分级机用高铬铸铁叶片组织与性能的研究
详细信息    本馆镜像全文|  推荐本文 |  |   获取CNKI官网全文
摘要
本文在对分级机工况条件与工作原理进行分析的前提下,选择高铬铸铁代替原使用的灰铸铁作为分级机叶片材料,并通过试验研究了高铬铸铁叶片的成份、组织和性能。主要内容有:对分级机叶片进行受力和失效分析;确定高铬铸铁的成分、熔炼、铸造及热处理工艺,浇注试样;探讨了不同热处理工艺下,试样基体组织和碳化物的变化及其对试样力学性能和耐磨性的影响;通过金相观察、X射线衍射分析、能谱分析、洛氏硬度实验、冲击韧性实验、耐磨性实验、磨损试样的磨损面观察和冲击断口观察研究试样组织与性能之间的关系;确定最佳热处理工艺,制取叶片,并投入工艺性实验。
     高铬铸铁叶片最终确定成分为:碳3.0%、铬14.0%、硅1.3%、锰1.3%、钒0.1%、硫,磷<0.05%。在本实验温度范围内,850℃正火+回火态试样具有最佳综合力学性能。实验结果表明:高铬铸铁叶片成分中加入的钒对组织有很好的细化作用;叶片材料在铸态下基体组织中就出现了大面积分布的屈氏体,正火后基体组织向更多的屈氏体分布发展,同时基体中残余奥氏体量增多,试样硬度降低,冲击韧性提高,断裂类型由脆性断裂变为准解离+韧窝混合断裂;回火后残余奥氏体量减少,残余奥氏体量在21.67%时,合金材料耐磨性最佳。
     此外,本文将在叶片底部出现的粒状珠光体组织与叶片顶部、中部出现的层片状珠光体组织进行比较,并对前者形成原因及其对性能的影响进行了研究。研究结果表明:基体宏观偏析是粒状珠光体形成的主要原因;粒状珠光体的硬度和冲击韧性均优于层片状珠光体,但耐磨性较差;在本实验温度范围内,随着正火温度提高,珠光体球化更完全。900℃正火试样珠光体球化完全,但耐磨性较差,850℃正火试样拥有最佳耐磨性。
On the premise of analyzing the working condition and the working principle of the classifier blade, high chromium white cast iron were chosen for the material of classifier blade instead of gray cast iron. The microstructure and properties of the classifier blade were also researched by experiment. In the paper, stress analyzing and failure analysis of the classifier blade were carried, the composition and the process of smelting, casting and heat-treatment of high chromium cast iron were decided. The changes of matrix microstructure and carbide of high chromium cast iron and the effect on performance were studied with different heat treatment process. By means of microstructure observation, X-ray Difractometer (XRD), Scanning Electron Microscopy (SEM) with Energy Dispersive Spectrometer (EDS), rock well hardness test, impact-toughness test, abrasive wear test and observation of the wear surface and the as-cast morphology of impact fracture, mechanical properties and wear resistance were researched. The optimal heat treatment process was determined, preparate blade,then put it into manufacturability experiment.
     The chemical composition selected ultimately of the high alloy white cast iron blade: chromium 14.0%,carbon3.0%,vanadium0.1%,silicon1.3%,manganese1.3%,sulphur andphosphorus<0.05%. In the experimental temperature range, the sample after normalized at 850℃and tempering have best overall mechanical properties. The experimental results indicate that: Vanadium in the high chromium white cast iron blade is beneficial to refining microstructures; large distribution of the troostite in matrix structure of area appeared in the material of blade at as-cast. With normalized temperature increasing, troostite quantity and residual austenite both increasd, the strength decreased and the toughness improved. The fractographic features transferred brittle fracture to quasi-cleavage fracture and dimple fracture mixed features; After tempering, the amount of retained austenite decreased. Alloy has best wear resistance, when the amount of retained austenite is 21.67%.
     Moreover, the structure of the granular pearlite appeared at the bottom and lamellar pearlite on the top or middle of the blade were compared, and the forming reason of the former and the influence on the properties were also studied. The results show that the main cause of pearlite spheroidization is the macro-segregation of the matrix.. Both hardness and impact toughness of the granular pearlite are better than the lamellar pearlite's, but the lamellar wear resistance of pearlite is weaker. In the experimental temperature range, as normalized temperature rising, pearlite spheroidization process more absolutely. Sample at 900℃normalized whose wear resistance is weaker have spheroidized absolutely, and the sample at 850℃normalized have best wear resistance.
