Through the electron probe microanalysis of biotites from Caixi, Sifang and Luoboling plutons in southwestern Fujian Province, the paper discusses their geochemical characteristics and petrogenesis implication. The results indicate that the biotite in Caixi monzogranite can be classified into high-Fe type, and the biotite in Sifang and Luoboling granodiorites into high-Mg type. On the material source discrimination diagram, the compositions of biotites are plotted in the crust-mantle zone, implying that all of the plutons belong to the crust-mantle granitoids and that with the ages of the granitoids becoming younger more mantle constituents were mingled in their materials compositions during the formation of granitoids.