Three Complexes Based on Synthetic-condition Strategy Involving a Universal Mixed-ligand System
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摘要
Three coordination polymers([Zn(H_2biim)_2(H_2O)_2]_2·2(HO-BDC)·x(H_2O)(1)[Cd(H_2biim)_2(H_2O)_2]_2·2(HO-BDC)·x(H_2O)(2) and [Co(HO-BDC)(bbi)]n(3)) are obtained by using synthetic-condition strategy in the mixed-ligand system 5-hydroxyisophthalic acid(OH-BDC)together with bisimidazole ligands(2,2?-biimidazole(H2 biim) and 1,1?-(1,4-butanediyl)bis(imidazole)(bbi)). The structure determination reveals that complexes 1 and 2 are zero-dimensional(0 D) structures, and complex 3 is a dinuclear two-dimensional(2D) layer structure. They are all 3D supramolecular networks. The comparisons of the synthetic-condition effects and structure differences among 1 ～3 and our previous work complexes 4([Co_2(HO-BDC)_2(bbi)_2]·H_2O) and 5([Zn(HO-BDC)(bbi)]) have been discussed in detail. Furthermore, the luminescent properties and thermal stabilities of compounds 1～3 in the solid state have been studied.
Three coordination polymers([Zn(H_2biim)_2(H_2O)_2]_2·2(HO-BDC)·x(H_2O)(1)[Cd(H_2biim)_2(H_2O)_2]_2·2(HO-BDC)·x(H_2O)(2) and [Co(HO-BDC)(bbi)]n(3)) are obtained by using synthetic-condition strategy in the mixed-ligand system 5-hydroxyisophthalic acid(OH-BDC)together with bisimidazole ligands(2,2?-biimidazole(H2 biim) and 1,1?-(1,4-butanediyl)bis(imidazole)(bbi)). The structure determination reveals that complexes 1 and 2 are zero-dimensional(0 D) structures, and complex 3 is a dinuclear two-dimensional(2D) layer structure. They are all 3D supramolecular networks. The comparisons of the synthetic-condition effects and structure differences among 1 ～3 and our previous work complexes 4([Co_2(HO-BDC)_2(bbi)_2]·H_2O) and 5([Zn(HO-BDC)(bbi)]) have been discussed in detail. Furthermore, the luminescent properties and thermal stabilities of compounds 1～3 in the solid state have been studied.
Three coordination polymers([Zn(H_2biim)_2(H_2O)_2]_2·2(HO-BDC)·x(H_2O)(1)[Cd(H_2biim)_2(H_2O)_2]_2·2(HO-BDC)·x(H_2O)(2) and [Co(HO-BDC)(bbi)]n(3)) are obtained by using synthetic-condition strategy in the mixed-ligand system 5-hydroxyisophthalic acid(OH-BDC)together with bisimidazole ligands(2,2?-biimidazole(H2 biim) and 1,1?-(1,4-butanediyl)bis(imidazole)(bbi)). The structure determination reveals that complexes 1 and 2 are zero-dimensional(0 D) structures, and complex 3 is a dinuclear two-dimensional(2D) layer structure. They are all 3D supramolecular networks. The comparisons of the synthetic-condition effects and structure differences among 1 ～3 and our previous work complexes 4([Co_2(HO-BDC)_2(bbi)_2]·H_2O) and 5([Zn(HO-BDC)(bbi)]) have been discussed in detail. Furthermore, the luminescent properties and thermal stabilities of compounds 1～3 in the solid state have been studied.
引文
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(18)Fu,R.L.;Ma,J.F.Crystal structure of catena-(-2-5-hydroxybenzene-1,3-dicarboxylato)-(-2-1,1'-(1,4-butyl)bis(imidazole))cobalt(II),Co(C8H4O5)(C10H14N4).Z.Kristallogr.NCS.2012,227,281-282.
(19)Sheldrick,G.SHELXS-97,Programs for the X-ray Crystal Structure Solution,University of G?tingen,G?tingen 1997.
(20)Sheldrick G.SHELXS-97,Programs for the X-ray Crystal Structure Refinement,University of G?tingen,G?tingen 1997.
