Iodine-Mediated Highly Regio- and Stereoselective Iodoamination of Ferrocenyl Allene: An Approach for the Synthesis of Ferrocene-Containing Allylic Amines

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• 作者：Shufeng Chen ; Qing Yan ; Haiying Zhao ; Baoguo Li
• 刊名：The Journal of Organic Chemistry
• 出版年：2013
• 出版时间：May 17, 2013
• 年：2013
• 卷：78
• 期：10
• 页码：5085-5089
• 全文大小：295K
• 年卷期：v.78,no.10(May 17, 2013)
• ISSN：1520-6904

文摘

A straightforward and efficient protocol for the highly regio- and stereoselective synthesis of ferrocene-containing allylic amine derivatives via an iodine-mediated iodoamination of ferrocenyl allene was developed. The regio- and stereoselectivity of this reaction may be controlled by the steric effect of the bulky ferrocene group.