Occurrence of coalbed methane (CBM) is different from that in shallow seam, and a new method is demanded to predicate deep CBM content. Based on the isothermal methane adsorption experiments of coal samples under various temperature and pressure, geological controls of coal adsorption constants was discussed and a predicting method for deep CBM content was established with principal component analysis in a case of the main coal seam in the eastern Ordos Basin. A predicating model of deep CBM content was set up based on the Langmuir equation combining with gas saturation. Using the models, deep CBM content in the eastern Ordos Basin was predicted.