固体推进剂组分迁移动力学研究进展
|
摘要
在简要介绍组分迁移机理以及迁移过程影响因素的基础上,综述了推进剂组分迁移动力学的研究进展。根据物质扩散的介质,迁移动力学研究模型主要分为在一维平板中的扩散和半无限介质中的扩散两类,依据都是Fick扩散第二定律。也有学者将半导体中杂质原子的扩散机理运用到推进剂组分迁移中,得到了可靠的结论。另外,近年来随着计算模拟水平的发展,计算模拟方法如分子动力学等成功地模拟推进剂中增塑剂的迁移并求得动力学参数,得到与实验相一致的结论。
On the basis of brief introduction to the mechanism of ingredient migration and factors affecting the migration process,progress on kinetic studies of ingredient migration in solid propellant is mainly dicussed. According to the sorts of diffusion media,the model of kinetics studies can mainly be divided into two types,diffusion in a plane sheet and diffusion in semi-infinite media,respectively. Both the two types are based on the Fick's Second Law. Besides,some scholors have applied the machenism of impurity atom diffusion in semiconductors to ingredient migration in solid propellant and obtain reliable conclusions. In recent years,with the development of calculation and simulation,simulation methods like Melecular Dynamics( MD) have been successfully used to simulate the plasticizers migration in propellant and to get the dynamics parameters that have a good consistency with the conclusions of experiments.
On the basis of brief introduction to the mechanism of ingredient migration and factors affecting the migration process,progress on kinetic studies of ingredient migration in solid propellant is mainly dicussed. According to the sorts of diffusion media,the model of kinetics studies can mainly be divided into two types,diffusion in a plane sheet and diffusion in semi-infinite media,respectively. Both the two types are based on the Fick's Second Law. Besides,some scholors have applied the machenism of impurity atom diffusion in semiconductors to ingredient migration in solid propellant and obtain reliable conclusions. In recent years,with the development of calculation and simulation,simulation methods like Melecular Dynamics( MD) have been successfully used to simulate the plasticizers migration in propellant and to get the dynamics parameters that have a good consistency with the conclusions of experiments.
引文
[1]张海燕.高性能固体推进剂在海空军导弹武器中的应用[J].飞航导弹.1997,10:39-42.
[2]庞爱民.固体火箭推进剂理论与工程[M].北京:宇航出版社,2014:129.
[3]尹华丽,李东峰,张纲要.IPDI型HTPB推进剂界面软化因素研究[J].固体火箭技术,2005(01):44-48.
[4]Agrawal J P.Migration of nitroglycerine through felled unsaturated Polyester and ehloro Polyester blend[J].Technology,1990,28:538.
[5]高敬民.二茂铁基化合物和二茂铁基聚合物及其接枝碳材料的合成、表征及应用研究[D].杭州:浙江大学.2011.
[6]Crac K J,Park G S.Diffusion in potylners[M].Academie Press,New York,1968.
[7]Hirsehfelder J O,Curtiss C F,Bird R B.Moleeular theory of gases and liquids[M].Wiley,New York,1964.
[8]Lau O W,Wong S K.Contamination in food from packaging material[J].Journal of Chromatography A.2000,882(1-2):255-270.
[9]宋晓岚.无机材料科学基础[M].北京:化学工业出版社,2006.
[10]李伟生,张子青.关于双基火箭装药中硝化甘油迁移研究的评述[J].现代兵器.1986(12):50-56.
[11]尹华丽,张纲要,王玉.丁羟推进剂粘接体系中的组分迁移[J].固体火箭技术.2007,30(5):416-419.
[12]尹华丽,李东峰,王玉,张纲要.组分迁移对NEPE推进剂界面粘接性能的影响[J].固体火箭技术.2005,28(2):126-129.
[13]金日光,华幼卿.高分子物理[M].北京:化学工业出版社,2006.
[14]Crank J.The Mathematics of Diffusion[M].Oxford City:Oxford University Press,1975.
[15]Agrawal J P,Agawane N T,Diwakar R P,et al.Nitroglycerine(NG)migration to various unsaturated polyesters and chloropolyesters used for inhibition of rocket propellants[J].Propellants,Explosives,Pyrotechnics.1999,24(6):371-378.
