Synthesis of allylic sulfonic acids via regioselective Pd-catalyzed allylic substitutions of Na₂SO₃

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• 作者：Wei Liu ; Xiaoming Zhao ; ^{xmzhao08@mail.tongji.edu.cn" class="auth_mail" title="E-mail the corresponding author}
• 关键词：Regioselectivity ; Allylation ; Na2SO3 ; Palladium ; Sulfonic acid
• 刊名：Tetrahedron Letters
• 出版年：2015
• 出版时间：2 December 2015
• 年：2015
• 卷：56
• 期：48
• 页码：6800-6802
• 全文大小：523 K

文摘

Palladium-catalyzed allylic sulfonations of the linear allylic carbonates with sodium sulfite (Na₂SO₃) were accomplished under mild conditions. This method gave allylic sulfonic acids in good to excellent yields with high level of regioselectivities.