Synthesis of Fullerene-Fused Dioxanes/Dioxepanes: Ferric Perchlorate-Mediated One-Step Reaction of [60]Fullerene with Diols
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- 作者：Xiao-Feng Zhang ; Fa-Bao Li ; Jun Wu ; Ji-Long Shi ; Zhan Liu ; Li Liu
- 刊名：Journal of Organic Chemistry
- 出版年：2015
- 出版时间：June 19, 2015
- 年：2015
- 卷：80
- 期：12
- 页码：6037-6043
- 全文大小：367K
- ISSN：1520-6904
文摘
The facile one-step reaction of [60]fullerene with various diols in the presence of ferric perchlorate afforded a series of rare fullerene-fused dioxanes/dioxepanes. Nevertheless, the reaction of [60]fullerene with diethylene glycol, triethylene glycol, and tripropylene glycol promoted by ferric perchlorate unexpectedly generated fullerene-fused dioxanes instead of the anticipated fullerene-fused crown ethers. A plausible reaction mechanism is proposed to explain the formation of fullerene-fused dioxane/dioxepane products.