摘要
基于尾煤的高灰、难处理等特点,利用热重分析和管式炉热解实验,研究了升温速率、温度及催化剂等因素下尾煤、废轮胎热解特性及产品收率情况。进而探讨了尾煤和废轮胎在不同配比、升温速率、终温及催化剂条件下的共热解特性及产品分布。尾煤和废轮胎共热解TG-DTG曲线显示,共热解的特征温度和失重峰面积均优于单独热解,存在协同作用。对煤矸石作催化剂初步研究表明煤矸石在热解中有较好的催化效果。尾煤管式炉实验表明,30g尾煤950℃最大产气4300mL,产氢气1722mL,850℃液体产率最高达6%。30g尾煤和废轮胎共热解实验显示,温度和配比对产率有重要影响。尾煤和废轮胎在质量比3：1时协同效应显著,随着尾煤增加液相产率降低,气相产量先升高后减少,反应由液相控制过程向尾煤热解过程过度,最大产气量5100mL,产油率12.11%,研究的氧化钙、金属铁和煤矸石三种催化剂中,氧化钙的产气量最好,煤矸石次之,其次是金属铁。尾煤和废轮胎在3：1比例下共热解半焦热值大约12540kJ/kg,液体热值20900kJ/kg,具备良好的应用前景。
Based on the characteric of high ash component and difficult to treat, the characteric of production and distribution on taillings and waste tire are researched respectively at heating rate and temperature and catalytic.Using TGA and fixed-bed reactor, the behavior and products of the co-pyrolysis on tailings and waste tires are discussed at the different of heating rate and temperature and catalyst.The curve of TG-DTG show that the characteristics temperature and weight loss peak area of copyrplysis were better than the separately pyrolysis and there is a synergistic effect. Gangue as a catalyst to carry out a preliminary study results show that gangue has a better catalytic effect in pyrolysis.The result of tailings pyrolysis show that the maximum production of total gas and hydrogen respectively is4000mL and1722mL at950℃,the maximum production of liquid is6%at850℃.The fixed-bed experiments by30charges reveal that gas production increased and liquid first increased and then decreased with increasing temperature. Experiment of co-pyrolysis in the fixed-reactor reveal that the mass ratio of3:1of tailings and waste tires has a good synergistic effects. Liquid yield decreased and gas production firstly increased then decreased and the reaction from liquid behaviors to gas behaviors with increasing tailings and the maximum production of gas is5100mL and the maximum liquid production is12.11%. The yield of gas is highest with calcium oxide and gangue took second place and the yield of liquid is west with metallic iron. Co-pyrolysis of3:1has a good yield and reuse value and calorific value of char and liquid is respectively12540kJ/kg and20900kJ/kg.
引文
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