Magnetic and Dendritic Catalysts

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• 作者：Dong Wang ; Christophe Deraedt ; Jaime Ruiz ; Didier Astruc
• 刊名：Accounts of Chemical Research
• 出版年：2015
• 出版时间：July 21, 2015
• 年：2015
• 卷：48
• 期：7
• 页码：1871-1880
• 全文大小：685K
• ISSN：1520-4898

文摘

The recovery and reuse of catalysts is a major challenge in the development of sustainable chemical processes. Two methods at the frontier between homogeneous and heterogeneous catalysis have recently emerged for addressing this problem: loading the catalyst onto a dendrimer or onto a magnetic nanoparticle. In this Account, we describe representative examples of these two methods, primarily from our research group, and compare them. We then describe new chemistry that combines the benefits of these two methods of catalysis.