引文
[1]谢振军.选矿设备的应用现状.矿业快报[J],2003,8(8):1-4
    [2]IISI.Macquarie Research.2006(12)
    [3]陈炳辰.磨矿分级(上).金属矿山[J],1999,10(11):12-17
    [4]于永琪,段树桐.水力分级机的应用现状及技术改进建议.中国非金属矿工业导刊[J],2007,25(3):44-46
    [5]韩英,尤官林.关于超细分级机几个问题的探讨.武汉化工学院学报[J],1999,21(2):39-43
    [6]杨华明,王淀佐.超细粉碎技术的进展.金属矿山[J],1998,12(9):20-27
    [7]郑水林.超细粉碎原理.工艺设备及应用.中国建材工业出版社[M],1993:1-214
    [8]倪玲英.水力旋流器的研究现状及其在石油工业中的应用前景.过滤与分离[J],1999,8(3):1-4
    [9]陈炳辰.磨矿分级(下).金属矿山[J],1999,282(12):16-24
    [10]张鹏飞,黄枢.新型水力旋流器的研究和应用.金属矿山[J],1993,8(3):47-51
    [11]庞学诗.水力旋流器的发展特点.国外金属矿选矿[J],1996,9(5):33-34
    [12]王宗林,杨任新,张志华.螺旋分级筛分机的研制及工业试验.金属矿山[J],1998,26(2):27-30
    [13]周兴龙,张文彬,王文潜.国内外水力重力分级设备研究应用进展.矿冶工程[J],2005,24(2):23-30
    [14]盖国胜,徐政,彭晓.超细粉碎与分级技术年评.第八届选矿年评报告文集[C],1997:138-157
    [15]王永章.高频振动细筛在密云铁矿的应用及其经济效益.金属矿山[J],1990,16(1):36-41
    [16]习淑芳,张世礼.非金属矿物工艺及工厂设计概述.矿山机械[J],2000,9(4):22-24
    [17]王漪靖,朱永安.金堆城旋流器分级和螺旋分级比较研究.有色金属[J],2003,19(6):36-39
    [18]郗芳,谢良友,王延亮.新型分级机的研制.新疆钢铁[J],2001,8(4):7-8
    [19]李树荣,陈希杰.高锰钢的发展与应用.矿山机械[J],1998,25(3):70-71
    [20]张敬澈.提高奥氏体锰钢耐磨性的探讨.铸造[J],1991,19(9):29-31
    [21]谢敬佩,李卫,宋延沛等.耐磨铸钢及熔炼.机械工业出版社[M],2003:46-65
    [22]贺同正,仝健民.高铬铸铁叶片材质研究.机械工程材料[J],2001,12(6):27-31
    [23]刘超锋,纪莲清,刘建秀.孕育剂对灰铸铁件不同性能的影响.铸造[J],2007,8(10):12-14
    [24]辜祖勋.高强度灰铸铁件典型质量问题探讨.中国铸造装备与技术[J],2007,11(4):26-30
    [25]Wiengmoon A,Chairuamgsri T,Pearce J.T.H.A.Microstructural Study of Destlabilizd 30wt%Cr-2.3wt%C High Chromium Cast Iron,ISIJ International[J],2004(2):396-403
    [26]乔晓梅,王文平.铬系耐磨铸铁研究状况.陕西机械[J],2000年增刊,26(2):19-22
    [27]彭晓春,张长军.27%Cr高铬铸铁组织及性能研究.机械工程材料[J],2005,23(11):35-37
    [28]苏俊义.铬系耐磨白口铸铁.国防工业出版社[M],1990:85-124
    [29]管一非,高立爱,刘江义.球磨机用高铬铸铁球的变质处理工艺研究.机械管理开发[J],2005,18(2):8-9
    [30]潘传宏.抗磨白口铸铁的强韧化处理.材料开发与应用[J],2001,15(6):13-15
    [31]王耀敏,纪胜珏.冲天炉生产低铬合金铸铁磨球.江苏冶金[J],1999,8(6):29-30
    [32]王文才,刘根生,李海鹏等.Si/C和冷却速度对中铬铸铁铸态组织和性能的影响.河北工业大学学报[J],2001,30(3):16-20
    [33]刘国宇,刑建东,高义民.铬系耐磨铸铁的研究与展望.水利电力机械[J],2003,32(1):31-34
    [34]熊博文,张军,吴振卿.碳化物对高铬铸铁高应力磨料磨损的影响.铸造技术[J],2005,26(10):944-946
    [35]F.H.Herbstein,J.A.Snyman.Inorg.Chem[M],1964,3:804
    [36]李玉和,文玉庆.在高温下钒对高铬铸铁耐磨性的影响.四川冶金[J],1995,32(7):17-25
    [37]马永庆,戴乐阳.高铬铸铁高温马氏体相变与摩擦诱发马氏体相变关系的研究.物理测试[J],2002,18(1):13-15
    [38]蒋业华,周荣.控制冷却获得贝氏体/马氏体球墨铸铁的组织转变及耐磨性.铸造[J],1999,21(3):20-23
    [39]于广文,孙玉福,李志明等.钨对Cr24高铬铸铁组织及性能的影响.铸造[J],2007,13(12):24-26
    [40]BEDOLLA Jacuinde A,RAINFORTH W M.The wear behaviour of high-chromium white cast irons as a function of silicon and Mischmetal content[J].Wear.2001(250):449-461
