洗涤剂和化妆品中烷基酚和烷基酚聚氧乙烯醚的检测进展
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摘要
概述了壬基酚、辛基酚、壬基酚聚氧乙烯醚和辛基酚聚氧乙烯醚的性质、应用情况和安全性评价;简单介绍了国内外与洗涤用品中烷基酚和烷基酚聚氧乙烯醚相关的法规和标准;综述了一些标准和论文中关于洗涤剂和化妆品中壬基酚、辛基酚、壬基酚聚氧乙烯醚和辛基酚聚氧乙烯醚的检测方法,并对一些检测方法所采用的技术和注意事项进行了重点说明。
Properties,applications and safety evaluation of nonylphenol,octylphenol,nonylphenol ethoxylates and octylphenol ethoxylates were described. The regulations and standards for alkylphenols and alkylphenol polyethoxylates related to detergent products in China as well as in foreign countries were briefed. An overview of detection methods for nonylphenol,octylphenol,nonylphenol ethoxylates and octylphenol ethoxylates composed in detergent products and cosmetics was reviewed. Operation technique and attention to be paid in the detection process were emphatically presented.
Properties,applications and safety evaluation of nonylphenol,octylphenol,nonylphenol ethoxylates and octylphenol ethoxylates were described. The regulations and standards for alkylphenols and alkylphenol polyethoxylates related to detergent products in China as well as in foreign countries were briefed. An overview of detection methods for nonylphenol,octylphenol,nonylphenol ethoxylates and octylphenol ethoxylates composed in detergent products and cosmetics was reviewed. Operation technique and attention to be paid in the detection process were emphatically presented.
引文
[1]贾丽华,郭祥峰,郑宝河.壬基酚衍生的季铵盐阳离子表面活性剂的合成及性能[J].日用化学工业,2002,32(5):17-18.
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[5]户献雷,饶剑辉,张鹏,等.烷基酚聚氧乙烯醚(APEOs)的检测方法的研究进展[J].非织造布,2008,16(1):25-30.
[6]章杰.禁用染料和环保型染料[M].北京:中国化学工业出版社,2001:93-98.
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[8]章杰.“壬基酚”事件的最新进展和创新机遇[J].上海染料,2012,40(2):15-20.
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[10]余增丽,张立实,徐培渝,等.三种增塑剂对乳腺癌细胞株MCF-7增殖的影响[J].中华预防医学杂志,2003,37(3):150-153.
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[12]Lu Y Y,Chen M L,Sung F C,et al.Daily intake of 4-nonyl-phenol in Taiwanese[J].Environment International,2007,33(7):903-910.
[13]谢明勇,刘晓珍,陈泱杰.壬基酚在食品中的污染现状及其生物毒性概述[J].食品科学技术学报,2014,32(1):1-7.
[14]Qian Q Z,Cao X K,Wang Q,et al.High-performance liquid chromatographic method for the determination of bisphenol a,nonylphenol and octylphenol in sewage[J].Informatics and Management Science,2012,204:691-697.
[15]中国台湾地区卫生福利部.食品用洗洁剂中壬基苯酚及壬基苯酚聚乙氧基醇类之检验方法[S].台北:中国台湾地区卫生福利部,2013.
[16]李晓睿,姚晨之,严方.反相高效液相色谱法测定洗涤用品中的烷基酚聚氧乙烯醚[J].印染助剂,2015,32(6):50-52.
[17]刘欣,谷明生,河合富佐子.正相高效液相色谱法分离检测壬基酚和短链壬基酚聚氧乙烯醚[J].分析化学,2005,33(8):1189-1191.
[18]孙艺,吴天伟,崔蓉,等.高效液相色谱法测定动物组织中壬基酚、辛基酚和2,4-二叔丁基酚[J].中国卫生检验杂志,2016,26(15):2164-2167.
[19]Petrie B,Mc Adam E J,Whelan M J,et al.The determination of nonylphenol and its precursors in a trickling filter wastewater treatment process[J].Analytical and Bioanalytical Chemistry,2013,405(10):3243-3253.
[20]彭莺,吴治将,黎军,等.高效液相色谱质谱联用法测定洗涤用品中的壬基苯酚聚氧乙烯醚和辛基苯酚聚氧乙烯醚[J].顺德职业技术学院学报,2014,12(3):23-27.
[21]李小莹,李琼,刘华鼐.高效液相色谱-串联质谱法检测玩具中的壬基酚和辛基酚[J].广东化工,2016,43(14):212-213.
[22]宁洁,李帮锐.在线捕集消除本底-超高效液相色谱-串联质谱法测定婴幼儿辅助食品中双酚A和壬基酚[J].中国卫生检验杂志,2016,26(14):1983-1986.
[23]刘玲君,何香婷,赵君,等.高效液相色谱-串联质谱法测定奶粉中的壬基酚[J].中国乳品工业,2016,44(6):46-47.
[24]李翔宇,舒敏,陆姝欢,等.LC-MS-MS法测定包装材料中壬基酚含量及其迁移量[J].中国食品添加剂,2016(8):172-176.
[25]曲双双,肖光辉,刘婷,等.UPLC-MS/MS法同时测定婴幼儿配方奶粉中的壬基酚和双酚A[J].中国食品添加剂,2016(8):185-190.
