Charge Renormalization for Ellipsoidal Macroions

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• 作者：YongSeok Jho ; Jonathan Landy ; P. A. Pincus
• 刊名：ACS Macro Letters
• 出版年：2015
• 出版时间：June 16, 2015
• 年：2015
• 卷：4
• 期：6
• 页码：640-644
• 全文大小：313K
• ISSN：2161-1653

文摘

We study the problem of counterion condensation for ellipsoidal macroions, a geometry well-suited for modeling liquid crystals, anisotropic vesicles, and polymers. We find that the ions within an ellipsoid鈥檚 condensation layer are relatively unrestricted in their motions, and consequently work to establish a quasi-equipotential at its surface. This simplifies the application of Alexander et al.鈥檚 procedure, enabling us to obtain accurate analytic estimates for the critical valence of a general ellipsoid in the weak screening limit. Interestingly, we find that the critical valence of an eccentric ellipsoid is always larger than that of the sphere of equal volume, implying that counterion condensation provides a force resisting the deformation of spherical macroions. This contrasts with a recent study of flexible spherical macroions, which observed a preference for deformation into flattened shapes when considering only linear effects. Our work suggests that the balance of these competing forces might alter the nature of the transition.