    [41]周永欣,吕振林.铸态贝氏体白口铁磨球组织与性能的研究.热加工工艺[J],2001,32(2):31-34
    [42]王铁重.我国磨球的生产及使用状况.水利电力机械[J],2005,35(6):32-33
    [43]张祥珍.铸态屈氏体高铬合金磨球的试验与使用.福建建材[J],1996,13(1):22-23
    [44]周忠林,孙廷祥.高铬铸铁的研究与应用现状.中国建材装备[J],1996,8(11):35-39
    [45]胡建军,张子伦.屈氏体高铬铸铁球的生产工艺对磨球质量的影响.中国锰业[J],1999,28(11):43-45
    [46]胡建军,康仁,钱火根.屈氏体高铬铸铁球在永平铜矿的应用.矿冶工程[J],2000,36(6):23
    [47]闫华,谢敬佩,王文焱.超高锰钢耐磨性及其冲击磨料磨损行为的研究.铸造技术[J],2007,11(5):618-621,627
    [48]Emin Bayraktar,Fazal A.Khalid,Christophe Levaillant.Deformation and fracture behavior of high manganese austenitic steel.Journal of Materials Processing Technology[J],2004(147):145-154.
    [49]赵中玲.高铬铸铁磨损性能的研究.黑龙江交通科技[J],2007,31(5):42-46
    [50]武宏,刘文刚,许云华.冷轧高锰钢耐磨性及磨损机制研究.润滑与密封[J],2007,13(6):32-35
    [51]Karimi A,Verdon C.Slurry erosion behavior of thermally sprayed WC-coating.Wear[J],1995,186(11):480-486
    [52]羊浩,蒋业华,李祖来.不同磨料粒度下WC体积分数对铁基表面复合材料磨损性能的影响.铸造,2007,86(11):28-30
    [53]姜晓霞,李诗卓,赵先明.耐磨耐蚀钢发展途径的探索.材料研究学报[J],1994,46(4):35-42
    [54]熊博文,龙文元,万红.高铬铸铁复合磨辊磨料磨损研究.矿山机械[J],2007,56(4):15-21
    [55]Arnold B K,Heijkoop T,Lloyd P G.Wear of cast-bonded components in a coal pulverizer mill.Wear[J],1997(24):663-670.
    [56]张复宝.高铬合金耐磨铸铁生产技术.机械工人(热加工)[J],2007,25(1):66-67
    [57]李玄军,赵红杰.合金元素在高铬铸铁中的作用.河南冶金[J],1999,46(2):28-30
    [58]向红亮.几种磨盘材料耐磨性研究.中国造纸学报[J],2007,32(1):77-79
    [59]马幼平,李俊,刘玉高.碳量变化对高铬铸铁初生奥氏体稳定性的影响.铸造[J],2006,6(10):1079-1081
    [60]向道平,唐建新.Cr/C比及热处理工艺对高铬铸铁抗磨粒磨损性能的影响.热加工工艺[J],2004,43(5):21-23
    [61]彭晓春,张长军.27%Cr高铬铸铁组织及性能研究.机械工程材料[J],2005,25(11):35-37
    [62]马中立,朱宏远.Cr27抗磨白口铸铁的研究及生产应用.北京工业大学学报[J],1999,16(1):88-92
    [63]子澍,宋润泽,张云霞.高铬抗磨白口铸铁化学成分的最佳设计.现代铸铁[J],2005,25(6):23-25
    [64]周庆德,饶启昌,苏俊义.铬系抗磨铸铁.西安交通大学[M],1986:113-124
    [65]于春田.含硅量和冷却速度对中铬铸铁碳化物的影响.铸造[J],2001,32(5):258-262
    [66]段汉桥.锰对高铬铸铁凝固过程和组织的影响.热加工工艺[J],2001,8(3):23-25
    [67]Yu.s.k,Matsulara Y.Abrasion wear resistance of alloyed white cast iron with several types of carbide sand matrices.AFS Trans[J],1998(106):53-58
    [68]王玉玮,石雯.钒在高铬铸铁中的作用.铸造[J],1989(5):9-12
    [69]黄继武.MDI JADE使用手册.中南大学[M]:16-26
    [70]王均,孙志平,刘浩怀等.一种高铬白口铸铁亚临界处理的硬化动力学研究.铸造[J],2003, 9(11):1065-1068
    [71]周玉,武高辉.材料分析测试技术.哈尔滨:哈尔滨工业大学出版社[M],1998:45-62
    [72]祁景玉.X射线结构分析.同济大学出版社[M].2003:56-72,166-172
    [73]湖南邵阳汽车保养厂热处理问答编写小组.热处理问答.机械工业出版社[M],1974:30-31
    [74]Zum GahrKH.Abrasive wear of White Cast Iron.Wear[J],1980(64):176-194.
