四氢呋喃-水共沸物体系分离方法
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摘要
从工业化分离方法与新型分离方法 2个层面分别介绍近年来四氢呋喃-水共沸物分离的研究进展。工业化分离方法主要包括萃取精馏和变压共沸精馏,新型分离方法中主要讨论了吸附法与渗透蒸发方法。对于工业分离方法,以后的发展方向将是在保证分离要求的前提下,进一步减少能耗、满足绿色环保的要求。
The research progress on separation of tetrahydrofuran-water azeotrope in recent years is reviewed from the aspects of industrialized separation methods and novel separation approaches. The industrialized separation methods reviewed mainly include the extractive distillation method and the pressure swing azeotropic distillation method. Novel separation approaches discussed mainly include the adsorption and pervaporation methods. As for the industrialized separation methods,the future direction will develop towards reducing energy consumption and meeting the requirement of environmental protection regulations in the premise of ensuring requirements of separation.
The research progress on separation of tetrahydrofuran-water azeotrope in recent years is reviewed from the aspects of industrialized separation methods and novel separation approaches. The industrialized separation methods reviewed mainly include the extractive distillation method and the pressure swing azeotropic distillation method. Novel separation approaches discussed mainly include the adsorption and pervaporation methods. As for the industrialized separation methods,the future direction will develop towards reducing energy consumption and meeting the requirement of environmental protection regulations in the premise of ensuring requirements of separation.
引文
[1]王惠媛,许松林.含水四氢呋喃萃取精馏塔的动态模拟[J].化工进展,2005,24(S1):36-39.
[2]王延吉.化工产品手册—有机化工原料[M].北京:化学工业出版社,2008.
[3]王宏伟.有机化工的基础原料—四氢呋喃[J].化学工程师,2010,(1):29-30.
[4]宋海华,孙伟,王秀丽,等.萃取精馏溶剂选择的研究进展[J].化学工业与工程,2002,19(1):83-88.
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[6]Xu S,Wang H.Separation of tetrahydrofuran-water azeotropic mixture by batch extractive distillation process[J].Chemical Engineering Research&Design,2006,84(6):478-482.
[7]Zhang Z G,Huang D H,Lv M,et al.Entrainer selection for separating tetrahydrofuran/water azeotropic mixture by extractive distillation[J].Separation&Purification Technology,2014,122(122):73-77.
[8]黄动昊,张志刚,郑立娇,等.萃取精馏分离四氢呋喃/水共沸物系的Aspen模拟[J].沈阳化工大学学报,2015,29(3):211-215.
[9]Kossack S,Kraemer K,Gani R,et al.A systematic synthesis framework for extractive distillation processes[J].Chemical Engineering Research&Design,2008,86(7):781-792.
[10]张光旭,王延儒,卞白桂,等.四氢呋喃-水恒沸物萃取精馏过程的三塔优化计算[J].武汉工程大学学报,2004,26(4):27-30.
[11]Xu S,Wang H.A new entrainer for separation of tetrahydrofuranwater azeotropic mixture by extractive distillation[J].Chemical Engineering&Processing Process Intensification,2006,45(11):954-958.
[12]Gómez P A,Gil I D.Simulation of the tetrahydrofuran dehydration process by extractive distillation[J].Latin American Applied Research,2009,39(4):275-284.
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[14]赵路阳,蔡旺锋,张旭斌.联合精馏分离四氢呋喃-水共沸物的实验及优化模拟[J].化学工业与工程,2015,32(1):48-53.
[15]Deorukhkar O A,Deogharkar B S,Mahajan Y S.Purification of tetrahydrofuran from its aqueous azeotrope by extractive distillation:Pilot plant studies[J].Chemical Engineering&Processing Process Intensification,2016,105:79-91.
[16]马春蕾,唐建可.萃取精馏分离四氢呋喃-水共沸物的模拟研究[J].现代化工,2016,36(9):182-185.
[17]纪智玲,王志恒,廖丽华,等.具有最低共沸点难分离物系变压精馏分离[J].化工进展,2014,33(S1):85-88.
[18]Luis P,Amelio A,Vreysen S,et al.Simulation and environmental evaluation of process design:Distillation vs.hybrid distillation-pervaporation for methanol/tetrahydrofuran separation[J].Applied Energy,2014,113(1):565-575.
[19]陈晓春,张频,王焕凤,等.制药废液中四氢呋喃回收系统的模拟与优化[J].现代化工,2009,29(6):29-62.
[20]李仕超,孔艳.四氢呋喃水溶液共沸精馏工艺技术的设计与应用[J].石油化工应用,2011,30(6):81-84.
[21]Lee J,Cho J,Dong M K,et al.Separation of tetrahydrofuran and water using pressure swing distillation:Modeling and optimization[J].Korean Journal of Chemical Engineering,2011,28(2):591-596.
[22]沈体峰,仇汝臣,万京帆,等.四氢呋喃-水高低压双塔共沸精馏设计与热集成[J].当代化工,2015,(10):2418-2421.
[23]Li Y P,Liu Z Y.Heat integration of a tetrahydrofuran recovery system to save energy[J].Asia-Pacific Journal of Chemical Engineering,2014,9(2):303-308.
[24]刘家祺.分离过程与技术[M].天津:天津大学出版社,2001:130-137.
[25]居沈贵,刘健,张和平.4A分子筛脱除四氢呋喃中微量水的研究[J].化学工程师,2006,20(6):1-3.
