贵州金鼎山下寒武统黑色岩系的有机地球化学特征
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摘要
对贵州遵义金鼎山下寒武统牛蹄塘组黑色岩系的氯仿沥青“A”及族组分做了成分检测,并进行了岩石氯仿抽提物中饱和烃气相色谱分析。结果表明,黑色岩系属生油岩,且为腐泥型和混合型生油岩,以腐泥型为主;黑色岩系有机质丰度高,有机质主要来源于海生低等菌、藻类生物;黑色岩系姥姣烷与植烷比值、岩性和生物特征指示其形成于一种缺氧还原沉积环境。
This paper deals with the formation conditions of black shales on the basis of analyzing such items as the component of chloroform bitumen "A" and the gas_facies chromatogram of saturated hydrocarbon. Studies show that the Lower Cambrian black shales in Jindingshan of Guizhou Province are sapropelic type and mixed type oil_forming rocks. The black shales are characterized by high content of organic matters, and the organic sources are algae and fungi. Organic geochemical features indicate that black shales were formed in an anoxic sea environment.
This paper deals with the formation conditions of black shales on the basis of analyzing such items as the component of chloroform bitumen "A" and the gas_facies chromatogram of saturated hydrocarbon. Studies show that the Lower Cambrian black shales in Jindingshan of Guizhou Province are sapropelic type and mixed type oil_forming rocks. The black shales are characterized by high content of organic matters, and the organic sources are algae and fungi. Organic geochemical features indicate that black shales were formed in an anoxic sea environment.
引文
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BernhardPeucker_EhrenbrinkandHanniganRE.2000.Effectsofblack shaleweatheringonthemobilityofrheniumandplatinumgroupele ments[J].Geology,28(5):475~478.
ChenHuayongandZhangZengjie.2001.Themultipurposeuseofmin eralresourceofblackshaleinthenorthwestHunan[J].Geologyand Prospecting,37(3):32~35(inChinesewithEnglishabstract).
ChuXL,SunMandZhouMF.2001.Theplatinum_groupelement geochemistryinchemicalgeodynamics[J].ActaPetrologicaSinica,17(1):1212~1229.
ClarkRCandBlumerM.1967.Distributionofn_poraffinesinmarine organismsandsediment[J].LimnolOceanogr,12:79~87.
CoveneyRMandNanshengC.1991.Ni_Mo_PGE_Au_richoresinChi neseblackshalesandspeculationsonpossibleanaloguesintheUnited States[J].MineraliumDeposita,26(2):83~88.
CoveneyRM,MurowchickJB,GrauchRI,etal.1992.Fieldrela tions,origins,andresourceimplicationsforplatiniferousMolybde num_NickeloresinblackshalesofsouthChina[J].Explor.Mining Geol.,1(1):21~28.
FanDelian,YangXiuzhen,WangLianfang,etal.1973.Petrological andgeochemicalcharacteristicsofaNi_Momulti_element_bearing LowerCambrianblackshalefromacertaindistrict[J].Geochimica,3:143~163(inChinesewithEnglishabstract).
GaoZhenmin,LuoTaiyiandLiShengrong.1997.Theoriginofmetal-enrichedlayerintheblackrockseries[J].Geology-Geochem istry,1:18~23(inChinesewithEnglishabstract).
HuKai,LiuYingjun,WangHenian,etal.1995.Theoriginandor ganicgeochemistrycharacteristicsofgolddespoitsincarbonicrock series,southofChina[J].ScienceinChina(SeriesB),25(10):1099~1107(inChinese).
HuangZhanqi,ShenCunliandWangShouguang.2002.Oreprospects ofplatinum_groupelementdepositshostedinblackshalesinthe Langshan-Zha’ertaishanarea,InnerMongolia[J].GeologicalBul letinofChina,21(10):663~667(inChinesewithEnglishab stract).
LeiJiajin,LiRenwei,TobschallHJ,etal.2000a.Theoriginandsul phurcharacteristicsofEarlyCambrianblackshalesonthesouth fringeofYangtzeplatform[J].ScienceinChina(SeriesD),30(6):592~601(inChinese).
LeiJiajin,LiRenweiandCaoJie.2000b.Thecharacteristicsofblack shale-hostedconcretionaryphosphatesandthemechanismsofmi crobesmediatedphosphorusprecipitationinCambrianhorizonon Yangtzeplatform[J].ScientiaGeologicaSinica,35(3):277~287(inChinesewithEnglishabstract).
LiShengrongandGaoZhenmin.1995.REEcharacteristicsofblackrock seriesoftheLowerCambrianNiutitangFormationinHunan-Guizhouprovince,China,withadiscussionontheREEpatternsin marinehydrothermalsediments[J].ActaMineralogicaSinica,15(2):225~229(inChinesewithEnglishabstract).
LiShengrongandGaoZhenmin.2000.SourcetracingofnoblemetalelementsinblackshalesoftheCambrianbottominHunanandGuizhou province[J].ScienceinChina(SeriesD),30(2):169~174(in ChinesewithEnglishabstract).
LiShengrong,XiaoQiyun,ShenJunfeng,etal.2002.SourceofPGE andRe_OsisotopesrestrictionoforeageintheLowerCambrian blackshaleseriesinHunanandGuizhouprovince[J].ScienceinChi na(SeriesD),32(7):568~575(inChinese).
MaoJW,ZhangGDandDuAD.2001.Geology,geochemistryand Re_OsisotopicdatingoftheHuangjiawanNi_Mo_PGEdeposit,Zun yi,Guizhouprovince[J].ActaGeologicaSinica,75(2):234~243.
MurowchickJB,CoveneyRM,GrauchRI,etal.1994.Cyclicvaria tionsofsulfurisotopesinCambrianstrataboundNi_Mo_(PGE_Au)oresofsouthernChina[J].GeochimicaetCosmochimicaActa,58(7):1813~1823.
