Unusual binuclear alkoxomolybdenum(V) complex free of oxo groups: synthesis, structure and IR spectra

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• 作者：Nadezhda V. Bardina ; Tamara A. Bazhenova ; Konstantin A. Lyssenko ; Mikhail Yu. Antipin ; Yurii M. Shulga ; Tatyana A. Filina ; Alex ; er F. Shestakov
• 刊名：Mendeleev Communications
• 出版年：2006
• 出版时间：2006
• 年：2006
• 卷：16
• 期：6
• 页码：307-308
• 全文大小：191 K

文摘

The interaction of MoCl₅ with NaOMe in methanol led to the formation of a new neutral binuclear molybdenum(V) alkoxo complex with Cl ligands, trans-[Cl(OMe)₃Mo(μ-OMe)₂Mo(OMe)₃Cl]; the complex was characterised by X-ray analysis, IR spectroscopy and DFT quantum-chemical calculations.