[26]彭跃莲.膜技术前沿及工程应用[M].北京:中国纺织出版社,2009:245-276.
[27]Huang S H,Liu Y Y,Huang Y H,et al.Study on characterization and pervaporation performance of interfacially polymerized polyamide thin-film composite membranes for dehydrating tetrahydrofuran[J].Journal of Membrane Science,2014,470(23):411-420.
[28]Han Y J,Su W C,Lai J Y,et al.Hydrophilically surface-modified and crosslinked polybenzimidazole membranes for pervaporation dehydration on tetrahydrofuran aqueous solutions[J].Journal of Membrane Science,2015,475(3):496-503.
[2]王延吉.化工产品手册—有机化工原料[M].北京:化学工业出版社,2008.
[3]王宏伟.有机化工的基础原料—四氢呋喃[J].化学工程师,2010,(1):29-30.
[4]宋海华,孙伟,王秀丽,等.萃取精馏溶剂选择的研究进展[J].化学工业与工程,2002,19(1):83-88.
[5]唐晓东,袁娇阳,李晶晶,等.萃取精馏溶剂的研究应用进展[J].现代化工,2013,33(12):31-35.
[6]Xu S,Wang H.Separation of tetrahydrofuran-water azeotropic mixture by batch extractive distillation process[J].Chemical Engineering Research&Design,2006,84(6):478-482.
[7]Zhang Z G,Huang D H,Lv M,et al.Entrainer selection for separating tetrahydrofuran/water azeotropic mixture by extractive distillation[J].Separation&Purification Technology,2014,122(122):73-77.
[8]黄动昊,张志刚,郑立娇,等.萃取精馏分离四氢呋喃/水共沸物系的Aspen模拟[J].沈阳化工大学学报,2015,29(3):211-215.
[9]Kossack S,Kraemer K,Gani R,et al.A systematic synthesis framework for extractive distillation processes[J].Chemical Engineering Research&Design,2008,86(7):781-792.
[10]张光旭,王延儒,卞白桂,等.四氢呋喃-水恒沸物萃取精馏过程的三塔优化计算[J].武汉工程大学学报,2004,26(4):27-30.
[11]Xu S,Wang H.A new entrainer for separation of tetrahydrofuranwater azeotropic mixture by extractive distillation[J].Chemical Engineering&Processing Process Intensification,2006,45(11):954-958.
[12]Gómez P A,Gil I D.Simulation of the tetrahydrofuran dehydration process by extractive distillation[J].Latin American Applied Research,2009,39(4):275-284.
[13]Fan Z D,Zhang X B,Zhao L Y,et al.Study on the separation of azeotrope of tetrahydrofuran-water using a combined method of extractive and general distillation[J].Advanced Materials Research,2013,803:149-152.
[14]赵路阳,蔡旺锋,张旭斌.联合精馏分离四氢呋喃-水共沸物的实验及优化模拟[J].化学工业与工程,2015,32(1):48-53.
[15]Deorukhkar O A,Deogharkar B S,Mahajan Y S.Purification of tetrahydrofuran from its aqueous azeotrope by extractive distillation:Pilot plant studies[J].Chemical Engineering&Processing Process Intensification,2016,105:79-91.
[16]马春蕾,唐建可.萃取精馏分离四氢呋喃-水共沸物的模拟研究[J].现代化工,2016,36(9):182-185.
[17]纪智玲,王志恒,廖丽华,等.具有最低共沸点难分离物系变压精馏分离[J].化工进展,2014,33(S1):85-88.
[18]Luis P,Amelio A,Vreysen S,et al.Simulation and environmental evaluation of process design:Distillation vs.hybrid distillation-pervaporation for methanol/tetrahydrofuran separation[J].Applied Energy,2014,113(1):565-575.
[19]陈晓春,张频,王焕凤,等.制药废液中四氢呋喃回收系统的模拟与优化[J].现代化工,2009,29(6):29-62.
[20]李仕超,孔艳.四氢呋喃水溶液共沸精馏工艺技术的设计与应用[J].石油化工应用,2011,30(6):81-84.
[21]Lee J,Cho J,Dong M K,et al.Separation of tetrahydrofuran and water using pressure swing distillation:Modeling and optimization[J].Korean Journal of Chemical Engineering,2011,28(2):591-596.
[22]沈体峰,仇汝臣,万京帆,等.四氢呋喃-水高低压双塔共沸精馏设计与热集成[J].当代化工,2015,(10):2418-2421.
[23]Li Y P,Liu Z Y.Heat integration of a tetrahydrofuran recovery system to save energy[J].Asia-Pacific Journal of Chemical Engineering,2014,9(2):303-308.
[24]刘家祺.分离过程与技术[M].天津:天津大学出版社,2001:130-137.
[25]居沈贵,刘健,张和平.4A分子筛脱除四氢呋喃中微量水的研究[J].化学工程师,2006,20(6):1-3.
[26]彭跃莲.膜技术前沿及工程应用[M].北京:中国纺织出版社,2009:245-276.
[27]Huang S H,Liu Y Y,Huang Y H,et al.Study on characterization and pervaporation performance of interfacially polymerized polyamide thin-film composite membranes for dehydrating tetrahydrofuran[J].Journal of Membrane Science,2014,470(23):411-420.
[28]Han Y J,Su W C,Lai J Y,et al.Hydrophilically surface-modified and crosslinked polybenzimidazole membranes for pervaporation dehydration on tetrahydrofuran aqueous solutions[J].Journal of Membrane Science,2015,475(3):496-503.