Electrosynthesis of (E)-Vinyl Sulfones Directly from Cinnamic Acids and Sodium Sulfinates via Decarboxylative Sulfono Functionalization

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• 作者：Peng Qian ; Meixiang Bi ; Jihu Su ; Zhenggen Zha ; Zhiyong Wang
• 刊名：Journal of Organic Chemistry
• 出版年：2016
• 出版时间：June 3, 2016
• 年：2016
• 卷：81
• 期：11
• 页码：4876-4882
• 全文大小：443K
• 年卷期：0
• ISSN：1520-6904

文摘

A variety of (E)-vinyl sulfones were constructed directly from cinnamic acids and sodium sulfinates with high regioselectivity at room temperature by virtue of an electrocatalytic oxidation. A radical intermediate was detected, and the corresponding mechanism was investigated.