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CO2 abatement from the iron and steel industry using a combined Ca-Fe chemical loop
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FeO/Fe2O3 redox and CaO/CaCO3 calcination cycles are coupled for an auto-thermal CO2 capture.

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The highly exothermic oxidation of FeO drives the energy-intensive CaCO3 calcination reaction.

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The material developed exhibits a stable cyclic CO2 uptake and appreciably reduced net heat demand.

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The combined Ca–Fe chemical loop proposed is promising for CO2 capture from iron and steel industry.

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