[16]Nancy D,Nicolas D,Marie F V,et al.Diffusion mechanism at the liner propellant interface[C].43th International Annual Conference of the Fraunhofer ICT,Karlsruhe.2012-06.
[17]Bar L G.Migration of Plasticizer between bonded propellant interfaces[J].Propellants,Explosives,Pyrotechnics.2003,28(1):12-17.
[18]Margolin E D.Naval Powder Factory Report[R].1953.
[19]Potgieter H F,Sanderson R D.NG-migration into double-base inhibitors sorption[J].Journal of Applied Polymer Science,1993,50(10):1761-1772.
[20]Juliano L S.Study of plasticizer diffusion in a solid rocket motor’s bondline[J].Journal of Aerospace Technology and Management,2010,1(2):223-229.
[21]Grythe K F,Hansen F K.Diffusion rates and the role of diffusion insolid propellant rocket motor adhesion[J].Journal of Applied Polymer Science,2007,103(3):1529-1538.
[22]Huang Z P,Nie H Y,Zhang Y Y,et al.Migration kinetics and mechanisms of plasticizers,stabilizers at interfaces of NEPE propellant/HTPB liner/EDPM insulation[J].Journal of Hazardous Materials,2012,251-257.
[23]nver A,Dilsiz N,Volkan M,et al.Investigation of acetyl ferrocene migration from hydroxyl-terminated polybutadiene based elastomers by means of ultraviolet–visible and atomic absorption spectroscopic techniques[J].Journal of Applied Polymer Science,2005,96:1654-1661.
[24]Xiao F J,Feng F F,Li L L,et al.Investigation on ultraviolet absorption properties,migration,and catalytic performances of ferrocene-modified hyper-branched polyesters[J].Propellants Explosives Pyrotechnics,2013,38(3):358-365.
[25]施敏,伍国珏,耿莉,等.半导体器件物理[M].西安:西安交通大学出版社,2008.
[26]Wilken J.Migration of nitroglycerine in double base-propellants from guided missiles[C].39th International Annual Conference of the Fraunhofer ICT,Karlsruhe.June06,24-26,2008.
[27]李红霞,强洪夫,李新其,等.丁羟推进剂黏结体系中增塑剂迁移的分子模拟[J].火炸药学报,2008,31(5):74-78.
[28]李红霞,强洪夫,李新其,等.基于MD方法的增塑剂扩散行为的模拟研究[J].含能材料,2009,17(1):36-41.
[29]王晓,姚大虎,白森虎,等.NG在聚氨酯中扩散性能的分子动力学模拟[J].含能材料,2013,21(5):594-598.
[30]李红霞,强洪夫,李新其,等.HTPB推进剂中增塑剂扩散系数计算[J].固体火箭技术,2012,35(03):387-404.
[31]朱伟,刘冬梅,肖继军,等.NEPE推进剂/衬层结构-性能MD模拟(Ⅱ)——复杂体系组分分子迁移和配方设计示例[J].固体火箭技术,2014,37(5):678-683.
[32]虞振飞,付小龙,蔚红建,等.聚氨酯弹性体中NG和BTTN迁移的介观模拟[J].含能材料,2015,23(9):858-864.
[2]庞爱民.固体火箭推进剂理论与工程[M].北京:宇航出版社,2014:129.
[3]尹华丽,李东峰,张纲要.IPDI型HTPB推进剂界面软化因素研究[J].固体火箭技术,2005(01):44-48.
[4]Agrawal J P.Migration of nitroglycerine through felled unsaturated Polyester and ehloro Polyester blend[J].Technology,1990,28:538.
[5]高敬民.二茂铁基化合物和二茂铁基聚合物及其接枝碳材料的合成、表征及应用研究[D].杭州:浙江大学.2011.
[6]Crac K J,Park G S.Diffusion in potylners[M].Academie Press,New York,1968.
[7]Hirsehfelder J O,Curtiss C F,Bird R B.Moleeular theory of gases and liquids[M].Wiley,New York,1964.
[8]Lau O W,Wong S K.Contamination in food from packaging material[J].Journal of Chromatography A.2000,882(1-2):255-270.
