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Assembly of a check-patterned CuSx-TiO2 film with an electron-rich pool and its application for the photoreduction of carbon dioxide to methane
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A new check-patterned CuSx–TiO2 film was prepared by the squeeze printing method.

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Significantly increased amounts of CO2 were adsorbed on the CuSx–TiO2 film.

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High amounts of CH4 (53.2 μmolgcat−1 L−1) were produced over the CuSx–TiO2 film.

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An electron-rich pool was supposedly formed at the boundary between TiO2 and CuSx.

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