Intermolecular Interactions between Encapsulated Aromatic Compounds and the Host Framework of a Crystalline Sponge
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- 作者：Lilian M. HayesNeil J. Press ; Derek A. Tocher ; Claire J. Carmalt
- 刊名：Crystal Growth & Design
- 出版年：2017
- 出版时间：February 1, 2017
- 年：2017
- 卷：17
- 期：2
- 页码：858-863
- 全文大小：455K
- ISSN：1528-7505
文摘
The crystalline sponge [{(ZnI2)3(tris(4-pyridyl)-1,3,5-triazine)2·x(solvent)}n] has been used to produce a range of novel encapsulation compounds with acetophene, trans-cinnamaldehyde, naphthalene, anthracene, and benzylcyanide. Using additional data from previously reported encapsulation compounds, three systematic series have been created and analyzed to investigate the behavior of guest molecules within the sponge framework and identify the dominant intermolecular interactions.