安徽金寨县沙坪沟钼矿成矿岩体矿物学特征及其成岩成矿意义
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摘要
安徽金寨县沙坪沟钼矿成矿岩体主要包括二长花岗斑岩、正长斑岩及花岗斑岩,主要矿物组成为石英、钾长石、斜长石、黑云母。本文利用电子探针技术对主要矿物的矿物学特征进行了研究,结果表明,岩石中斜长石为钠长石;钾长石以条纹长石为主;黑云母属于镁质黑云母,富Mg、Al、K,贫Ca,MF值变化于0.65~0.72之间。黑云母化学成分显示本区岩体为I型花岗岩,属于造山带钙碱性花岗岩类,其成岩物质具壳幔混合的特点。黑云母矿物温压计计算结果显示,岩体固结温度约500~580℃,氧逸度变化范围是10-14~10-15.8,其含铁指数对寻找钼矿具较好的指示意义。
The Shapinggou molybdenum deposit in Jinzhai County of Anhui Province is situated in the QinlingDabie orogenic belt, with mineralization substantially hosted in monzonitic granite porphyry, syenite porphyry and granite porphyry. Microscopic observation shows that the rocks mainly consist of plagioclase, potassium feldspar, biotite and quartz. With these minerals as the study objects, the authors used electron microprobe technology to analyze their mineralogical characteristics, and the results show that,in the rocks, the plagioclase is albite, K-feldspar is mainly perthite, and biotite is Mg-biotite rich in Mg,Al and K and depleted in Ca,with MF changing from 0.65 to 0.72. Chemical composition of biotite suggests that the intrusion is I-type granite,which is a sort of calc-alkali orogenic granite, materially sourced from both the crust and the mantle. Biotite geothermometer and geobarometer imply that the intrusion was consolidated at 500~ 580℃, with the oxygen fugacity ranging from 10- 14 to 10- 15.8 and the iron index being a good indicator for molybdenum mineralization.
The Shapinggou molybdenum deposit in Jinzhai County of Anhui Province is situated in the QinlingDabie orogenic belt, with mineralization substantially hosted in monzonitic granite porphyry, syenite porphyry and granite porphyry. Microscopic observation shows that the rocks mainly consist of plagioclase, potassium feldspar, biotite and quartz. With these minerals as the study objects, the authors used electron microprobe technology to analyze their mineralogical characteristics, and the results show that,in the rocks, the plagioclase is albite, K-feldspar is mainly perthite, and biotite is Mg-biotite rich in Mg,Al and K and depleted in Ca,with MF changing from 0.65 to 0.72. Chemical composition of biotite suggests that the intrusion is I-type granite,which is a sort of calc-alkali orogenic granite, materially sourced from both the crust and the mantle. Biotite geothermometer and geobarometer imply that the intrusion was consolidated at 500~ 580℃, with the oxygen fugacity ranging from 10- 14 to 10- 15.8 and the iron index being a good indicator for molybdenum mineralization.
引文
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Li Yongfeng,Mao Jingwen,Hu Huabin,et al.2005.Geology,distribution,types and tectonic settings of Mesozoic molybdenum depositsin East Qinling area[J].Mineral Deposits,24(3):292~304.
Liu Bin,Ma Changqian,Liu Yuanyuan,et al.2010.Mineral chemistry of biotites from the Tongshankou Cu-Mo deposit Implications for petrogenesis and mineralization[J].Acta Petrologica et Mineralogica,29(2):151~165(in Chinese).
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Meng Xiangjin,Xu Wenyi,Lu Qintian,et al.2012.Zircon U-Pb Dating of Ore-Bearing Rocks and Molybdenite Re-Os Age in Shapinggou Porphyry Molybdenum deposit,Anhui Province[J].Acta Geologica Sinica,48(3):486~493(in Chinese).
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Smith J V.1974.Feldspar Mineral[M].New York:Springer-Verlag Berlin and Heidelberg,1~200.
