Front Cover: Taming of Thioketones: The First Asymmetric Thia-Diels-Alder Reaction with Thioketones as Heterodienophiles (Eur. J. Org. Chem. 5/2017)

详细信息    查看全文

• 作者：Joanna Hejmanowska ; Marcin Jasiński ; Grzegorz Mlostoń and Łukasz Albrecht
• 刊名：European Journal of Organic Chemistry
• 出版年：2017
• 出版时间：February 03, 2017
• 年：2017
• 卷：2017
• 期：5
• 页码：939
• 全文大小：1811K
• ISSN：1099-0690

文摘

The cover picture shows the concept of the enantioselective thia-Diels–Alder reaction with aryl and hetaryl thioketones as dienophiles proceeding according to the trienamine activation model described in the manuscript. The ant shown in the picture symbolizes the aminocatalyst that does the hard work in the catalytic cycle, being responsible for the formation of the crucial trienamine intermediate and efficient chirality transfer. The artwork is by Sandra Bednarska and Jan Bojanowski. Details are discussed in the Communication by Ł. Albrecht et al. on page 950 ff (DOI: inelibrary.wiley.com/doi/10.1002/ejoc.201601307/abstract" title="Link to external resource: http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201601307/abstract" target="_blank">10.1002/ejoc.201601307).