[9]宋晓岚.无机材料科学基础[M].北京:化学工业出版社,2006.
[10]李伟生,张子青.关于双基火箭装药中硝化甘油迁移研究的评述[J].现代兵器.1986(12):50-56.
[11]尹华丽,张纲要,王玉.丁羟推进剂粘接体系中的组分迁移[J].固体火箭技术.2007,30(5):416-419.
[12]尹华丽,李东峰,王玉,张纲要.组分迁移对NEPE推进剂界面粘接性能的影响[J].固体火箭技术.2005,28(2):126-129.
[13]金日光,华幼卿.高分子物理[M].北京:化学工业出版社,2006.
[14]Crank J.The Mathematics of Diffusion[M].Oxford City:Oxford University Press,1975.
[15]Agrawal J P,Agawane N T,Diwakar R P,et al.Nitroglycerine(NG)migration to various unsaturated polyesters and chloropolyesters used for inhibition of rocket propellants[J].Propellants,Explosives,Pyrotechnics.1999,24(6):371-378.
[16]Nancy D,Nicolas D,Marie F V,et al.Diffusion mechanism at the liner propellant interface[C].43th International Annual Conference of the Fraunhofer ICT,Karlsruhe.2012-06.
[17]Bar L G.Migration of Plasticizer between bonded propellant interfaces[J].Propellants,Explosives,Pyrotechnics.2003,28(1):12-17.
[18]Margolin E D.Naval Powder Factory Report[R].1953.
[19]Potgieter H F,Sanderson R D.NG-migration into double-base inhibitors sorption[J].Journal of Applied Polymer Science,1993,50(10):1761-1772.
[20]Juliano L S.Study of plasticizer diffusion in a solid rocket motor’s bondline[J].Journal of Aerospace Technology and Management,2010,1(2):223-229.
[21]Grythe K F,Hansen F K.Diffusion rates and the role of diffusion insolid propellant rocket motor adhesion[J].Journal of Applied Polymer Science,2007,103(3):1529-1538.
[22]Huang Z P,Nie H Y,Zhang Y Y,et al.Migration kinetics and mechanisms of plasticizers,stabilizers at interfaces of NEPE propellant/HTPB liner/EDPM insulation[J].Journal of Hazardous Materials,2012,251-257.
[23]nver A,Dilsiz N,Volkan M,et al.Investigation of acetyl ferrocene migration from hydroxyl-terminated polybutadiene based elastomers by means of ultraviolet–visible and atomic absorption spectroscopic techniques[J].Journal of Applied Polymer Science,2005,96:1654-1661.
[24]Xiao F J,Feng F F,Li L L,et al.Investigation on ultraviolet absorption properties,migration,and catalytic performances of ferrocene-modified hyper-branched polyesters[J].Propellants Explosives Pyrotechnics,2013,38(3):358-365.
[25]施敏,伍国珏,耿莉,等.半导体器件物理[M].西安:西安交通大学出版社,2008.
[26]Wilken J.Migration of nitroglycerine in double base-propellants from guided missiles[C].39th International Annual Conference of the Fraunhofer ICT,Karlsruhe.June06,24-26,2008.
[27]李红霞,强洪夫,李新其,等.丁羟推进剂黏结体系中增塑剂迁移的分子模拟[J].火炸药学报,2008,31(5):74-78.
[28]李红霞,强洪夫,李新其,等.基于MD方法的增塑剂扩散行为的模拟研究[J].含能材料,2009,17(1):36-41.
[29]王晓,姚大虎,白森虎,等.NG在聚氨酯中扩散性能的分子动力学模拟[J].含能材料,2013,21(5):594-598.
[30]李红霞,强洪夫,李新其,等.HTPB推进剂中增塑剂扩散系数计算[J].固体火箭技术,2012,35(03):387-404.
[31]朱伟,刘冬梅,肖继军,等.NEPE推进剂/衬层结构-性能MD模拟(Ⅱ)——复杂体系组分分子迁移和配方设计示例[J].固体火箭技术,2014,37(5):678-683.
[32]虞振飞,付小龙,蔚红建,等.聚氨酯弹性体中NG和BTTN迁移的介观模拟[J].含能材料,2015,23(9):858-864.