitation emission matrix fluorescence and parallel factor analysis(EEM-PARAFAC)[J]. Limnol Oceanogr,2008,53(5):1900-1908.
[56]STEDMON C A,MARKAGER S. Tracing the production and degradation of autochthonous fractions of dissolved organic matter by fluorescence analysis[J]. Limnol Oceanogr,2005,50(5):1415-1426.
[57]CORY R Mand MCKNIGHT D M. Fluorescence spectroscopy reveals ubiquitous presence of oxidized and reduced quinones in dissolved organic matter[J]. EnvironSciTechnol,2005,39(21):8142-8149.
[58]ZHANG Y,LIU X,OSBURN C L,et al. Photobleaching Response of Different Sources of Chromophoric Dissolved Organic Matter Exposed to Natural Solar Radiation Using Absorption and Excitation-Emission Matrix Spectra[J]. PLo S One,2013,8(10):e77515.
[59]CHEN W,WESTERHOFF P,LEENHEER J A,et al. Fluorescence excitation-Emission matrix regional integration to quantify spectra for dissolved organic matter[J]. EnvironSciTechnol,2003,37(24):5701-5710.
[60]ZHAO Y,SONG K,WEN Z,et al. Seasonal characterization of CDOM for lakes in semiarid regions of Northeast China using excitation-emission matrix fluorescence and parallel factor analysis(EEM-PARAFAC)[J]. Biogeosciences,2016,13(5):1635-1645.
[61]OGAWA H,AMAGAI Y,KOIKE I,et al. Production of refractory dissolved organic matter by bacteria[J]. Science,2001,292(5518):917-920.
[62]姚昕,张运林,朱广伟,等.湖泊草、藻来源溶解性有机质及其微生物降解的差异[J].环境科学学报,2014,34(3):688-694.
[63]SUN L,PERDUE E M,MEYER J L,et al. Use of elemental composition to predict bioavailability of dissolved organic matter in a Georgia river[J]. Limnol Oceanogr,1997,42(4):714-721.
[64]FINDLAY S,SINSABAUGH R L. Aquatic Ecosystems Interactivity of Dissolved Organic Matter[M]. USA:Academic press,Elsevier Science,2003.
[65]白莹,黄东海.春秋季有色溶解性有机物(CDOM)的分布特征及季节变化的研究[M].青岛:中国海洋大学,2014.
[66]ROMERA-CASTILLO C,SARMENTO H,ALVAREZ-SALGADO X A,et al. Net production and consumption of fluorescent colored dissolved organic matter by natural bacterial assemblages growing on marine phytoplankton exudates[J]. Appl Environ Microbiol,2011,77(21):7490-7498.
[67]CHEN J,ZHU W N,TIAN Y Q,et al. Estimation of colored dissolved organic matter from landsat-8 imagery for complex inland water:case study of lake huron[J]. IEEE Trans Geosci Remote Sens,2017,55(4):2201-2212.
[68]周博天,刘湘南,吴伶,等.基于水色遥感的香港海域黄色物质浓度反演模型[J].海洋环境科学,2013,32(1):115-119.
[69]田野,郭子祺,乔彦超,等.基于遥感的官厅水库水质监测研究[J].生态学报,2015,35(7):2217-2226.
[70]乐成峰,李云梅,查勇,等.太湖水体浮游藻类吸收系数分离方法研究[J].光学学报,2010,30(11):3090-3096.
[71]ZHU W,YU Q,TIAN Y Q,et al. Estimation of chromophoric dissolved organic matter in the Mississippi and Atchafalaya river plume regions using above-surface hyperspectral remote sensing[J]. J GeophysRes-Oceans,2011,116.
[72]WANG Y C,SHEN F,SOKOLETSKY L,et al. Validation and Calibration of QAA Algorithm for CDOM Absorption Retrieval in the Changjiang(Yangtze)Estuarine and Coastal Waters[J]. Remote Sens,2017,9(11).
[73]ARENZ R F,LEWIS W M,SAUNDERS J F. Determination of chlorophyll and dissolved organic carbon from reflectance data for Colorado reservoirs[J]. Int J Remote Sens,1996,17(8):1547-1565.
[74]张运林,黄群芳,马荣华,等.基于反射率的太湖典型湖区溶解性有机碳的反演[J].地球科学进展,2005,20(7):772-777.
[75]陈楚群,施平.应用水色卫星遥感技术估算珠江口海域溶解有机碳浓度[J].环境科学学报,2001,21(6):715-719.
[76]MANNINO A,RUSS M E,HOOKER S B. Algorithm development and validation for satellite-derived distributions of DOC and CDOM in the US Middle Atlantic Bight[J]. J GeophysRes-Oceans,2008,113(C7).
[77]DEL CASTILLO C E,MILLER R L. On the use of ocean color remote sensing to measure the transport of dissolved organic carbon by the Mississippi River Plume[J]. Remote Sens Environ,2008,112(3):836-844.
[78]MATSUOKA A,BABIN M,DOXARAN D,et al. A synthesis of light absorption properties of the Arctic Ocean:application to semianalytical estimates of dissolved organic carbon concentrations from space[J]. Biogeosciences,2014,11(12):3131-3147.
[79]DEL VECCHIO R,SUBRAMANIAM A. Influence of the Amazon River on the surface optical properties of the western tropical North Atlantic Ocean[J]. J Geophys Res-Oceans,2004,109(C11).
[80]PACKARD T,CHEN W,BLASCO D,et al. Dissolved organic carbon in the Gulf of St. Lawrence[J]. Deep-Sea Res Pt Ii,2000,47(3-4):435-459.
[81]LIU D,PAN D,BAI Y,et al. Variation of dissolved organic carbon transported by two Chinese rivers:The Changjiang River and Yellow River[J]. Mar Pollut Bull,2015,100(1):60-69.
[82]CAO F,TZORTZIOU M,HU C,et al. Remote sensing retrievals of colored dissolved organic matter and dissolved organic carbon dynamics in North American estuaries and their margins[J]. Remote Sens Environ,2018,205:151-165.
[83]YU X,SHEN F,LIU Y. Light absorption properties of CDOM in the Changjiang(Yangtze)estuarine and coastal waters:An alternative approach for DOC estimation[J]. Estuar Coast Shelf S,2016,181:302-311.
[84]NELSON N B,SIEGEL D A. The global distribution and dynamics of chromophoric dissolved organic matter[J]. Annu Rev Mar Sci,2013,5:.447-476.
[85]朱伟健,沈芳,洪官林.长江口及邻近海域有色溶解有机物(CDOM)的光学特性[J].环境科学,2010,31(10):2292-2298.
[86]陈晓玲,陈莉琼,于之锋,等.长江中游湖泊CDOM光学特性及其空间分布对比[J].湖泊科学,2009,21(2):248-254.