江西彭山锡多金属矿集区隐伏花岗岩体的岩石地球化学、锆石U-Pb年代学和Hf同位素组成
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摘要
本文对江西彭山锡多金属矿集区隐伏花岗岩体进行了详细的锆石U-Pb年代学、Hf同位素组成和岩石地球化学研究。SHRIMP和LA-ICP-MS锆石U-Pb定年表明,该岩体年龄为128~129Ma,属燕山晚期岩浆活动的产物。详细的地球化学分析显示,彭山隐伏花岗岩体具有高硅(SiO2=75.42%~76.46%)、富碱(Na2O+K2O=7.93%~8.35%,K2O/Na2O=1.32~1.61)的特征,极度贫Mg(普遍MgO=0~0.07%),贫Ca(CaO=0.37%~0.69%),弱过铝质(A/CNK=1.04~1.11),富集Rb、Th、U等大离子亲石元素及Hf、Nb等高场强元素,强烈亏损Sr、Ba、Eu、P、Ti。稀土总量偏低(∑REE=41.18×10-6~85.06×10-6),强烈的Eu负异常(Eu/Eu*=0.05~0.11)。104×Ga/Al比值变化于2.75~4.04,平均值为3.19。这些特征均不同于典型的A型和S型花岗岩。岩石学和地球化学特征指示该岩体可能是一个高分异的I型花岗岩。该花岗岩中锆石εHf(t)值偏高,主要集中在-0.6~-4.5,显示在成岩过程中有地幔组分的参与,属壳幔混源花岗岩,推测该岩体的形成可能与燕山晚期华南岩石圈伸展拉张环境有关。
In this study,we carried out a comprehensive research including zircon U-Pb dating and Hf isotopic composition analysis,and petrochemistry on the granite related to the Huangjinwa tin deposit in Pengshan Sn-polymetallic orefield,Jiangxi Province,China.SHRIMP and LA-ICP-MS zircon U-Pb chronology indicated that the Pengshan granitic pluton emplaced at 128~129Ma.Chemical analyses show the Pengshan granite has high SiO2(SiO2=75.42%~76.46%),high alkaline(Na2O+K2O=7.93%~8.35%,K2O/Na2O=1.32~1.61)contents,low Mg and Ca(MgO= 0~0.07%,CaO=0.37%~0.69%),weakly peraluminous(A/CNK=1.04~1.11),enriched in LILEs such as Rb,Th,U,and HFSEs such as Hf and Nb,and depleted in Sr,Ba,Eu,P,and Ti.The rocks also display low total REE contents(∑REE=41.18×10-6~85.06×10-6)with strong negative Eu anomalies(Eu/Eu=0.05~0.11).The 104×Ga/Al ratios vary from 2.75 to 4.04,averaging 3.19.These characteristics indicate that the Pengshan granite is different from typical S-type or A-type granites.Overall,our integrated petrological and geochemical data suggest that the rocks are highly fractionated I-type granite.Zircon Hf isotope analyses show relatively homogeneous Hf isotopic compositions,with εHf(t)values from-0.6 to-4.5,which are higher than many of the granites in South China,and may indicate a significant involvement of mantle component in petrogenesis.The granite was likely generated via crust-mantle interaction during Late Yanshanian lithosphere extension events in South China.
In this study,we carried out a comprehensive research including zircon U-Pb dating and Hf isotopic composition analysis,and petrochemistry on the granite related to the Huangjinwa tin deposit in Pengshan Sn-polymetallic orefield,Jiangxi Province,China.SHRIMP and LA-ICP-MS zircon U-Pb chronology indicated that the Pengshan granitic pluton emplaced at 128~129Ma.Chemical analyses show the Pengshan granite has high SiO2(SiO2=75.42%~76.46%),high alkaline(Na2O+K2O=7.93%~8.35%,K2O/Na2O=1.32~1.61)contents,low Mg and Ca(MgO= 0~0.07%,CaO=0.37%~0.69%),weakly peraluminous(A/CNK=1.04~1.11),enriched in LILEs such as Rb,Th,U,and HFSEs such as Hf and Nb,and depleted in Sr,Ba,Eu,P,and Ti.The rocks also display low total REE contents(∑REE=41.18×10-6~85.06×10-6)with strong negative Eu anomalies(Eu/Eu=0.05~0.11).The 104×Ga/Al ratios vary from 2.75 to 4.04,averaging 3.19.These characteristics indicate that the Pengshan granite is different from typical S-type or A-type granites.Overall,our integrated petrological and geochemical data suggest that the rocks are highly fractionated I-type granite.Zircon Hf isotope analyses show relatively homogeneous Hf isotopic compositions,with εHf(t)values from-0.6 to-4.5,which are higher than many of the granites in South China,and may indicate a significant involvement of mantle component in petrogenesis.The granite was likely generated via crust-mantle interaction during Late Yanshanian lithosphere extension events in South China.
引文
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