Stone D.2000.Temperature and pressure variations in suites of archean felsic plutonic rocks,Berens river aera,northwest superior province,Ontario,Cananda[J].The Canadian Mineralogist,38:455 ~470.
Wang Xiaoxia and Lu Xinxiang.1998.A Study of biotite from the Shahewan Rapakivi granite in Qinling and its significance[J].Acta Petrologica et Mineralogica,17(4):352~358(in Chinese).
Wones D R and Eugster H P.1965.Stability of biotite:experiment,theory,and application[J].Am.Mineral.,50:1 228~1 235.
Wones D R.1989.Significance of the assemblage titanite+magnetite+quartz in granitic rocks[J].Am.Mineral.,74:744~749.
Xu Xiaochun,Lou Jinwei,Lu Sanming,et al.2009.Re-Os age of molybdenum-lead-zinc polymetallic deposits and 40Ar-39Ar ages of related magmatic rocks in Yinshan area,Jinzhai,Anhui Province[J].Mineral Deposits,28(5):621~632(in Chinese).
Yu Wen,Ni Pei,Wang Guoguang,et al.2012.Evolution of ore-forming fluids of the Shapinggou Porphyry moloybdenum deposit,Jinzhai,Anhui Province[J].Journal of Nanjing University(Natural Sciences),48(3):240~255(in Chinese).
Zhang Dongyang,Zhang Zhaochong,Ai Yu,et al.2009.Mineralogy of ore-bearing porphyries in Lailisigao'er area of the West Tianshan Mountain and its implications for petrogenesis and mineralization[J].Acta Petrologica et Mineralogica,28(1):3~16(in Chinese).
Zhang Hong,Sun Weidong,Yang Xiaoyong,et al.2011.Geochronology and Metallogenesis of the Shapinggou Giant Porphyry Molybdenum Deposit in the Dabie Orogenic Belt[J].Acta Geologica Sinica,85 (12):2 039~2 059(in Chinese).
Zhang Huaidong,Shi Dongfang,Hao Yuejin,et al.2010.Geological features of the shapinggou porphyry molybdenum ore deposit,Jinzhai county,Anhui Province[J].Geology of Anhui,20(2):104~108(in Chinese).
Zhang Huaidong,Wang Bohua,Hao Yuejin,et al.2012.Geological characteristics and comprehensive ore-prospecting information of Shapinggou porphyry-type molybdenum deposit in Anhui Province[J].Mineral Deposits,31(1):41~51(in Chinese).
Zhang Huaidong,Wang Genjie and Shi Dongfang.2010.Metallogenic conditions of the Shapinggou porphyry molybdenumore deposit,Jinzhai county,Anhui Province and the prospecting direction[J].Shanghai Geology,31:203~205(in Chinese).
Zhang Zhengwei and Deng Jun.2001a.Geological setting of the eastern Qinling molybdemun ore belt and features of the Mo-associated intrusion[A].Chen Yanjing,Zhang Jing and Lai Yong.Continental Geodynamics and Metallogenesis[C].Beijing:Seismological Press,100 ~109(in Chinses).
Zhang Zhengwei,Zhu Bingquan,Chang Xiangyang,et al.2001.Petrogenetic metallogenetic background and time space relationship of the East Qinling molybdenum ore belt,China[J].Geological Journal of China University,7(3):307~315(in Chinese with English abstract).
Zhao Xilin and Mao Jianren.2010.Characteristics of biotites and their petrogenesis implication of late Yanshanian granites in southwestern Fujian province[J].Resources Survey and Environment,31(1):12 ~18(in Chinese).
Zhou Zuoxia.1988.Chemical characteristics of mafic mica in intrusive rocks and its geological meaning[J].Acta Petrologica Sinica,3:63~73(in Chinese).
陈光远,孙岱生,周王旬若,等.1993.胶东郭家岭花岗闪长岩成因矿物学与金矿化[M].北京:中国地质大学出版社,107~140.
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