    [75]何崇智.X射线衍射实验技术.上海:科学技术出版社[M],1988:140-158
    [76]甘宅平.高铬铸铁残余奥氏体测定方法的探讨.钢铁研究[J],2002,31(6):18-20
    [77]宛农,董建新,谢锡善.15Cr系高铬铸铁组织特征的热力学分析.铸造[J]2005,11(4):23-25
    [78]Collins DN,Donmer.J.Deep cryogenic treatment of a D2 Cold-work tool steel.Heat Treatment of Metals[J],1997(3):71-74.
    [79]漆睿,戎泳华.X射线衍射与电子显微分析.上海交通大学出版社[M],1992(9):35-40,46-52
    [80]郝石坚.铬系耐磨铸铁.煤炭工业出版社[M],1986:156-232
    [81]王文才,刘根生.矿山用高铬多元合金铸铁磨球.金属矿山[J],1994,13(4):43-47.
    [82]Kootsookos A,Gates J D.The effect of the reduction of carbon content on toughness of hi chromium white iron in the as-cast state.JoumaI of MaterialsScience[J],2004(1):73-84.
    [83]李海鹏,梁春永,王立辉.热处理对中铬铸铁组织和性能的影响.热加工工艺[J],2006,12(10):40-46
    [84]M.Izciler,H.Celik.Two-and three-body abrasive wear behaviour of different heat-treated boron alloyed high chromium cast iron grinding balls.Jounal of Materials Processing Technology[J],2000(105):237-245.
    [85]苏俊义.定向凝固高铬铸铁耐磨性的初探.西安交通大学学报[J],1983,25(4):59-64
    [86]O.N.Dogan,J.A.Hawk.Effect of carbide orientation on abrasion of high Cr white cast iron.Wear[J],1995(189):136-142.
    [87]D.Mohan Lal,S.Renganarayanan,A.Kalankdhi.Cryogenic treatment to augment wear resistance of tool and die steels.Cryogenics[J],2001(41):149-155.
    [88]王兆昌,周年.奥氏体白口铸铁与马氏体白口铸铁的磨料磨损行为及抗磨性能.铸造[J],1993,2(9):24-28.
    [89]崔忠圻.金属材料学及热处理.北京:机械工业出版社[M],1995:160-195
    [90]高万夫.15CrMo钢珠光体球化对机械性能的影响.石油化工高等学校校报[J],1997,46(4):40-42
    [91]孔祥军,张国福,宋天民等.15CrMo钢珠光体球化对减粘塔管线的影响.石油化工腐蚀与防护[J],2006,48(6):43-44
    [92]赵登志,鞠占英,宋静.温度对12CrlMoV钢管珠光体球化及力学性能的影响.电站系统工程[J], 2002,28(3):58-59
    [93]李文学,闫俊萍,张风云等.3Cr2W8钢的珠光体转变.包头钢铁学院学报[J],2003,9(22):232-235
    [94]樊亚军,蔺卫平,张占领等.球化工艺对热轧超高碳钢组织性能的影响.热加工工艺[J],2006,18(20):13-16
    [95]叶以富.影响低铬系白口铸铁中碳化物团球化的几个因素.铸造技术[J],1986,22(3):4
    [96]张茂勋,大城桂作.高铬铸铁耐磨粒磨损特性.机械工程材料[J],1991,15(4):5-22
    [97]叶以富,范同翔.白口铸铁碳化物的团球化.现代铸铁[J],1995,19(3):28-32