[26]林奕云,郑家概,付强,等.DSPE-UPLC-MS/MS测定畜禽产品中壬基酚和双酚A[J].食品工业,2016,37(6):279-284.
[27]刘秀清.婴幼儿配方乳粉中壬基酚污染检测与风险控制[J].现代农业科技,2016(21):260-261.
[28]吴维吉,李旭,刘佳,等.气相色谱串联质谱法测定植物油中壬基酚[J].粮油食品科技,2016,24(6):67-70.
[2]Editorial Department.Greenpeace report:toxic water pollution‘global’[J].International Dyer,201l,10:32.
[3]Xu J,Li J M,Feng Z,et al.Neurotoxic effects of nonylphenol:a review[J].Wiener Klinische Wochenschrift,2013,125(3):61-70.
[4]盛毅,周述琼,章骅,等.烷基酚聚氧乙烯醚的环境危害及检测方法评价[J].现代科学仪器,2009,4(4):141-145.
[5]户献雷,饶剑辉,张鹏,等.烷基酚聚氧乙烯醚(APEOs)的检测方法的研究进展[J].非织造布,2008,16(1):25-30.
[6]章杰.禁用染料和环保型染料[M].北京:中国化学工业出版社,2001:93-98.
[7]王磊.壬基酚的研究进展分析[J].中国科技博览,2012(4):62-63.
[8]章杰.“壬基酚”事件的最新进展和创新机遇[J].上海染料,2012,40(2):15-20.
[9]章杰.从“壬基酚”事件看我国纺织印染助剂的安全性问题[J].印染助剂,2012,29(3):1-8.
[10]余增丽,张立实,徐培渝,等.三种增塑剂对乳腺癌细胞株MCF-7增殖的影响[J].中华预防医学杂志,2003,37(3):150-153.
[11]Fukamachi K,Han B S,Kim C K,et a1.Possible enhancing effects of atrazine and nonylphenol on 7,12-dimethyl benz[a]anthraceneinduced mammary tumor development in human c-Ha-ras protooncogene transgenic rats[J].Cancer Science,2004,95(5):404-410.
[12]Lu Y Y,Chen M L,Sung F C,et al.Daily intake of 4-nonyl-phenol in Taiwanese[J].Environment International,2007,33(7):903-910.
[13]谢明勇,刘晓珍,陈泱杰.壬基酚在食品中的污染现状及其生物毒性概述[J].食品科学技术学报,2014,32(1):1-7.
[14]Qian Q Z,Cao X K,Wang Q,et al.High-performance liquid chromatographic method for the determination of bisphenol a,nonylphenol and octylphenol in sewage[J].Informatics and Management Science,2012,204:691-697.
[15]中国台湾地区卫生福利部.食品用洗洁剂中壬基苯酚及壬基苯酚聚乙氧基醇类之检验方法[S].台北:中国台湾地区卫生福利部,2013.
[16]李晓睿,姚晨之,严方.反相高效液相色谱法测定洗涤用品中的烷基酚聚氧乙烯醚[J].印染助剂,2015,32(6):50-52.
[17]刘欣,谷明生,河合富佐子.正相高效液相色谱法分离检测壬基酚和短链壬基酚聚氧乙烯醚[J].分析化学,2005,33(8):1189-1191.
[18]孙艺,吴天伟,崔蓉,等.高效液相色谱法测定动物组织中壬基酚、辛基酚和2,4-二叔丁基酚[J].中国卫生检验杂志,2016,26(15):2164-2167.
[19]Petrie B,Mc Adam E J,Whelan M J,et al.The determination of nonylphenol and its precursors in a trickling filter wastewater treatment process[J].Analytical and Bioanalytical Chemistry,2013,405(10):3243-3253.
[20]彭莺,吴治将,黎军,等.高效液相色谱质谱联用法测定洗涤用品中的壬基苯酚聚氧乙烯醚和辛基苯酚聚氧乙烯醚[J].顺德职业技术学院学报,2014,12(3):23-27.
[21]李小莹,李琼,刘华鼐.高效液相色谱-串联质谱法检测玩具中的壬基酚和辛基酚[J].广东化工,2016,43(14):212-213.
[22]宁洁,李帮锐.在线捕集消除本底-超高效液相色谱-串联质谱法测定婴幼儿辅助食品中双酚A和壬基酚[J].中国卫生检验杂志,2016,26(14):1983-1986.
[23]刘玲君,何香婷,赵君,等.高效液相色谱-串联质谱法测定奶粉中的壬基酚[J].中国乳品工业,2016,44(6):46-47.
[24]李翔宇,舒敏,陆姝欢,等.LC-MS-MS法测定包装材料中壬基酚含量及其迁移量[J].中国食品添加剂,2016(8):172-176.
[25]曲双双,肖光辉,刘婷,等.UPLC-MS/MS法同时测定婴幼儿配方奶粉中的壬基酚和双酚A[J].中国食品添加剂,2016(8):185-190.
[26]林奕云,郑家概,付强,等.DSPE-UPLC-MS/MS测定畜禽产品中壬基酚和双酚A[J].食品工业,2016,37(6):279-284.
[27]刘秀清.婴幼儿配方乳粉中壬基酚污染检测与风险控制[J].现代农业科技,2016(21):260-261.
[28]吴维吉,李旭,刘佳,等.气相色谱串联质谱法测定植物油中壬基酚[J].粮油食品科技,2016,24(6):67-70.