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• 作者：Denise Mé ; ry ; Lauriane Plault ; C&aacute ; tia Ornelas ; Jaime Ruiz ; Sylvain Nlate ; Didier Astruc ; Jean-Claude Blais ; Joã ; o Rodrigues ; Sté ; phane Cordier ; Kaplan Kirakci ; and Christiane P
• 刊名：Inorganic Chemistry
• 出版年：2006
• 出版时间：February 6, 2006
• 年：2006
• 卷：45
• 期：3
• 页码：1156 - 1167
• 全文大小：427K
• 年卷期：v.45,no.3(February 6, 2006)
• ISSN：1520-510X

文摘

Hexasubstitution of apical triflate ligands in the octahedral clusters [M]₂[Mo₆X₈(CF₃SO₃)₆] (M = n-Bu₄N or Cs, X =Br or I) and monosubstitution in [n-Bu₄N]₂[Mo₆Br₁₃(CF₃SO₃)] was carried out in tetrahydrofuran at 60 mages/entities/deg.gif">C with simplepyridines and then extended to organometallic pyridines, yielding cluster-cored stars, and to dendronic polyallyl-and polyferrocenylpyridines, yielding cluster-cored polyallyl and polyferrocenyl dendrimers and dendrons. The orangepyridine-substituted clusters, whose pyridine protons are deshielded in ¹H NMR (a practical tool for characterization),are air-stable and thermally stable with simple pyridines, light- and air-sensitive with organometallic pyridines, andair-fragile and thermally fragile with large dendronized pyridines.