(21)Wang,X.F.;Yu,X.Y.;Hu,J.K.;Zhang,H.Syntheses,crystal structures and luminescent properties of two new cadmium(II)complexes based on bis(imidazole)and dicarboxylate ligands.J.Coord.Chem.2013,66,2118-2128.
(22)Yu,X.Y.;Cui,X.B.;Yang,J.J.;Zhang,J.P.;Luo,Y.H.;Zhang,H.;Gao,W.P.A series of coordination polymers constructed from in situ amidation ligands:syntheses,structures and luminescent properties.Cryst EngComm.2012,14,4719-4727.
(23)Tian,D.;Zhou,Y.H.;Guan,L.;Zhang,H.Hydrothermal syntheses,characterizations and luminescence of three new complexes based on4,6-dibenzoylisophthalic acid.J.Coord.Chem.2011,64,565-573.
(24)Wang,X.F.;Luo,Y.H.;Yang,F.F.;Yu X.Y.;Zhang,H.From 2D layer to 2D→3D parallel interpenetration:syntheses,structures and luminescent properties.J.Coord.Chem.2016,69,585-593.
(2)Lee,J.Y.;Farha,O.K.;Roberts,J.;Scheidt,K.A.;Nguyen,S.T.;Hupp,J.T.Metal-organic framework materials as catalysts.Chem.Soc.Rev.2009,38,1450-1459.
(3)Xue,M.;Zhang,Z.J.;Xiang,S.C.;Jin,Z.;Liang,C.D.;Zhu,G.S.;Qiu,S.L.;Chen,B.L.Selective gas adsorption within a five-connected porous metal-organic framework,J.Mater.Chem.2010,20,3984-3988.
(4)Wang,X.F.;Pan,Y.;Li,Z.;Li,X.;Qiu,S.L.;Xue,M.Constructing three new metal-organic frameworks based on a mixed-donor ligand:Topological analysis and fluorescence properties.Polyhedron 2017,122,55-60.
(5)Zhang,M.L.;Qiao,L.;Ma,Z.Z.;Zhao,X.L.Synthesis,crystal structure,and luminescence of a 1D chain Cd(II)polymer with3,3?,5,5?-benzene-1,3-biyl-tetrabenzoic acid.Chin.J.Struct.Chem.2017,36,1532-1536.
(6)Yang,F.F.;Wang,X.F.;Yu,X.Y.;Luo,Y.H.;Zhang,H.Coordination polymers of the bis(imidazole)ligand modulated by dicarboxylate ligands:from 2D layer to 3D framework.Polyhedron 2015,98,40-46.
(7)Ye,R.P.;Zhang,X.;Zhai,J.Q.;Qin,Y.Y.;Zhang,L.;Yao,Y.G.;Zhang,J.N-donor ligands enhancing luminescence properties of seven Zn/Cd(II)MOFs based on a large rigidπ-conjugated carboxylate ligand.CrystEngComm.2015,17,9155-9166.
(8)Zhang,S.Q.;Jiang,F.L.;Wu,M.Y.;Ma,J.;Bu,Y.;Hong,M.C.Assembly of discrete one-,two-,and three-dimensional Zn(II)complexes containing semirigid V-shaped tricarboxylate ligands.Cryst.Growth Des.2012,12,1452-1463.
(9)Liu,F.J.;Hao,H.J.;Sun,C.J.;Lin,X.H.;Chen,H.P.;Huang,R.B.;Zheng,L.S.Syntheses,structures,and photoluminescences of four Cd(II)coordination architectures based on 1-(4-pyridylmethyl)-2-methylimidazole and aromatic carboxylates:from one-dimensional chain to three-dimensional coordination architecture.Cryst.Growth Des.2012,12,2004-2012.
(10)Li,C.P.;Yu,Q.;Zhang,Z.H.;Du,M.Multifarious Zn II and Cd II coordination frameworks constructed by a versatile trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene tecton and various benzenedicarboxyl ligands.CrystEngComm.2010,12,834-844.
