Measuring Order in Contact-Poled Organic Electrooptic Materials with Variable-Angle Polarization-Referenced Absorption Spectroscopy (VAPRAS)

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• 作者：Benjamin C. Olbricht ; Philip A. Sullivan ; Peter C. Dennis ; Jeffrey T. Hurst ; Lewis E. Johnson ; Stephanie J. Benight ; Joshua A. Davies ; Antao Chen ; Bruce E. Eichinger ; Philip J. Reid ; Larry R. Dalton ; Bruce H. Robinson
• 刊名：Journal of Physical Chemistry B
• 出版年：2011
• 出版时间：January 20, 2011
• 年：2011
• 卷：115
• 期：2
• 页码：231-241
• 全文大小：327K
• 年卷期：v.115,no.2(January 20, 2011)
• ISSN：1520-5207

文摘

Organic nonlinear electrooptical (ONLO) chromophores must be acentrically ordered for the ONLO material to have electrooptic (EO) activity. The magnitude of the order is characterized by the acentric order parameter, cos³ 尾, where 尾 is the major Euler angle between the main axis of the chromophore and the poling field which imposes the acentric order. The acentric order parameter, which is difficult to measure directly, is related to the centrosymmetric order parameter, defined as P₂ = ¹/₂(3cos² 尾 鈭?1), through the underlying statistical distribution. We have developed a method to determine centrosymmetric order of the ONLO chromophores when the order is low (i.e., P₂ < 0.1). We have extended the method (begun by Graf et al. J. Appl. Phys. 1994, 75, 3335.) based on the absorption of light to determine the centrosymmetric order parameter induced by a poling field on a thin film sample of ONLO material. We find that the order parameters, analyzed by two different methods, are similar and also consistent with theoretical estimates from modeling of the system using coarse-grained Monte Carlo statistical mechanical methods.