A novel recognition mechanism supported by experiment and theoretical calculation for hypochlorites recognition and its practical application
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- 作者：Kangming Xionga ; 1Author Vitae ; Fangjun Huob ; huofj@sxu.edu.cn" class="auth_mail" title="E-mail the corresponding authorAuthor Vitae ; Caixia Yina ; yincx@sxu.edu.cn" class="auth_mail" title="E-mail the corresponding authorAuthor Vitae ; Yueying ChucAuthor Vitae ; Yutao Yanga ; 1Author Vitae ; Jianbin ChaobAuthor Vitae ; Anmin Zhengc ; zhenganm@wipm.ac.cn" class="auth_mail" title="E-mail the corresponding authorAuthor Vitae
- 关键词：Recognition mechanism ; Nitroso ; Hypochlorite ; Bioimagings
- 刊名：Sensors & Actuators: B. Chemical
- 出版年：2016
- 出版时间：1 March 2016
- 年：2016
- 卷：224
- 期：Complete
- 页码：307-314
- 全文大小：2782 K
文摘
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We have developed two new colorimetric and fluorescent probes for hypochlorite based on a novel recognition mechanism: amido oxidized nitroso-group by hypochlorites.
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The optical properties of the probe 2 and its ClO−-addition product were studied based on DFT and TDDFT were explored at the m062x/6-31+G (d) level.
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The probe 2 could be applied in practical applications such as detecting the hypochlorite concentration of sodium hypochlorite disinfectant and bioimagings.