ShangHuiyun,LiJingchaoandGuoShunling.1990.OrganicGeochem istryandFluorescentMicroscopeTechnology[M].Beijing:The PetroleumIndustryPress,1~287(inChinese).
SinghSK,TrivediJRandKrishnaswamiS.1999.Re_Osisotopesys tematicsinblackshalesfromtheLesserHimalaya:Theirchronology androleinthe187Os/188Osevolutionofseawater[J].Geochimicaet CosmochimicaActa,63(16):2381~2392.
VolkmanJKandMaxwellJR.1986.Acyclicisoprenoidsasbiological makers[A].JonesRB.BiologicalMakersintheSedimentray Record[C].NewYork:ElsevierPublishers,1~42.
WangDenghong.1997.Advanceinthestudyofmineraldepositsassoci atedwithblackshales[J].Geology-Geochemistry,2:85~88(in ChinesewithEnglishabstract).
WangHongmei,ZhangWenhuai,XieShucheng,etal.2000.Theor ganicgeochemistrycharacteristicsofJinyagolddeposit,Guangxi[J].ActaPetrologicaSinica,16(4):602~608(inChinesewith Englishabstract).
WenHanjie,QiuYuzhuo,YaoLinbo,etal.2000.Theorganicgeo chemistrycharacteristicsofsomeLowerCambrianSe_richsteatain Chinaandtheirbiomarkers’study[J].Geochimica,29(1):28~34(inChinesewithEnglishabstract).
WuChaodong,ChenQiyingandLeiJiajin.1999c.Thegenesisfactors andorganicpetrologyofblackshaleseriesfromtheupperSinianto theLowerCambrian,southwestofChina[J].ActaPetrologicaSini ca,15(3):453~462(inChinesewithEnglishabstract).
WuChaodong,YangChengyunandChenQiying.1999a.Theorigin andgeochemicalcharacteristicsofUpperSinian-LowerCambrian blackshalesinwesternHunan[J].ActaPetrologicaetMineralogica,18(1):26~38(inChinesewithEnglishabstract).
WuChaodong,YangChengyunandChenQiying.1999d.Thehy drothermalsedimentarygenesisofbaritedepositsinwestHunanand eastGuizhou[J].ActaScientianrumNaturaliumUniversitatis Pekinensis,35(6):1~12(inChinesewithEnglishabstract).
WuChaodong,ZengFangang,LeiJiajin,etal.1999b.Theoriginof LowerCambrianblackshalesinwesternHunan,withthemethods ofsulphurspeciesandisotopicanalysis[J].ScienceBulletinofChina,44(6):1~5(inChinese).
XiangLiwen.1981.StratigraphyofChina(No.4):TheCambrianSys temofChina[M].Beijing:GeologicalPublishingHouse,1~210(in Chinese).
XiaoQiyunandLiShengrong.2002.Thesurfacetransportationofele mentsandtheenvironmentaleffectoftheLowerCambrianmineral izedblackshalesinHunan-Guizhouregion[J].HaidianUniversity Journal,59(3):44~52(inChinesewithEnglishabstract).
YeJieandFanDelian.1994.TraceelementsCharacteristicsofFe_Mn oredepositsinWafangzi,LiaoningProvince[A].OpeningLaborato ryofOreDepositsandGeochemistry,InstituteofGeochemistryChi neseAcademyofScinces.StudyofOreDepositsandGeochemistry[C].Beijing:EarthquakePress,80~82(inChinese).
YeJieandFanDelian.2000.Characteristicsandmineralizationofore depositsrelatedtoblackshaleseries[J].BulletinofMineralogy,PetrologyandGeochemistry,19(2):95~102(inChinesewith Englishabstract).
ZhangGuangdi,LiJiuling,XiongQunyao,etal.2002.Enrichment featuresandpatternsofPGEmetalsinblackshalefromZunyiarea,Guizhouprovince[J].MineralDeposits,21(4):377~386(inChi nesewithEnglishabstract).
鲍正襄,万榕江,包觉敏.2002.上扬子台区下寒武统黑色岩系中的钒矿床[J].云南地质,21(2):175~182.
陈华勇,张增杰.2001.湘西北黑色岩系中矿产资源的综合利用[J].地质与勘探,37(3):32~35.
范德廉,杨秀珍,王连芳,等.1973.某地下寒武统含镍钼多元素黑色岩系的岩石学及地球化学特点[J].地球化学,3:143~163.
高振敏,罗泰义,李胜荣.1997.黑色岩系中贵金属富集层的成因:来自固定铵的佐证[J].地质地球化学,1:18~23.
胡凯,刘英俊,王鹤年,等.1995.华南碳质岩系层控金矿的有机地球化学特征和成因[J].中国科学(B辑),25(10):1099~1107.
黄占起,沈存利,王守光.2002.内蒙古狼山—渣尔泰山地区与黑色岩系有关的铂族元素矿床找矿前景[J].地质通报,21(10):663~667.
雷加锦,李任伟,曹杰.2000b.上扬子区早寒武世黑色页岩磷结核特征及生化淀磷机制[J].地质科学,35(3):277~287.
雷加锦,李任伟,TobschallHJ,等.2000a.扬子地台南缘早寒武世黑色岩系中形态硫特征及成因意义[J].中国科学(D辑),30(6):592~601.
李胜荣,高振敏.1995.湘黔地区牛蹄塘组黑色岩系稀土特征———兼论海相热水沉积岩稀土模式[J].矿物学报,15(2):225~229.
李胜荣,高振敏.2000.湘黔寒武系底部黑色岩系贵金属元素来源示踪[J].中国科学(D辑),30(2):169~174.
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