(11)Forster,P.M.;Stock,N.;Cheetham,A.K.A high-throughput investigation of the role of pH,temperature,concentration,and time on the synthesis of hybrid inorganic-organic materials.Angew.Chem.,Int.Ed.2005,44,7608-7611.
(12)Han,Z.B.;Ji,J.W.;An,H.Y.;Zhang,W.;Han,G.X.;Zhang,G.X.;Yang,L.G.Two 3D chiral coordination polymers with 4-connected 66topological net:synthesis,structure and magnetic properties.Dalton Trans.2009,9807-9811.
(13)Lu,Y.L.;Wu,J.Y.;Chan,M.C.;Huang,S.M.;Lin,C.S.;Chiu,T.W.;Liu,Y.H.;Wen,Y.S.;Ueng,C.H.;Chin,T.M.;Hung,C.H.;Lu,K.L.Influence of water content on the self-assembly of metal-organic frameworks based on pyridine-3,5-dicarboxylate.Inorg.Chem.2006,45,2430-2437.
(14)Kan,W.Q.;Liu,Y.Y.;Yang,J.;Liu,Y.Y.;Ma,J.F.Syntheses,structures and photoluminescent properties of a series of metal-organic frameworks based on a flexible tetracarboxylic acid and different bis(imidazole)ligands.CrystEngComm.2011,13,4256-4269.
(15)Li,X.J.;Cao,R.;Bi,W.H.;Wang,Y.Q.;Wang,Y.L.;Li,X.;Guo,Z.G.A new family of cadmium(II)coordination polymers from coligands:effect of the coexistent groups(R=H,-NO2,-OH)on crystal structures and properties.Cryst.Growth Des.2005,5 1651-1656.
(16)Liu,Y.Y.;Wang,Z.H.;Yang,J.;Liu,B.;Liu,Y.Y.;Ma,J.F.A series of coordination polymers based on reduced Schiff base multidentate anions and bis(imidazole)ligands:syntheses,structures and photoluminescence.CrystEngComm.2011,13,3811-3821.
(17)Li,X.J.;Cai,Y.Z.;Fang,Z.L.;Wu,L.J.;Wei,B.;Lin,S.Three two-folded interpenetrating 3D metal-organic frameworks consisting of dinuclear metal units:Syntheses,structures,and magnetic properties.Cryst.Growth Des.2011,11,4517-4524.
(18)Fu,R.L.;Ma,J.F.Crystal structure of catena-(-2-5-hydroxybenzene-1,3-dicarboxylato)-(-2-1,1'-(1,4-butyl)bis(imidazole))cobalt(II),Co(C8H4O5)(C10H14N4).Z.Kristallogr.NCS.2012,227,281-282.
(19)Sheldrick,G.SHELXS-97,Programs for the X-ray Crystal Structure Solution,University of G?tingen,G?tingen 1997.
(20)Sheldrick G.SHELXS-97,Programs for the X-ray Crystal Structure Refinement,University of G?tingen,G?tingen 1997.
(21)Wang,X.F.;Yu,X.Y.;Hu,J.K.;Zhang,H.Syntheses,crystal structures and luminescent properties of two new cadmium(II)complexes based on bis(imidazole)and dicarboxylate ligands.J.Coord.Chem.2013,66,2118-2128.
(22)Yu,X.Y.;Cui,X.B.;Yang,J.J.;Zhang,J.P.;Luo,Y.H.;Zhang,H.;Gao,W.P.A series of coordination polymers constructed from in situ amidation ligands:syntheses,structures and luminescent properties.Cryst EngComm.2012,14,4719-4727.
(23)Tian,D.;Zhou,Y.H.;Guan,L.;Zhang,H.Hydrothermal syntheses,characterizations and luminescence of three new complexes based on4,6-dibenzoylisophthalic acid.J.Coord.Chem.2011,64,565-573.
(24)Wang,X.F.;Luo,Y.H.;Yang,F.F.;Yu X.Y.;Zhang,H.From 2D layer to 2D→3D parallel interpenetration:syntheses,structures and luminescent properties.J.Coord.Chem.2016,69,585-593.