Based on various nitrogen-rich energetic ligands, high-energy metal–organic frameworks (HE-MOFs) have attracted considerable attention in the field of energetic materials.
HE-MOFs exhibit controllable structures, various modifiable functionalities, high density, remarkable heats of detonation, insensitivity, good thermal stability and favorable mechanical hardness.
The purpose of this review is to provide readers with an inductive overview of both in-depth understanding of energetic-sensitive-structural correlations.
This review is favorable to guide the future design of novel HEDMs through the combination of experiment and theory.